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LTĐH Tổng hợp Hữu cơ

1

 Trong một vài năm gần đây, đề thi hóa học có phần khó hơn các năm trước-đặc biệt khó ở các câu lý thuyết.
Đối với các câu hỏi lý thuyết thì ngoài việc nắm vững kiến thức về tính chất, hiện tượng, phương trình…Các em
cần “ tỉnh táo” đọc thật kỹ và phân tích câu hỏi sẽ giúp các em phá bẫy gài trong các câu hỏi.

 Nhằm hướng kỳ thi tuyển sinh ĐH- CĐ 2012, Tài liệu tổng hợp lý thuyết hóa vô cơ giúp các em bước đầu làm
quen và dần trở thành phản xạ với các dạng câu hỏi lý thuyết hữu cơ đếm, đúng-sai…Tài liệu được tổng hợp từ
diễn đàn học tập và các đề thi thử từ các năm của các trường
THPT trên cả nước. Hi vọng với bộ tài liệu này sẽ giúp các em tự tin hơn trước kỳ thi ĐH-CĐ đang tới gần.


Chúc các em thành công !
Vi Nhân Nan

Câu 1.

 : propen ; isobutilen; propin, buta-1,3- stiren 
 
A. 5 B. 6 C. 3 D. 4
Câu 2.

-metylbutan-2-
A. 2-metyl but-2-en B. 2-metyl but-1-en C. 3-metyl but-1-en D. Pent-1-en
Câu 3.

-(CH


2
)
4
-
1

Y
2

1

8
H
14
O
4

A. C
2
H
5
OH B. CH
3
OH C. CH
3

2
H
5
OH D. C

3
H
5
OH
Câu 4.

- :
A. cacbonyl B.  C. amin D. cacboxyl
Câu 5.


 
NaOH
X
1

 
 duHCl
X
2

2

A. H
2
N-CH
2
-COONa B. H
2
N-CH

2
-COOH C. ClH
3
N-CH
2
-COOH D. ClH
3
NCH
2
COONa
Câu 6.

Câu 6.  
3
COOH, CH
3
OH,
C
3
H
5
(OH)
3

3
CH=O.
A.  B. 
3
, dd AgNO
3


3

C. 
2
D. O
3

3

Câu 7.


[- NH-(CH
2
)
6
- NH-CO - (CH
2
)
4
- CO-]
n
(1); [-NH-(CH
2
)
5
-CO -]
n
(2) ; [-NH-(CH

2
)
6
- CO-]
n
(3) ;
[C
6
H
7
O
2
(OOCCH
3
)
3
]
n
(4) ; (-CH
2
-CH
2
-)
n
(5) ; (-CH
2
-CH=CH-CH
2
-)
n

(6) .

A. (5); (6) B. (4); (5); (6) C. (1); (2); (3); (4) D. (3); (4); (5); (6)
Câu 8.


4
H
6
O
2
. Y



A. HCOO-CH=CH-CH
3
B. CH
2
=CH-COOCH
3
C. HCOO-C(CH
3
)=CH
2
D. HCOO-CH
2
-CH=C
Câu 9.



3
H
7
O
2
N. 
1

2
H
4
O
2
NNa. 
 :
A. H
2
N-CH
2
-COOCH
3
B. H
2
N-CH
2
-COOCH
2
CH
3

C. CH
3
-CH(NH
2
)-COOH D. CH
3
-CH
2
COONH
4

Câu 10.


8
H
10
O
2


8
H
6
O
2

A. 4 B. 5 C. 3 D. 2
Câu 11.


 : axit axetic (1) ; axit acrylic (2) 
 
A. (2) < (3) < (1) < (4) B. (3) < (1) < (2) < (4) C. (3) < (4) < (1) < (2) D. (1) < (2) < (3) < (4)
Câu 12.


2

1
; X + O
2

2
; X
2
+ X
1

6
H
10
O
2
+ H
2
O.  :
A. CH
3
CH=O B. CH
3

CH
2
CH=O C. CH
2
=C(CH
3
)-CH=O D. CH
2
=CH-CH=O
Câu 13.



2

A. 1,2- B. 1,1- C. 1,1,2,2-tetraclo etan D. 1,1,1-triclo etan
Câu 14.



2

3
/NH
3


A. -CH=O B. 
3
CH=O

C. O=CH--CH
2
-CH=O D. CH
3
--CH
2
-CH=O
Câu 15.


2
SO
4


A.  B. 


LTĐH Tổng hợp Hữu cơ

2

C.  D. 
Câu 16.


5
H
10


4


5
H
12
O
2


A. But-2-en B. But-1-en C. 2-metyl buten-2 D. 2-metyl but-1-en
Câu 17.


2
 - alanin.

