phân tích eclectron trong hóa phân tích phần 10 pdf

lo °
• 10 -+
¢::
o 10 .=
0
L.
(D
m ] 10 "3
10 .4
10 .5
[] Included point "
• Excluded point
_
CX I
= 0.74
- O •
_
au= 0.91
T # =
0.80
- •
M
w
T = 235 °C
-P = 1.48 MPa,
H2/CO = 1.0
• O •
i
O
SV =,2.0 Nl/g-cat,h -
I I I ,_,, , , , I I , I , I I , , ,,t I

0 6 12 18 24 80 36 42 48 54
Carbon number
Pig.r~" 32. A.,letson-Schldz-Plory piol. for r.n PA-O3-1308-1, Lobtl products exel.dinB .ntecovered w~x.
0 ~ I ' ' "' ' I l ' ~ ' ' ~ I ' ' ' " ' I ' ' ' ' J I ' ' ' ' ' I ' ' ' ' ' I
I! ' Included point I
[]
•
Excluded point I
L __ |
10"
10 "~
10"'
O0
O
T = 235 °C
P - 1.48 MPa
i
H2/CO = 0.69
SV = 2.0 NI/g-cat,h
0
c< l 0.79
ocnl= 0.91
= 0.62
8 12 18 24 30 36 42
Carbon number
go
48
-i
.i
54

Figure 33. An,l~r~n-$eht,lz-Rory plot for r,n P^-03-1308-4. total products rxcl,di,g unre¢overrd ~'ax.
i°° l+'"
'"' '"'~'"' '"+ " '+"'"""" " '"+ ' '+ ' ' ' ' ""'" ','' "+~-
I-, ,. [] Included point
10"
10"
m ~ 10 .3
113 .+
10"'
_=~ • Excluded point .
",i,
: o. o ;
= ;

i
235 °C
P = 1,48 MPa
|
m
H2/CO = 1.0
SV = 2.0 NI/g-cat,h
, , _, . ! I , , , . I . , , , I , , , , I ., _' , , I _, _. , , ! , , , , I , , , ,
0 5 10 15 20 25 30 35 40
e
,
Carbon number
45
l"igure 34. Anderson-SdmlT,-Flory plot I'or r I,'A-t}~-I,lOS-x, tc;tnl prod.¢t.~ exclmling unre¢overe(! wnx,
z
C]0

~D
c:
O
m
O~
Q)
:>
c-
O
O
O
+
o4
3:
0<
60
70
00
60
40
8O
20
0
,ll
" k''
I
Oo
I " ' I' 1"'
• FA-15-1698 (100 Fell.0 Cu/0.2 K)
• FA-15-1768

235 °C
1.48 MPa
2.0 NI/g-cst.h
(H2/CO) = 0.67
O O
l •
I , , • I , , , L,, * I
60 100 150
Time on stream (h)
200
Pig,r,. 3~. SL,iI)ility ploi. (II~-I-CO) conversion vers,IA time on stfesm, for r,ns F^-I 5-1098 and l.'A-15- 1768.
70 - ~ ' ; - ~" i " ' ~ - • - | • • ±' • I ,L• , , I II II , n,~ln,ll,,I | n • • ~ | • . • t "~
05
8O
r-
0
m
55
>
C
0
O
50
0
0
+
cq 45
"r-
4O
85

80
O•
4ca,
(H2/CO) = 0.67
(H2/CO) = 1.0
e~~ o ~ • ~ ~.
~ oaPaV
0
FB-99-1588 (Ruhrohemle LP 33/81)
250 °C ,
1.48 MPa
2,0 NI/g-cat.h
• _, 0 _, _1 , ,_., , I , j • I
,
! ,. , , I , • • , I ,
,
, . ,
0 100 200 800 400 500 600
Time on stream (h)
700
PigLzre 30. SL~l)ility plof (llz4-CO) ronversion vers,s tiz,e on streams For r.n Fn-90-1588.
, I
60.0-
5OO
30.0
O.O
71 167 263 36O 42"7 528 623
"////////~
1' I
0-~

C2-C4
C5-~il
C12+
.g
3;
&O
&O
50
4Q
2_0
1~)
(10
71 167 263 380 427 ,528 623
Tin~ on S~ (h)
I I
(:;2
C3
C4
C8
I
C10
Figure 37. Effec~ of time on stream cn Ruhrchem]e LP
33/81
selectivity for rm~ FB 99-15S8:250
=C, 1.48
MPa, 2 ]v'l/g-cat.h,
(H2/CO) = 0.67 (71-427 h) amd 1.0 (528, 623 h).
• o
91
i

3:
•E}
m
3E:~ i
2gO
1DO
O,O
E~ 2 SA-3 F'B 5 SA-12
I I
O44
C2-C4
C5 Cll
C12÷
E:
7n
60
50
4.D
30
23
1.0
O0
F'B-2 SA-3 ~-6 SA-12
I I
C2
C3
C7777~
C#
C8
I' i

C10
Fig, u~e 38. Comparison offixecl bed a~cl slur~' reactor select3v]ty wi¢]~ tL~hrchemie I.P 33/81 cata]ys~
(FB = TB-99-1588, SA = 5A-99-0888): 250 °C, 1.48 MPa, 2.0
~'l/g-cat-h,
(H2/CO) =
0.67 (FB-2 amd SA-3) and 1.0 (PB-6 a~d SA-12).
92
e
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