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tổng hợp, nghiên cứu cấu trúc và thăm dò hoạt tính sinh học của phức tạo thành giữa cu(ii) và bazơ schiff đi từ isatin và 8 - aminoquinoline

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?8•63$r’?•&G1$;††6IWH3;W;'’K',?•&G1$;††1>3$•B%k1B;KL1$M3p?';6;'i$;

D
6Ig$X'•6$V‰1g$X'•63$M3$rB%k1(@;6IWH3?';6,
?•&G1$;††6IJ‡'g$›W1A?JŽ'(%'(3P(;…?$kg1$231?1’V'•64I?W;'
’51€ƒ,0OPg$‡'N'(3h'($kg’?•&G1$;††J?L,
SH
NH
2

NHC
O
S
N
H

C
H
N
N
SH
C
N
H
?•&G1$;††
?•&G1$;††1>3$•B%k139V3$I'$i$;1$V$kg1$231?1’V'•63:1OP'(4S;?W;'
3$&W  •i$t'(  1‹'  ln1  3:1‚,  0  OP  ’X'•?'BX$;3  3:1  OP'(  4S;  ?';6;'  39V  8?
’X'••6;BX'?';6;'•
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sªs



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„
=
Q
?•&G1$;††O˜’m3$L¯g$q'38V'(Wt;38%‘'(?l;338o69;?'BX$;34I?W;'’?'
B‹L1$Š'$…'(’?•&G1$;††J;'$8?3p$kg1$231?1’V'•63$&W4I?W;'3$&WWS;
’K'4…'(,
?•&G1$;††B>'(4?;38E823UL?'38@'(38V'(J;'$$>?4t1&B:'(1$n7
'$236I$V9330'$J;'$$@11A?1$n'(,$j;3v’?•&G1$;††B%k1JvOP'(8H'(8–;
38V'(3h'($kgg$N11$234rg$N11$231A?'>1>BH’K'1?V4Ii$‡'Œ'($E?3?'3j3
38V'(1:1OL'(Wt;3$t'(3$%‘'(,T3$j'(π38V'(’?•&G1$;††3$%‘'(1$mLJŽ38>;
’LH14K$r'$$@14I‡'$$%o'(BM'12L38n1X6X138V',!;KL'I•1>3$•i•BM'i$‡
'Œ'(ln13:11A?g$N1L•‚;•‚V•‚4S;’?•&G1$;††,,,€=Dƒ€Dƒ€ƒ,
(I•1I'(1>'$;KL'($;<'1NL4K’?•&G1$;††B%k1N'(OP'(O%S;Bq•6I
WH3Jj40OP,
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8V'(  1t'(  38r'$ €=ƒ ’?•&  G1$;††  3$L  B%k1  3p    
°
s•=‚s=s
l;16V$Xl?'B;?W;'  4I  =s$•O8Vl;sDsWX3•6’X'•?'OX$;3  =s  $•O8Vl;sDs
WX3•6’X'•?'OX$;3B–B%k1JvOP'('$%WH3g$j;3vB•39Vg$N14S;L•‚V•‚
;•‚1:1g$N13$LB%k11>O9'($r'$$@1’:3O;T'$V‰14Lt'(g$¤'(4IBKL1>
$V9330'$J;'$$@1,2L38n11A?g$N1B%k11$Š8?O%S;Bq••
O O
M
HC CHN
N
H
H

R
R


F
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Y

D

=
N
O
O
N
M
O
N
O
N
:1’?•&G1$;††6I'$…'(1?1’V$;B8?31š'(B–B%k1’;M3BM'38V'('$;KL'ŒW
UL?,(%‘;3?B–3h'($kgB%k1g$N11A?L•‚V•‚\X•‚;•‚4S;1:1’?•&
G1$;††B;3pB%‘'(?W;'V,%S;Bq•6I12L38n11A?g$N1;•‚,
O
Q
=
Q
Q
OH,H

