Đề thi thử đại học môn Hóa học trường chuyên Chu Văn An, Hà Nội 2011 lần 1 ppt

SO CIAO
DUC
VA EAO
TAO HA
NQI
NN rHr rNff
O4T HQC
LAN TII['
NUAT
rnUoNc rurr cuu vAn
ax
NAM
HgC
2010 -2011
vlolq:
noA
Hoc
(Di
thi
g6m
cd
5 trang)
rn*
ii'n*
ii| io
pn
t,
ivre ae thi 132
Chnbi6t nguyAnfikfuitcilacdcngwyAntij:
H: l;Li:7;
C:

12;N:
gffi
Mg:24;AI:27; P:31;
S:32;
Cl:35,5;
K 39; Ca:40;
Cr:52;
Mn:55; Fe:56;
Cu:
64; Br
:
80; Rb
:
85,5;
Ag
:
108;
Cs
L
1.33;
Ba:
137.
I.
PHAN
CHUNG
CHo TAr cA
cAc THi SINH
(40
cf,u,
tir ciu 1 d6n

cf;u
40).
CAu
1:
Cho so
i10
chuy6n
ho6
sau:
. khi clo, ti lg
mol I :1 NaOH
ddq
du
lIBr
Benzen
___________ ___>
X
_______+
f
_-________-__*
z
Fe,
to
to,
p
Bi6t
X, Y, Z ldc6c
sdn
phAm
chfnh .

Chc
chdtx,Y, Ztrong
so il6 tren
Bn luo.t
ld
A" CrHsCl, CeHsONa,
C6}I5OH,
C. CoHsCl, CeHsOH,
CeHsBr.
B. CeFI+Clz,
C5Ha(ONa)2,
C6FI+(OH)z
D. CeHsCI{zCl,
CoHsCHzOH,CeHsCI{zBr.
Cdu
?:
D6y
cluqc
sip
x6p theo
chidu
giAm
ddn
nhigt ctQ
s6i
ld
A. C2H5CHO,
CgHzOH,
CH3COOH.
B. CH3COOH,

CrHzOH, CzHsCHO.
C.
C3HzOH, CH:COOH,
CzHsCHO.
D. C2HsCHO,
CHgCOOH,
C3H7OH.
Cffu 3; Cho c6c
dung
dich: dung dich
HCI
(X1),
dung dieh
g6m
HzSO+
lodng
vi KNO3
(Xz),
dung
dich
KNOr
(X3),
dgng
dich Fez(SO+)3
(&).
Cdc
dung dich c6 th6
hod tan
hodn todn hdn
hqp

g6m
Cu
vi Fe2O3
(c6
ti lQ s6
mol I : 1) ld
A. Xr, Xz.
8.X2,X4.
C.
Xu,
X:.
D. Xr,
&.
'
Cflu
4: Este tlo'n chtlc
X c6 ti
ttrOi troi so vdi
khi oxi
bing
3,125.
Cho 0,15
mol X t6c dung vla dri
vdi
dung
dich NaOH. Cd can
dung dich sau
phin
img,
thu duo-c

2l
gam
ch6t
rin khan Y. Ch6t Y tac
dung cluoc
vdi
CuO nung
nong sinh ra sAn
ph6m
c6 th€ tham
gia phin
fng tr6ng bpc.
Cdng thric
cdu
tao cria
X ld
"rtr7:o
B. GH2:CHCOOCzHs.
D. CzHsCOOCH:CH2.
o
Cdu
5: MQt h5n
hqp
g6m
kali vd kim lopi kiAm X. Hodtan h6t 12,15
gam
h6n
hqp tr€n
vio
nu6c, thu

duoc 3,78
lft khi Hz
(dktc).
Bi6t
ti
lQ s5 mol
cria
X vd kali
trong
h5n hq
p
nhd hon 119. Nguy6n
tO X h
A.
CHi-CH-ICHrb-C:O.
-
\'
-"7
\o,
A. Na.
B. Cs.
C. Li.
D. Rb.
CAu
6: Cho 4,48
gam
h6n ho.
p
etyl axetat vd
phenyl

