CHUOI PHAN UNG HIDROCACBON

<span class='text_page_counter'>(1)</span>01699.002.889. HOÀNG TRUNG TRƯỜNG(kontum). Sơ đồ phản ứng HIDROCACBON BÀI TẬP VỀ ANKAN. o. t → CH 4 + 2 Na2CO3 1. Na − O − C − CH 2 − C − O − Na + 2 NaOH . O. O + CaO ,t o. → CH 4 + Na2CO3 + H 2O 2. CH 3COOH + 2 NaOH  3.. Al4C3 + 12 H 2O  → 3CH 4 + 4 Al ( OH )3. Al4C3 + 12 HCl  → 3CH 4 + 4 AlCl3 Al4C3 + 6 H 2 SO4  → 3CH 4 + 2 Al2 ( SO4 )3 o. 4.. Cracking ,t C3 H 8  → CH 4 + C2 H 6. 5.. 300 C C + 2 H 2  → CH 4. 6.. vikhuan CO2 + 4 H 2  → CH 4 + 2 H 2O. 7.. Ni ,250 C CO + 3H 2  → CH 4 + H 2O. 8.. CaO ,t CH 3COONa + NaOH  → CH 4 + Na2CO3. 9.. 1500 C 2CH 4  → C2 H 2 + 3 H 2 làm lanh nhanh. 10.. HgSO4 C2 H 2 + H 2O  → CH 3CHO 80o C. 11.. Ni CH 3CHO + H 2  → C2 H 5OH to. 12.. Al2O3 2C2 H 5OH  → C4 H 6 + 2 H 2 O + H 2 ↑ 450o C. 13.. Ni C4 H 6 + 2 H 2  → C4 H 10 to. o. o. o. o. Facebook : Clb gia sư trivietkontum Webside : violet.vn/Clbgiasutrivietkontum. Trang 1.

<span class='text_page_counter'>(2)</span> 01699.002.889. HOÀNG TRUNG TRƯỜNG(kontum). 14.. Cracking C4 H10  → C3 H 6 + CH 4. 15.. CH 3 − CH = CH 2 + HOH  → CH 3 − CH − CH 3 |. OH. 16.. dpdd 2CH 3COONa + 2 H 2O → C2 H 6 + 2CO2 + NaOH + H 2 ↑ có vách ngan. 17.. ánh sáng C2 H 6 + Cl2 → C2 H 5Cl + HCl. 18.. C2 H 5Cl + 2 Na + ClC2 H 5  → C4 H 10 + 2 NaCl. 19.. Cracking C4 H 10  → C3 H 6 + CH 4. 20.. Các oxit cua nito CH 4 + O2  → HCHO + H 2O 600o C. 21.. NH 3 HCHO + 2 Ag 2O  → CO2 + H 2O + 4 Ag ↓. 22.. t C3 H 7 Cl + NaOH loãng  → C3 H 7OH + NaCl. 23.. t C3 H 7OH + CuO  → CH 3 − CH 2 − CHO + Cu + H 2O. o. o. 1 Mn 2+ CH − CH − CHO + O  → CH 3 − CH 2 − COOH 3 2 2 24. 2 H SO ( d ) → CH 3 − CH = CH 2 + H 2O 25. CH 3 − CH 2 − CH 2OH  180 C 2. 26.. 4 o. CH 3 − CH 2 = CH 2 + HCl  → CH 3 − CH − CH 3 |. Cl o. 27.. t CH 3 − CH − CH 3 + NaOH loãng  → CH 3 − CH − CH 3 + NaCl |. |. Cl. OH. Facebook : Clb gia sư trivietkontum Webside : violet.vn/Clbgiasutrivietkontum. Trang 2.

<span class='text_page_counter'>(3)</span> 01699.002.889. HOÀNG TRUNG TRƯỜNG(kontum). o. 28.. t CH 3 − CH − CH 3 + CuO  → CH 3 − C − CH 3 + Cu + H 2O |. OH. 29.. 30.. 31.. O. Cracking C5 H12  → C3 H16 + C2 H 6.     xt ,t o  nCH 3 − CH = CH 2  → − CH − CH 2 −  |    CH  3  n     Dehidro  CH 2 = C − CH = CH 2  + 2 H 2 CH 3 − CH − CH 2 − CH 3 → | |     CH 3 CH 3  n.     xt ,t o nCH = C − CH = CH  →  −CH 2 − C = CH − CH 2 −  2 2 p 32. | |     CH 3 CH 3  n. 33.. 34.. Dehidro CH 3 − CH − CH 2 − CH 3 → CH 3 − C = CH − CH 3 + H 2 |. |. CH 3. CH 3.  CH 3    | xt ,t o nCH 3 − C = CH  →  − C − CH −  p | | | |    CH 3 CH 3  CH 3 CH 3  . Facebook : Clb gia sư trivietkontum Webside : violet.vn/Clbgiasutrivietkontum. n. Trang 3.