A. H
2
N-C(CH
3
)
2
-COOC
2
H
5
B. ClH
3
N-CH(CH

3
)-COOC
2
H
5

C. H
2
N-CH(CH
3
)-COOC
2
H
5
D. ClH
3
N-CH
2
-COOC
2
H
5

Câu 18.


3
/ NH
3
 ?

A.  B. 
C.  D. 
Câu 19.

 : X (C
x
H
y
Br
z
) + NaOH (t
0


A. C
6
H
10
Br
4
B. C
6
H
8
Br
2
C. C
6
H
6

Br
2
D. C
6
H
8
Br
4

Câu 20.


(X) + dd NaOH (t
0
 (1); 
0

4
+ (P) (2)
CH
4
(t
0

2
(3); (Q) + H
2
O (xt, t
0
 (4)


A. CH
3
COOCH=CH
2
CHO B. HCOOCH=CH
2

C. CH
3
COOCH=CH
2

3
CHO D. CH
3
COOC
2
H
5

3
CHO
Câu 21.



A. 4 B. 5 C. 6 D. 3
Câu 22.



3
H
9
O
2


A. HCOONH
2
(CH
3
)
2
B. CH
3
COONH
3
-CH
3
C. CH
3
CH
2
COONH
4
D. HCOONH
3
-CH
2

CH
3

Câu 23.

 : benzen
(1) ; toluen (2); p-
A. (4) < (1) < (2) < (3) B. (1) < (2) < (3) < (4) C. (4) < (1) < (3) < (2) D. (3) < (4) < (1) < (2)
Câu 24.


2
SO
4

0

 : nCO
2
: nH
2
O = 0,25 : 1 : 

A. CH
3

2
H
5
OH B. CH

3

2
=CH-CH
2
OH
C. C
2
H
5

2
=CH-CH
2
OH D. C
2
H
5

2
=CHOH
Câu 25.


3
H
6
O
2


3

3
,t
0


0

A. HO-CH
2
-CH
2
-CH=O B. CH
3
-CH
2
-COOH C. CH
3
-CH(OH)-CH=O D. HCOO-CH
2
CH
3

Câu 26.

 
3
/ NH
3

thu

A. 2 B. 4 C. 1 D. 3
Câu 27.   

A. CH
4
. B. C
2
H
6
. C. C
3
H
8
. D. C
4
H
10
.


Câu 28. 
2
. 
A. C
2
H
4
.


B. C
4
H
8
. C. C
3
H
6
. D. C
5
H
10
.
Câu 29. 
A. metylamin. B. etylamin. C. pentylamin. D. phenylamin.
Câu 30. 
(1) NH
3
, (2) CH
3
NH
2
, (3) C
6
H
5
NH
2
,

(4) (CH
3
)
2
NH, (5) C
2
H
5
NH
2
, (6) p-O
2
N-C
6
H
4
NH
2
.
A. 6, 3, 1, 2, 5, 4. B. 3, 6, 1, 2, 4, 5. C. 4, 5, 2, 3, 1, 6. D. 1, 2, 3, 4, 5, 6.
Câu 31. 
3
)
2
CHCH(OH)CH
3
 
A. 2-metylbuten-1. B. 2-metylbuten-2. C. 3-metylbuten-1. D. penten-2.
Câu 32. C
4

H
8
-
-2----2-

A. 2--2. B. 2-.
C. buten--2. D. buten-
Câu 33. :
 Metylamin (2), Amoniac (3),
Anilin (4), p-metylanilin (5), p-nitroanilin (6).


LTĐH Tổng hợp Hữu cơ

3


A. (1), (2), (3), (4), (5), (6) B. (3), (2), (1), (4), (5), (6)
C. (6), (4), (5), (3), (2), (1) D. (6), (5), (4), (3), (2), (1)
Câu 34. 

A. Na. B.  C.  D. 
2
.
Câu 35. 
6
H
5
NH
3

 
 
2
.
C. 
3
, NaOH, Br
2
. 
3
, Br
2

Câu 36.  
CH
3
OH(1), C
2
H
5
OH(2), CH
3
COOH(3), CH
3
COOC
2
H
5
(4), HCHO(5).
A. 5, 4, 1, 2, 3. B. 1, 2, 3, 4, 5. C. 5, 4, 3, 2, 1. D. 3, 2, 1, 5, 4.