Ni
O
O
N
N
H
H
O

=
Q
Q
Q
OH,H
2L38n1g$N1•’;Jss€=sOXVl•ss(6L1Vg•8?'VJ•6s=s•=$•B8Vl•’X'•?6B;W;'?3‚ƒ';iX'•‚,
14Z4([\]%WXHYYH
H3Jjg$N11$2339V3$I'$(;…?J?3;'$•O8?•V'4S;L•‚;•‚4IZ'•‚
B–B%k13h'($kg€==ƒ,+L?'($;<'1NL1$V3$2•1$n'(1>i$‡'Œ'(N11$MJŽg$:3
38;•'3M’IVi$j;Lo'(%‘;,($;<'1NL1š'(1$N'(3u1:1g$N1'I•1>$V9330'$o
=F
1:1'C'(BHi$:1'$?L,L•'$;<'1&1$M3:1BH'(6<'1:13M’IVi$j;L4œ'1$%?
B%k16IWJ:'(3u€==ƒ,
$N11$231A?’?•&G1$;††4S;'$;KLi;W6V9;1$L••'3;Mg'$%\XQJ
L$,,,4S;$V9330'$J;'$$@1g$V'(g$n1š'(B–B%k1'($;<'1NL3h'($kg
38V'('$;KL1t'(38r'$40OP•
8V'(1t'(38r'$€=ƒ3:1(;‡B–3h'($kgB%k1g$N11A?\X•‚4S;’?•&
G1$;††lL23g$:33pG?6;1•6?'OX$•OX4S;?l;3'3$8?';6;1,
8V'(1t'(38r'$€Dƒ3:1(;‡B–3h'($kgg$N11$231A?G“3•‚4S;’?•&
G1$;††'$%J?L•
[Fe

3
L
2
(H
2
O)
6
]SO
4
khi L là đianion của N,N’-bis(3-formyl-5-
methoxy-6-hydroxy-benziliden) ethylenediamine (L)
H3JjOœ'lL23;W;'4IB;;W;'3$LB%k1’”'(1:1$'(%'(3P;J?3;'4S;1:1
?W;'i$:1'$?LB–B%k13h'($kg4Ig$N11$231A?1$n'(4S;;V'L•‚B–B%k1
i$‡VJ:3,$…'(g$N11$23'I•1>$V9330'$ln13:11š'('$%$V9330'$J;'$$@1,
($;<'1NL1$V3$2•'$…'($kg1$23'I•3C'39;1q'’”'(iX3VsX'V638V'(OL'(Om1$
=
'%S1 g$P  3$LH1 4IV g 4I 1> $V93  30'$ ln1 3:1 Bj; 4S; g$‡' N'( Vl; $>?
1?1’V$•O8?3’o;'(L•<'3vQl;€==ƒ,
G?LBq•6IWH3Jj1t'(3$N112L39V1A?g$N1L•‚;•‚Z'•‚4S;
;J?3;'B–B%k1'($;<'1NL38V'(1t'(38r'$€)ƒ€==ƒ€DDƒ€Dƒ,

N

Q
Q

L
=„

=

N
NH

[L•;J?$;J3‚•
=
Q‚]
=„
[L•;J?g'‚]

 
[L•;J?Xg•‚
=
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[L•;J?‚
=
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$•‚8•‚4S;’?•&G1$;††;J?3;''$%J?L•
789::: ;9::: ;:::: <98!
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G?LBq•6I'$…'(g$N11$23B–B%k13h'($kg4I'($;<'1NL38V'(1t'(
38r'$€ƒ€ƒ€Yƒ€=ƒ,t'(38r'$€ƒ’:V1:V'($;<'1NLg$N1;J€µs>>±s’;J•µs=s
Vl;OVg$X'•6WX3$•6X'X;W;'V‚g8Vg?'Xs=sO;?W;'?3V•Ds‚ƒ;8V'•‚
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1?8’Vl?6;OX'Xs=s?W;'Vg$X'V6•‚B–B%k13h'($kg,
=D
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$N1  \X•‚  4S;  ’?•&  G1$;††  ’;Js€s$•O8Vl•61VLW?8;'sDs•6ƒs

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1$j'('2W4I4;i$L›'(q•’T'$,2L38n1g$N1•
14^4   (_X' ((  '` [ \  ab  P  c *d
OeHf
14^414( /0g?gghE/0/0S>
$; 1$;ML 1$•W  3;?  B&'  J“1  1> Jj  J>'( '”W 38V'( 4•'(  $C'( '(V9; 
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3$P'I•3Lq'3$XVBm'$6L53?W’X83sXX8€ƒ€Dƒ€Yƒ•
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si•$TJj$2g3$PWV6

s6•BHOI•1L4X3
s•'C'(BH1$23g$q'301$
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