<span class='text_page_counter'>(4)</span> 01699.002.889. HOÀNG TRUNG TRƯỜNG(kontum). BÀI TẬP VỀ ANKEN. o. 1.. t NaOOC − CH = CH − COONa + 2 NaOH  → C2 H 4 + 2 Na2CO3. 2.. C2 H 4 + Br2  → C2 H 4 Br2. 3.. C2 H 4 Br2 + Zn  → C2 H 4 + ZnBr2 ddKMnO4 C2 H 4 + [O ] + H 2O  → C2 H 4 (OH ) 2. 4.. 3C2 H 4 + 2 KMnO4 + 4 H 2O  → 3C2 H 4 (OH ) 2 + 2 MnO2 + 2 KOH. 5.. nCH 2 = CH 2  → [ −CH 2 − CH 2 −]n. 6.. Cracking C4 H10  → C2 H 6 + C2 H 4. Ni ,t o. 7.. C2 H 4 + H 2  → C2 H 6. 8.. t C2 H 6  → C2 H 4 + H 2. 9.. H 2 SO4 C2 H 4 + H 2O → C2 H 5OH loãng, t o. 10.. H 2 SO4 ( d ) C2 H 5OH  → C2 H 4 + H 2O 180o C. 11.. t C2 H 5Cl + NaOH loãng  → C2 H 5OH + NaCl. 12.. C2 H 5OH + HCl  → C2 H 5Cl + H 2O. 13.. ás' C2 H 6 + Cl2  → C2 H 5Cl + HCl. 14.. H 2 SO4 ( d ) CH 3 − CH 2 − CH 2 − CH 2OH  → CH 3 − CH 2 − CH = CH 2 + H 2O 180o C. o. o. Facebook : Clb gia sư trivietkontum Webside : violet.vn/Clbgiasutrivietkontum. Trang 4.

<span class='text_page_counter'>(5)</span> 01699.002.889. HOÀNG TRUNG TRƯỜNG(kontum). 15.. Ni CH 3 − CH 2 − CH = CH 2 + H 2  → C4 H10. 16.. Cracking C4 H10  → CH 4 + C3 H 6. 17.. 1500 C 2CH 4  → C2 H 2 + 3H 2 làm lanh nhanh. 18.. Pd C2 H 2 + H 2  → C2 H 4. 19.. ddKMnO4 C2 H 4 + [O ] + H 2O  → C2 H 4 ( OH ) 2. 20.. C2 H 4 ( OH )2 + 2 HBr  → C2 H 4 Br2 + 2 H 2O. 21.. C2 H 4 Br2 + Zn  → C2 H 4 + ZnBr2. 22.. dpdd 2CH 3COONa + 2 H 2O  → C2 H 6 + 2CO2 + 2 NaOH + H 2 ↑. o. o. t → C2 H 4 + H 2 23. C2 H 6 . 24.. 3C2 H 4 + 2KMnO4 + 4H 2O  → 3C2 H 4 ( OH )2 + 2MnO2 + 2 KOH. 25.. C2 H 4 + HCl  → C2 H 5Cl. 26.. C2 H 5Cl + 2 Na + ClC2 H 5  → C4 H10 + 2 NaCl. 27.. Cracking C4 H 10  → C3 H 6 + CH 4. 28.. ddKMnO4 C3 H 6 + [O ] + H 2O  → C3 H 6 ( OH )2. 29.. CH 3 − CH = CH 2 + HBr  → CH 3 − CH − CH 3 |. Br o. 30.. t CH 3 − CH − CH 3 + NaOH loãng  → CH 3 − CH − CH 3 + NaBr |. |. Br. OH. Facebook : Clb gia sư trivietkontum Webside : violet.vn/Clbgiasutrivietkontum. Trang 5.