axetat
(c6
tt
lQ
s6
mol ld 1:1)
tdc
dung h6t
v6i
800 ml dung
dich NaOH 0,1M, thu
duo.'c
dung dich
X.
CO c4n
dung
dich X,
thu
ituo.c
m
gam
chdt
r[n
khan.
Gi6 tri cria m
ld
A.5,60.
8.3,29.
c.6,40.
D.4,88.

CAu 7:
Thu!
phAn
hodn toan 0,1
mol
este X
(X
tfuo.
c tao
thinh
ttr axit hopc
ancol
don chrlc)
can
ZOO
ml
dung
dfch
KOH
1M. MAt khdc, khi thuf
phdn
10,95
gam
X
cAn vira rtri
8,4
gam
KOH, thu duqc
1}{
gam

mu6i khan. Cdng
th6'c crla X
li
l)(cooczHs)2. B.
c2ll4(coocHr)2.
c. cH(coocHr)r.
D.
(cH3coo)zczril.
Cf,f,
Q:
Cho
khi CO
qua
6ng sri dlrng
0,5
mol h6n
ho.
p
X
gdm
Fe3Oa vd
FezOr
nung n6ng,
thu
dugc
100
gdm
ch6t rin
Y
g6m

4
ch6t.
Hod tan Y trong
luo.ng
du
dung
dfch HNO3
lodng,
thu dugc
ll,2lit
khi
Ndr(san phAm
khir
duy nh6t,dktc).
Phin tr[m vA khtii
lu-o.
ng
cria Fe:O+
trong
X
li
A. 3466%.
8.85,29yo.
C.62,34Yo.
D.4,7fA.
Trang
1/5
-
Ma dA
thi

132
()
^
1S-
\
z
-'
I\ r
e-
'
r\ t',l
L4
(/{h4
:
V
tz-
/J://\*Lu-t
CAu 9: Hdn
hgp X
gbm
2
anclehit.
Cho 0,04
mol
X
phin
rlng
hodn
todn v6i luqng
du

dung
dich
AgNO3
trong
t Ii{,
Oun
n6ng,
thu tlu-o.
c 11,88
gam
Ag.
Mat kh6c, n6u d5t
cnay hodn toin 0,04 mol
X
trJng khi o*i
thi thu
dugc Z,OrcVtkhi
CO2
(dktc).
Hai
andehit trong X
g6m
Ciu 10: Trong
quf
trinh itipn
phdn dung dlch
NaCl
(v6i di$n
cqc
trq

ming
ng[n xdp),
O catot xiry
n
A. s1r khrl
ionNa*.
B.
sg oxi ho6
ion Na+.
C. s1r khtr
phdn
tu I{zO.
D.
sg
oxi ho6
phdn
tti H2O.
CAu
11: Cho
c6c chAt: C+Hro, C4H16O,
C+HgCl,,C+HirN.
ChAt c6 s6 e6ng
phdn
c6u
tpo nhiAu
ntrAt h
A. CH3CHO
vd CzHsCHO
C.
(CHO)2

vi CHTCHO.
A. CaHro.
B. C+Hr
rN.
A.6,6.
8,7,7.
A. axit a-aminoisovaleric.
C. axit
p-aminopropionic.
,4,.
AgNO3 vdAu(NO:):.
C.
Fe(i.{O:):
vd Mg$.{Og)2.
B. HCHO vd CH:CHO.
D.
HCHO vd. CzHsCHO.
C. C+HroO.
D. C4HeCl.
c.5,4.
D.4,4.
B. alanin.
D.
glyxin.
B. MgO{Og)2 vd
Cu(t'{O3)2.
D.
CuQ'{O:)z vd AgNOr'
CAu
12: Cho

