Earth Materials:
Minerals
Today’s Lecture:
Chapter 5. Patterns in
Nature: Minerals &
Prelude A: Rock Groups
Chemical bonding: Focus
on covalent bonds
Mineral polymorphs
Physical properties of
minerals
Common rock-forming
“silicate” minerals
Introduction to rocks & the
rock cycle
Atomic Bonding
✦ Ionic Bonding
Example: Table Salt: Sodium (Na) and Chlorine (Cl)
Sodium gives up an
electron becoming
a positively-charged
charged cation.
cation
Chlorine picks up an electron
becoming a negatively charged
anion.
anion
Bonding between sodium and chlorine in halite
is based on these charge differences.
Sharing Electrons: Covalent Bonding
Nucleus
Shared electrons
Factors that determine the internal
structure of minerals:
1) Composition of magma or fluids from which the
minerals form.
2) Conditions under which the mineral forms:
◆ Temperature
◆ Pressure
Minerals comprised of the same elements in the
same proportions can possess markedly
different internal structures.
For example:
Higher pressure -> Denser packing of atoms -> Different mineral
Mineral Structure & Conditions of Formation
Different minerals w/ same chemical composition ,
but differing structures, are called “polymorphs”
Graphite (a form of pure carbon)
Soft gray material, e.g., pencil lead
Crystal structure: sheets of carbon
Diamond (also pure carbon)
Forms deep in Earth at high pressures,
& is hardest substance known to humans
Crystal structure: dense & compact
Identifying Minerals
To identify minerals, we use their physical and optical
properties. Some properties are more diagnostic than
others, so we try to use a combination when making a
determination. Useful properties include:
✦ Color
✦ Luster
✦ Hardness
✦ Streak
✦ Crystal form
✦ Cleavage
✦ Fracture
✦ Reaction to acid
✦ Taste
✦ Smell
✦ Magnetization
✦ Optical properties
✦ Elasticity
✦ Specific gravity
Physical properties of minerals
✦ Color
Obvious, but often misleading. Slight impurities in a mineral
can change its color.
Example: Quartz (when pure it is colorless), but there are
many color varieties which result from small amounts of other
elements.
Physical properties of minerals
✦ Luster
The appearance of light reflected from minerals.
Examples:
Metallic luster vs. nonmetallic luster
Glassy (vitreous) luster
Resinous luster
Physical properties of minerals
✦ Hardness
Very useful! Measures a mineral’s resistance to
scratching. We use Moh’s hardness scale (below)
for comparisons.
Crystal Form Reflects the Internal Arrangement of Atoms
Crystal form in halite
(salt; NaCl) is cubic
A law of mineralogy:
Constancy of angles between crystal faces
✦ Crystal Form
The shape of a well-formed crystal reflects
directly the orderly internal arrangement of
Its constituent atoms.
Well-formed crystals that grow without
interference are called “euhedral”.
Quartz
(SiO2)
Anhedral crystals form when
crystals don’t have room
to grow and bump into each other
feldspar in an igneous rock
Irregular boundaries between crystals
due to interference during growth
Anhedral crystals
formed by crowding
during growth
Quartz geode
Crystal terminations of
euhedral quartz
Anhedral quartz crystals
formed by crowding
during growth
Euhedral crystals of amphibole in a volcanic rock
Cleavage: Tendency to break along
preferred planes of weakness.
Cleavages represent directions of
weaker bonding between atoms.
2-directional cleavage in mica
In mica, atoms are arranged in
weakly-connected sheets
Asbestos
Cleaves into long flexible fibers
Asbesto
s
Asbestos
-group of silicate minerals that readily separate into fibers
that are: thin, flexible, heat resistant, chemically inert
=> many uses
- mainly three types:
chrysotile (“white asbestos”)
crocidolite (“blue asbestos”)
amosite (“brown asbestos”)
3-directional
cleavage
Cleavage in both Halite
(salt) & calcite (lime)
is in three directions.
But the angles between
cleavages are different
for these minerals.
Halite has a cubic
cleavage.
Calcite cleaves into
rhombohedra.
Can you spot which is
which in the samples
to the left?