<span class='text_page_counter'>(6)</span> 01699.002.889. HOÀNG TRUNG TRƯỜNG(kontum). 31.. 32..     nCH 3 − CH = CH 2  →  − CH − CH 2 −  |    CH  3  . CH 3 − CH = CH 2 + Br2  → CH 3 − CH − CH 2 |. |. Br. Br. o. 33.. t → CH 3 − CH − CH + 2 NaBr CH 3 − CH − CH 2 + 2 NaOH  loãng |. |. Br. Br. |. |. OH OH BÀI TẬP VỀ ANKAĐIEN. o. 1.. t HO − CH 2 − CH 2 − COONa + NaOH  → CH 3 − CH 2 − OH + Na2CO3. 2.. Al2O3 2C2 H 5OH  → CH 2 = CH − CH = CH 2 + 2 H 2O + H 2 450o C. 3.. CH 2 = CH − CH = CH 2 + Br2  → CH 2 − CH 2 − CH = CH 2. hay. |. |. Br. Br. CH 2 = CH − CH = CH 2 + Br2  → CH 2 − CH = CH − CH 2. Facebook : Clb gia sư trivietkontum Webside : violet.vn/Clbgiasutrivietkontum. |. |. Br. Br. Trang 6.

<span class='text_page_counter'>(7)</span> 01699.002.889. HOÀNG TRUNG TRƯỜNG(kontum). 4.. CH 2 = CH − CH = CH 2 + 2 Br2  → CH 2 − CH − CH − CH 2 |. |. |. |. Br. Br. Br. Br. 5.. Na nCH 2 = CH − CH = CH 2 + 2 Br2  → [ −CH 2 − CH = CH − CH 2 −]n. 6.. Pd CH 2 = CH − C ≡ CH 2 + H 2  → CH 2 = CH − CH = CH 2. 7.. CuCl , NH 4 Cl 2CH ≡ CH   → CH 2 = CH − C ≡ CH. Phương trình 8, 9, 10, 11, 12, 13 các bạn tự viết. 14.. H nC6 H12O6 ( C6 H10O5 )n + nH 2O →. 15.. men ruou C6 H12O6  → 2C2 H 5OH + 2CO2. +. 16. 17.. Al2O3 2C2 H 5OH  → CH 2 = CH − CH = CH 2 + 2 H 2O + H 2 ↑ 450o C. Na nCH 2 = CH − CH = CH 2  → [ −CH 2 − CH = CH − CH 2 −]n to. 18..     to , p nCH = CH  →  −CH 2 = CH −  xt | |    CH = CH 2 CH = CH 2  n . 19. dpdd 2CH 2 = CH − COONa + 2 H 2O  → CH 2 = CH − CH = CH 2 + 2 NaOH + 2CO2 ↑ + H 2 ↑. Facebook : Clb gia sư trivietkontum Webside : violet.vn/Clbgiasutrivietkontum. Trang 7.

<span class='text_page_counter'>(8)</span> 01699.002.889. HOÀNG TRUNG TRƯỜNG(kontum). 20.. cong 1,2 CH 2 = CH − CH = CH 2 + Br2  → CH 2 − CH − CH = CH 2 |. |. Br. Br. Theo t l 1 : 1 cong 1,4 CH 2 = CH − CH = CH 2 + Br2  → CH 2 − CH = CH − CH 2 |. |. Br. Br. Theo tỉ lệ 1 : 1. CH 2 = CH − CH = CH 2 + Br2  → CH 2 − CH = CH − CH 2 |. |. |. |. Br. Br. Br. Br. Theo tỉ lệ 1 : 2. 21.. 22.. CH 3 − CH − CH 2 − CH 3  → CH 2 = C − CH = CH 2 + 2 H 2 |. |. CH 3. CH 3.     to , p nCH 2 = C − CH = CH 2  →  −CH 2 − C = CH − CH 2 −  xt | |     CH 3 CH 3  n. 23.. Cl     |      −CH 2 − C = CH − CH 2 −  + nHCl  →  −CH 2 − C − CH 2 − CH 2 −  | |         CH CH 3 3  n  n 24.. Cracking C5 H12  → C3 H 6 + C2 H 6. Facebook : Clb gia sư trivietkontum Webside : violet.vn/Clbgiasutrivietkontum. Trang 8.