a
mol
h6n hqp X
g6m
H2,
CzHz,
CzH+
(s6
mol CzI{z
bang
pO
rnol CzFI+)
di
qua
xfc
tr{c
Ni nung n6ng
d6n khi
c6c
pfran n'ng
yhy
rahodn
todn,
thu
duo.'c
Ll,Zlith6n
hgp khi
Y
(dktc).
Ti khgi

cria Y so
v6'i
khi hidro
bing
6,6. N6u
cho a mol
h6n ho.p
X vio lugng du
dung dich
brom, thi
kh6i
luo.
ng blnh
dyng dung
dich brom
tdng m
gam'
Gi6 tri
cria m
ld
Cfiu 13;
HoiL
tan
htit
m
gam
A12(SOa): vdo
nu6c,
thu, dugc
dung dich X.

Cho
220
ml
dung
dich
NaOH
iM vio
X, thu du,gc
a
gam
k6t tfia. M{t
kh6c,
ntiu
cho 60 ml dung
dich NaOH lM
vio
X thi
cflng thu duo.
c a
gam
k6t tria.
Gi6
tri ctra m
ld
A.8,55.
B.10,26.
c.5,13.
D.
17,10.
CAu

14; Hdn h$,p
X
(c6
ti kh6i
so v6i khf
hidro
bing
3,6)
gOm
Nu vd
Hz.
Sau khi
ti6n hdnh
phen
fng
t6ng hqp u-oniu",
clugc h6n
hqp Y
c6 ti
khdi so
vdi
khf hidro bing
4.
HiQu
suAt cria
phin
rtng
t6ng
ho-p amoniac
ld

A. 15%.
8.250h.
c. r0%.
D.20%.
Cflu 1.5: Cho
V lit khi
CO2
(dktc)
h6p thg
hodn
toin
vdo
200 ml
dung dich
Ba(OH)2
0,751\4
thu
ducr. c
27,58
gamkiSt
tria.
Gi6 tri cria V
ld
A. 3,584.
B. 3,136.
C.
3,136
ho{c
2,688. D. 3,584
ho{c 3,136.

CAu
16:
Cho
0,1 mol arninoaxit
X t6c
dgng
vtra dri
vdi 80
ml dung dlch HCI
1,25IvI,
lim bay
hoi
dung dich,
thu
clury. c 12,55
gam
mu6i
khan.
fhi .no X
t6c
dgng
vdi
glyxin
thi thu
duo. c
sdrn
ptrAm
ta
dipeptit. TOn
ggi

cta
X ld
Cflu 17: MOt h6n
hqp X
gd;m
axetilen
vd andehit
axetic
c6 ti kh6i hoi so
vdi khf
hidro
bing 17,5.
Cho
0,2
mol h$n
hqp
X
vbo
to-qng
du
dung dich
AgNO3
trongNHr,
thu
dugc m
gam
k6t
tua.
Gi6
tr! crla

m
le
4.45,6.
B.4&.sb C.21,6.
D' 16,2'
Cflu
18r Cho
c6c chAt
sau: f6
ftCilNaOil,
g{$a)zCor.
Khi
cho c6c chht
tr6n
phf,n
img
vdi
nhau
tirng cldi m6.t
(trong
dung d!ch)
th-l@et-ao-nhi6u
ch6t khf?
A.6.
8.5.
c.3.
D.4.
Ciu 19: M6t rnflu
chAt b€o X
c6 chi s6

axit
bing 7
chrla tristearin
c6 lln mQt
lugng axit
stearic.
Chi
si5
xd
phdng
ho6 cria
m5u
ch6t b6o X
ld
a. 191.
B. 189.
c.182,
D.200.
Cflu 20:
Cha 62,42
gam
hdn
hqp
X
g6m
BaClz
vd
CaClz vlo I
lit dung dich
Y

gdm
hdn hqp
KzCOr
0,2M
vd
61r1110)2CO:-0,25M,
thu duqc 57,58
garn
kiit tUa.
PhAn tr[m vA ttrOi
lugng
cria
CaCl2
trong
X
le
A.53,35%.
8.44,17Yo.
c.55,83yo.
D,46,65ya.
Cf,u
21:
Nhi-6t
phdn hodn toin 2 mu6i
nitrat,
thu
dug'c
ch6t rfn
X.
Ni5u cho X

t6c
dgng
vdi
luqng
du
dung dich HCI
iodng thi
th6y X tan
mQt
phdn. Hai muSi
nitrat et6 li
Cda22:
Phdn
supephotphat
kdp thuc
t6 s6n
xuAt
dugc
thudng chi
ri'ng
vli 40,0Yo
PzOs.
Phdn
trdm
vA
khdi luqng cfia canxi
dihidrophotphat
trong
ph6n
b6n

d6
ld
D.65,920/o.
Trang2ll
- Me dA
thi
132
A.71,32Yo.
B.73,llYo.
C.69,0tYo.
Ciu
23:
Dung
dich duo"
c
dirng
d6
ldm
mAm nudc
c6
tfnh
crtng
vTnh
criu
gdy
n6n bdi c6c mu5i Caclz,
CaSO+
ld
A.
Ca(OH)2. B. Ca(HCO3)2. C.

Na2CO3.
D. BaClz.
Ciu24:
Cho
phdn
rlng
ho6 hgc sau
Al
+
HNO3
-+
Al(NOr)r
+
NzO
+
NO
+
H2O.
giist
U l$ n",o irNo: 3
:4.
Sau khi c6n bdng
phucmg
trinh
ho6
hgc tr6n
v6'i
h9 s5
h nhfmg
s5 nguy6n

t6i
gian,
thi hg s6
cria HNOg
ld
A. 10.
B. 8. C.46. D. 36.
CAu 25:
Cho
c6c
nguy6n trl X(Z:1 |),Y(Z:12),T(Z=19).
Ddy
duo-c x6p
theo
chiAu
ting
dAn bdn kinh
nguyOn
tu
ld
A.
Y,
X, T. B.
X,
Y,
T.
C. T, X,
Y.
D. X, T, Y.
Chu26: C6u hinh electron l6p ngodi cirng ctra ion

X2'ld 3s23p6.
Nguy6n
t6
X thuQc
A. chu ki 3, nh6m VIIIA.
B. chu ki
4, nh6m IIA.
C. chu ki 3, nh6m VIA" D.
chu ki 3, nh6m
IVA.
Cdt-27z Day
gdm
c6c
loai to t6ng
hgp
ln
'
A. to
capron,
to axetat,
nilon
-6,6.
B.
to tim,
xenlulozo,
nilon
-6.
C. nilon-6,
to
visco, to'nitron.

D. to nitron,
to capron, nilon-6,6.
Ciu
28:
Trong mQt binh
kfn c6 c6n bing ho5
hgc sau:
H,
(k)
+
12
(k)
GJ
2HI
(k);
AH
:
51,88 kJ.
CAn bing ho6
hoc trdn sE chuytin
dich theo chiAu
thu$n
khi
A. cho
th0m
chAt xtlc t6c.
B. t[ng ndng
dQ crla HI.
C. ting 6p
su6t

chung bing
c6ch
giim
dung tich binh.
D.
tdng ndng dQ cria
Hz hoflc 12.
Cf;u
29: Thuf
phin
khOng
hodn
todn
pentapeptit
mpch hd X, thu duo.c h6n hgp
sin
phAm
chria
c6c
dipeptit
Ala-Gly, Gly-Ala vd tri
peptit
Gly'Gly-Val.
Trflt tU sip x6p c6c aminoaxit
trong
pentapeptit
Xb
A.
Gly-Gly-Val-Gly-Ala. B.
Gly-Ala-Gly-Gly-Va1.