<span class='text_page_counter'>(9)</span> HOÀNG TRUNG TRƯỜNG(kontum). 25.. 01699.002.889.     nCH 3 − CH = CH 2  →  − CH − CH 2 −  |    CH  3  n BÀI TẬP VỀ AREN. 1.. Al4C3 + 12 HCl  → 4 AlCl3 + 3CH 4. 2.. 1500 C 2CH 4  → C2 H 2 + 3H 2 làm lanh nhanh. 3.. 600 C 3C2 H 2  → C6 H 6 C. 4.. Pd C6 H12  → C6 H 6 + 3H 2 300o C. 5.. Ni C6 H 6 + 3H 2  → C6 H12 to. 6.. bot Fe C6 H 6 + Br2  → C6 H 5 Br + HBr. 7.. AlCl3 C6 H 6 + Cl − CH 3  → C6 H 5 − CH 3 + HCl. 8.. ddKMnO4 C6 H 5CH 3 + 3[O ]  → C6 H 5COOH + H 2O to. 9.. C6 H 5COOH + NaOH  → C6 H 5COONa + H 2O. 10.. C6 H 5COONa + HCl  → C6 H 5COOH + NaCl. 11.. vôi tôi C6 H 5COONa(tinh thê) + NaOH ( r )  → C6 H 6 + Na2CO3 to. 12.. á s' C6 H 6 + 3Cl2  → C6 H 6Cl6. 13.. Pd C6 H12  → C6 H 6 + 3H 2 300o C. o. o. Facebook : Clb gia sư trivietkontum Webside : violet.vn/Clbgiasutrivietkontum. Trang 9.

<span class='text_page_counter'>(10)</span> 01699.002.889. HOÀNG TRUNG TRƯỜNG(kontum). o. 14.. 900 C CaCO3  → CaO + CO2. 15.. 2000 C CaO + 3C → CaC2 + CO. 16.. CaC2 + 2 H 2O  → Ca ( OH )2 + C2 H 2. o. o. 600 C → C6 H 6 17. 3C2 H 2  C. 18.. AlCl3 C6 H 6 + Cl − CH 3  → C6 H 5 − CH 3 + HCl. 19.. 20.. dpdd C2 H 5COONa + 2 H 2O  → C4 H10 + 2 NaOH + 2CO2 ↑ + H 2 ↑. 21.. Cracking C4 H10  → C3 H 6 + CH 4 600o C. 22.. 1500 C 2CH 4  → C2 H 2 + 3H 2 làm lanh nhanh. o. o. 600 C → C6 H 6 23. 3C2 H 2  C. 24.. 25.. Dehidro C7 H16 → C6 H 5 − CH 3 + 4 H 2 to. 26.. á s' C6 H 5 − CH 3 + Br2  → C6 H 5 − CH 2 Br + HBr. 27.. OH C6 H 5 − CH 2 Br + H 2O  → C6 H 5 − CH 2OH + HBr. 28.. CH 3COOH + HO − CH 2 − C6 H 5. −. H 2 SO4 ( d ). Facebook : Clb gia sư trivietkontum Webside : violet.vn/Clbgiasutrivietkontum. CH 3COOCH 2 − C6 H 5 + H 2O. Trang 10.

<span class='text_page_counter'>(11)</span> 01699.002.889. HOÀNG TRUNG TRƯỜNG(kontum). 29.. 30.. C6 H 5CH 2CH 3 + Cl2  → C6 H 5 − CH 2 − CH 2 − Cl + HCl. C6 H 5CH 2CH 3 + Cl2  → C6 H 5 − CH − CH 3 + HCl |. Cl 31.. OH C6 H 5 − CH 2 − CH 2 − Cl + H 2O → C6 H 5 − CH 2 − CH 2 − OH + HCl. 32.. t C6 H 5 − CH 2 − CH 2OH + CuO  → C6 H 5CH 2CHO + Cu + H 2O. 33.. t C6 H 5CH 2CHO + 2  Ag ( NH 3 )2  OH  → C6 H 5CH 2 − COONH 4 + 3NH 3 + 2 Ag ↓ + H 2O. 34.. 2C6 H 5CH 2 − COONH 4 + H 2 SO4  → 2C6 H 5CH 2COOH + ( NH 4 ) 2 SO4. o. o. −. 35.. 36.. OH C6 H 5 − CH − CH 3 + H 2O  → C6 H 5 − CH − CH 3 + HCl |. |. Cl. OH. H 2 SO4 ( d ) → C6 H 5 − CH = CH 2 + H 2O C6 H 5 − CH − CH 3  to |. OH. 37..     nC6 H 5 − CH = CH 2  →  − CH − CH 2 −  |    CH   6 5 n. Facebook : Clb gia sư trivietkontum Webside : violet.vn/Clbgiasutrivietkontum. Trang 11.

<span class='text_page_counter'>(12)</span>