C.
Val-Gly-Gly-Gly-Ala.
D. Ala-Gly-Va1-Gly-Giy.
CAu
30: C6ng
thric
ph8n
tri'cfia
mdt
hA"p chAt htu
co'X
ld
CgHroN2O3.
Dun
n6ng
18,3
gam
X
v6i mQt
lugng
vila
dri dung dich
NaOH,
thu duo. c dung dich Y. CO
cAn Y, thu duo. c
phAn
hoi chrla
hqrp
chAt
htu co

Z c6banguy€n trl
cacbon vd
cdn lpi a
gam
ch6t ran khan.
Gi6
tri
cria
a
li
A.L2,75.
B. 16,65.
C.14,40.
D. 11,65.
Cflu 31: Tr$n
3 dung dich HCI 0,3M, HzSO+
0,2M vi HNO3 0,3M
v6'i
tir,5 tictr
bi'ng nhau,
thu duqc
dung
dlch X. D6 trung hod
300 ml dung
dich
X
cAn
ding V ml
dung dich
gdm

h6n
hqp NaOH
0,lM
vi Ba(OlIlz
0,2M,
thu
iluo. c dung dich Y c6
pH
=
13.
Gi6 tr!
cta V li
A.200.
8.325.
C.300. D.375.
Ciu 32:
Thu!
phAn
hodn todn 31,25
gam
dung dich
saccarozo
l3,68yo
trong
m6i truhng
axit,
thu
du-oc
dung dich X. Trung hod X bing dung
dich NaOH,

sau d6 cho tiSp
lugng du dung
dich
AgNO:
trong NH3
dun n6ng nhg, sau khi c6c
phin
rlng xAy ra
hoin todn thi kh6i
lu-o.
ng
Ag thu ttugc ld
A.2,565
gam.
8.2,700
gam.
C.
5,130
gam.
D.
5,400
gam.
Cf;u 33:
Cho 0,la mol Fe
vdo
250 ml dung dich
AgNOr a molll
(H
=
100%), thu

dugc
dung dich
X
A.
chi c6
Fe(NO3)3'
B.
BQm
Fe(tlO3)2 vd AgNO:.
C. chi c6
Fe(NO3)2.
D.
g6m
Fe(NO:)r
vd
Fo(NO:)2.
Cflu 34: Cho
c6c ch6t:
CzHo, C2Ha,
CH3CHO, CHgCooCH:CH2. So ch6t
phri
ho.
p
v6'i X
theo so dd
CzHz-+
X
-+Y
-+CHECOOH
ld

A.4. 8.3.
C.2.
D. 1.
Ciu 35:
56
edng
phdn
c6u tao thuQc
lopi hgp ch6t
thom c6 cdng thric
phdn
trl CgHrz
li
A.5-
8.8.
C.9. D.2.
Cflu 36: ThC
tich khi Cl2
(dktc)
sinh ra nhiAu
nh6t khi
cho luo-ng du
dung dich
HCI
d[c
vdo
m
gam
A.
MnO2,

dun n6ng. B. KMnO+.
C.KzCrzOt
D. KClOr.
Trang3l5
-
Ma dA
thi 132
Cflu 37: Cho
c6c
ch6t
h
dbng
phdn
cAu
tao
d4ng
mpch
hd
cria CzH+@.ldn
luE
t6c dung
vdi Na,
NaOH, NaHCO:.
S6 ttri nghiQm
x&y ra
phin
fng
ho6
hgc
ld

L.7.
8.5.
A.
1,0.
B. 0,8.
CuClz.
56
trub'ng
hgp
xAy ra
sg
[n mdn
diQn
ho6li
A.
1.
8.2.
Cflu
40: Cho V
lit khi CO2
(dktc) h6p thg hodn
toin
vdo
250
ml dung
dich
NaOH
2M,
thu
duo.

c dung
dich
X. Cho
luo. ng du
dung
airfr
buifr
vio
X, thu duo.
c 39,4
gamtrtit
tua.
Gi6 tri
cria
V ld
A.4,48
hoac
8,96.
-p.6,72
ho6c
8,96.
C.4,48
ho[c
5,60.
D. 4,48
ho6c
6,72.
rr. PHAN
RrtNG
[10

caul
Thi sinh
chi
cluqrc chqn
mQt
trong hai
phin
tptttl
ho[c_B)
A.
Theo chuang
trinh
ChuAn
(10 cAu,
tir ciu
41
cl€n
cAu 50).
Ciu
41: Cho
4 thanh
sit
nguy€n
ch6t
vao
c6c
dung
dlch
sau:
FeCl:,

HCl,
CuSO+,
HCI
c6
l6n mQt
it
c.3.
c.0,5.
c.4.
D.0,4.
D.3.
D.8.
Cflu 38: M6t
h6n ho.p X
gdm
hai
anken ld
ddng
ding.k6
ti6p cria
nhau.
Cho 1,68
gam
X
phin
fmg
vila
hiit
v6{
8

gam
Urom
trong
dung dich. M{t
khi4c,
ntiu
hiclrat
ho6
hodn
todn 1,68
gam
X,
thu
du-ry. c
h6n hqp *"oiy.
Cho Y
phan ung hodn
todn
vdi CuO
nung
n6ng
thu tluqg
h6n
hqp Z. Cho
Z vdo
luqne
du
dung
dlch
AgNO3

trong
NH3
dun
n6ng,
thu
tlugc 7,56
gam
Ag
(bi6t
rlng c6c
phan
img dat
hiQu suAt
lO0%).
Phdn trim
leir6i lugng
cua ancol
b6c
2 trong Y ld
A. 19,58%.
8.34,88%.
'
C.
ll,63yo.
D' 18,34%'
C6u
39: Cho
1 1,34
gambqt
Al vdo

300
ml dungcilch
hdn ho.
p gdm FeCl3
1,2M.vd
CuClz
aM,
sau
khi
c6c
phin
rlng xiy
,u-ho*
toan,
thu
dugc
dung
dich
Xvd26,4
gam
h6n
ho.
p
g6m
2 kim
lo+i.
Gi6
tri
ctla a
ld

Ciu
42: Hoi
tan
hoin
todn h5n
h-o.p
gdm 0,02 mol
FeS2
vd
0,03
m91
Fe.S
vdo
lugng
du
d]1e-dich
HzSO+
d6c,
n6ng
thu
duo. c lrhf
SOz
(san
phAm Lhri
duy
nh6t
cua
5*6;.
Hdp
thp

hodn
todn
SOz
blng
luqng
yrra
An aung
Oich
fUnO+,
thu
cfuo-i
V
lit dung
dich
khOng
mdu
c6
pH:2' Gi6
tri
cfia V
ld
n. tt,+.
B.
17,1.
c.22,8.
D. 16,8-
Cf,u
43:
Cho
tir

tir
di5n
du
dung
dleh
NHr
vio
cdc
dung
dich
ri6ng
biQt
sau:
Fe(NO3)3,.2n(l'{.O3)2,
AgNO3,
Al(NOg)r,
Cug{O3)2,
NiSOo.
Sau
khi
tiitttilic
phin
irng,
s5
thf nghiem.thu
dugc
k€ttria
li
A.2.
8.3.

c.5.
D'
4'
CAu
44: Cho
r6t tir
tir 250
ml
dung
dich
HCI
lM
vdo
100
ml dung
dich
hdn
hqp
g6m
NazCOr
a
mol/l
vd
KHCO,
b
mol/I,
thu
duo.
c z,z6
rc khi

(dktc) vd dung
dich
X. cho
lu-o.
ng
du
dung
dich
ca(oH)2
vdo
dung
di"h
x,
thu dugc
5
gam
kct
tria.
Gi6
tri cfia
a vd b
ldn
luqt li
A. lM
vd 0,5M.
n.
zvr vd
2M.
c.
lM vd

1M.
D.
1,5M
vd 2M.
ciu
45:
Thu6c
thrl
duo.c
dnng
d6
phan biQt
c6c
dung
dich
ri6ng
bigt
Nll4cl,
MgCl2,
0{H+)zso+,
A1Cl3,
FeClz, FeClg
li
a Oung
dich
NaOH.
B'
dung
dlch
HCI'

C.
dun[
dich
BaClz.
D'
dung
dich
Ba(OH)z'
cf;u
46:
H6n ho.p
X
gom
.2
axitcacboxylic
no,
m4ch-ho.
9ot
ch6y
hoantgal-O:3
mol
X,
thu
dugc
Il,Z
litkhi
COz
t6f.Li.
lj6
t*ng

ftoa
0,i
mol
X
c6n
dirng
500
ml dung
dich
NaOH
1M'
COng
thtc
cria
2 axit trong
X ld
A.HCooHvd(Cootf)2.B.CHlCooHviCzHsCooH.
C.
HCOOH
va
CzHsCOOU.
D'
CFI3COOH
vd CH2(COOH)2'
c1u
41tph6n
ti' kh5i
trung
binh
ctra

nilon-6,6
lit2g832.
sd mit xfch
trung
binh
ctra
polime d6
ld
L.125.
9.132.'
c'
155'
D'264'
cau
48:
Thuoc
thrl
dugc
dnng
d0
phan biQt
c6c
dung
dich
ri€ng
biet:
NaoH,
Ala-Gly,
Gly-A-la-Gly
ld

A.
dung
dich
CuSO+.
n Oung
dich
BaClz'
i'
CulOU;t'
D'
dung
dich
CaClz'
CAu
49:
Dun
n6ng
anccl
don
chf'c,
m4ch
h6'X
v6'i
HzSO+
ddc,
6 nhiet
dQ
thich
hgp,
thu

duqc
mQt
chft
hnu
co Y.
Ti
khSi
hoi
cria
y
so
vOiX
bing
1,7.
Cho
X t6c
dgng
vdi
CuO
ilun
n6ng
t*o
ra
chit
hfl.u
co.Z
c6 th€
tham
gia
phf,n ri'ng

tr*ng
b4c.
c6ng
thti'c
cin_X
ld
A.
(CH3)2CHOIL
B.
CH3CH2iH2OH'
c'
cH3oH'
D' CzHsoH'
Ciu
5b:
Cho so'dd
chuY6n
ho6
sau:
Trang4/5
-MadCthi
132
1800C, H2So4 d4c H2O, H2Soa
lodng,
to
Cuo,
t0
cI{3cH2cH2oH
+
X

*
y
(sin pham
chfnh)
+
z
ChiitZtrong sCI dO
trCn la
A.
CH3CHO. B.
CH:CHzCHO.
C. CI{3CH2COOH.
D.
CI{3COCH3.
B. Theo
chuong trinh
Nflng cao
(10
cfiuo
tir cAu 51 d6n cflu 60).
Ciu
51: ChAt X
ln mQt
disaccarit duoc
t4o boi 2
g6c
o-glucozo
li€n ktit
vdi
nhau boi liOn ki5t CI-1,4-

glicozit.
ChAt
X khdng
thd tham
gia phAn
rlng
A. thuy
phAn
trong
mdi trudng
axit.
B.
vdi CH:OH
(HCl
khan ld
xric tilc) theo ti'lQ.mol nx :nca,oa
:
I
:2.
C. vdi dung
dich
AgNOr trong NH3.
D. hodtan
Cu(OH)2
o nhi$t
dQ
thucrng.
Ciu 52:
Cho
h6n hgp

gdm
a
mol CuSO+ vd
b mol KCI vdo
nudc
(du),
thu dugc dung
dich
X. DiQn
phdn
dung dlch X
vfi dign cgc tro vd mdng ng6n
xdp,
thu
dugc mQt dung
dlch c6 th6 hoa
tan
AlzO:.
Mdi
quan
h0
gifta
a
vd
b li
A.b<2a.
B.b>2a.
C.b>2aho{cb<2a.
D.b:2a"
Cflu 53: Cho

dung
dich
X chfa
h6n hqp
g6m
NHr
0,1M
vi
NH+CI 0,lM.
ni6t O ZSOC hing
s5
phin
li
bazo criaNH3 ld 1,8.10'5
vi bo
qua
sU
pnan
U cfa
nudc. Dung dich
X
c6
gi6
tri
pH
O ZSoC
bang
A.2,875. B. 11,125.
C.9,255.
D.4,745.

Cflu
54: Hod tan hodn
todn
a
gam
FeSO+"7HzO vdo
nudc,
thu
tluqc I.lit dung
dich X.
Ldy 250 ml
dung
dlch
X
cho
th6m
dung dich
HzSO+ lodng ldm m6i
tru'dng r6i chudn dQ
b[ng
dung dich KMnO+
0,lM
thi dtng
vla tri5t +O
ml
dung dich. Gi6
tr! cria a
ld
L.12,16.
B. 37,80.

C.
5,56.
D.22,24.
Cdu 55:
Phenol CoHsOH
khdng tdc dgng v6i
t6t ctt
citc
chlit
trong d6y:
A.
CH3COOH, CzHsOH,
HCl.
B. Brz
(dung
dich), H2, NaOH.
C. Na NaOH,
(CH3CO)2O.
D.
CH3COCI,
(CFI3CO)2O,
HNO:.
CAu 56: Cho
so'dd chuyCn
ho6 sau:
HCN H2SOa lodng,
to
HzSO+ d{c,
to
CH:-CH=O

*
X
+
Y +
Z.
C6c chAt htu
co X,Y,
Ztrong
so db
tr6n lin
luqt li
A. CH3CH(OH)CN, CH3CH(OH)COOH,
CHz=gHaOO".
B.
CHrCH(OI!CN, CH3CH(OH)COONru,
CHt=61taOONH+.
C. CH3-CH2-CN, CH:CHzCOOH,
CHz=CHCOOH.
D.
CHr-CHz-CN,
CHTCHzCOONH4,
CHr:gltaOONH+'
COu 57: Dung dfch
ndo
sau ddy c6
the hodtan
hodn
todn
1,92
gam

Cu?
A.
dung dich
HzSOq lo6ng,
du c6 hoi
tan
0,32
gam
khi oxi.
8.200
ml
dung dich
gdm
HzSO+
0,175M viNaNOr
0,1M.
C.
200
ml
ciung dich
g6m
HzSO+
0,2M vd
KNOr
0,l5M'
D.200
ml dung
dich Fe2(SOa)3
0,1M.
CAu

58:
Ddy
gdm
cdc chht khi
tdc dgng
v6i dung
dlch
gdm
NaNOz vd
axit
axetic
dAu sinh ra
khi
Nz
le
A.
glyxin,
etylamin,
anilin.
B.
glyxin,
dimetylamin,
alanin.
C. etylamin, dimetylamin,
anilin.
D. anilin,
glixerol,
etanal.
Ciu 59: OA tacn Al(Of& ra
kh6i h6n h-o'p

gOm
AgCl,
AI(OH), Zn(OH)2,
Ni(OH)2
ngudi
ta
dtng
lugng du
A. dung dich NH3.
B.
dung dlch NaOH.
C.
dung
dich HCl.
D.
dung dich Ba(OlDz.
C0u
60: Thutic thrl kh6ng
th6 dnng
d6
phdn
biQt
propanal vd axeton ld
A. dung dich KMnO+.
B.
nu6c brom'
C. dung dich
AgNO3
trong NH3.
D.

Cu(OH)2 o
nhiQt
d$
thud'ng.
Trang 5/5
-
Ma dB
thi 132