Câu 37. Tron
8
H
10

  
 
 OH
2
(Y)
 
xtpt ,,

A. 1. B. 3. C. 4. D. 2.
Câu 38. 


A. C
7
H
8
O. B. C
8
H
10
O. C. C
9
H
12
O. D. C

10
H
14
O.
Câu 39. 
3
H
4
O
2
, C
3
H
6
O
2
, C
4
H
6
O
2
, C
4
H
8
O
2
 


A. C
3
H
4
O
2

4
H
8
O
2
. B. C
3
H
4
O
2

4
H
6
O
2
. C. C
3
H
4
O
2


3
H
6
O
2
. D. C
4
H
6
O
2

4
H
8
O
2
.
Câu 40. 
2
(OCOC
17
H
33
)-CH(OCOC
15
H
31
)-CH

2
(OCOC
17
H
29

2


A. 1. B. 3. C. 4. D. 5.
Câu 41.  
A. CH
2
=CH-COOCH
3
. B. CH
2
=CH-COOH. C. CH
2
=CH-COOC
2
H
5
. D. CH
2
=CH-OCOCH
3
.
Câu 42. 
  len (3); 

 Nilon-6,6 (6); 
 
A. (1), (2), (3). B. (2), (3), (4) C. (1), (4), (5). D. (4), (6), (7).
Câu 43. 
2
O
o
axit,t


 
   
Câu 44. 
 B. phenolphtalein.  
Câu 45. 
2


A. 4 B. 6 C. 5 D. 3
Câu 46. 
a) 6X
xt

Y b) X + O
2

xt

Z c) E + H
2

O
xt

G
d) E + Z
xt

F e) F + H
2
O
H


Z + G.

A. 
B. 
C. 
2
O trong NH
3
.
D. 
Câu 47. S 
4
H
9
NO
2
  

A. 2 B. 3 C. 4 D. 5
Câu 48. --


C. 
3
/NH
3


4
.
Câu 49. 

A. pentan. B. xiclopentan. C. 2- metylbutan. D. 2,2-.


LTĐH Tổng hợp Hữu cơ

4

Câu 50. 
 

A.CH
2
H
2
. B. CH
3


3

C. HCOOCH=CHCH
3

3
CH=CHCOOH D. CH
2
=CHCH
2

3
COOCH=CH
2

Câu 51. 
2

t
A. 2 B. 3 C.4 D.5
Câu 52. 

A. H
2
NCH
2
COOH B.H
2
NCH(COOH)

2
C. H
2
NCH
2
CH
2
COOH D. H
2
NCH
2
CH(COOH)
2

Câu 53. 
2
CO
3


3
/NH
3

A. HCOOH B. HCOOCH
3
C. HCHO D. CH
3
COOH
Câu 54. 



A. 15,1 gam. B. 16,1 gam. C. 17,1 gam. D. 18,1 gam.
Câu 55. 
2


2

2
O trong dun
3
sinh

A. HCOOC
2
H
5
B. C
2
H
5
COOH C. HOOC-CHO D. HOCH
2
CH
2
CHO
Câu 56. 
A. CuO(t
o

) ; Ag
2
O/NH
3
B. CH
3
COOH; NaOH C. H
2
SO

(170
o
C) D. O
2
(men gi
Câu 57. Cho H
2
SO
4



2
SO
4
. 
2
. 
2
. 

2
S.
Câu 58. 
A.  B. etyl sec-
C.  D. 
Câu 59. 
A. Axit no. B. Axit   
Câu 60. 
A. H
2
SO
4
 B. H
2
SO
4
 C.  
Câu 61. 
 B. 
 D
Câu 62. 
6
H
14

2
SO
4

o


A. 2,3--2. B. 2,3--1.
C. 2-metyl pentanol-3. D. 3,3--2.
Câu 63. 
4
H
8

brom 2-metyl propan 
A. 2--2. B. 2-
C. buten--2. D. buten-
Câu 64. 
2
, (2) Ag
2
O/NH
3
, (3) H
2
/Ni, t
0
, (4) H
2
SO
4


A. (2), (3), (4). B. (2), (4). C. (1), (2), (4). D. (3), (4).
Câu 65. 


A. 609,83 kg. B. 619,83 kg. C. 629,83 kg. D. 639,83 kg.
Câu 66. 
6
H
6

 
. 
Câu 67.  
2
, 6,3 gam H
2

2



A. CH
3
COOCH
2
NH
2
. B. H
2
NCH
2
COOCH
3.
C. CH

3
CH(NH
2
)COOCH
3
D. H
2
NCH
2
CH
2
COOCH
3

Câu 68. Cho 1,47 gam

-

A. H
2
NCH
2
COOH. B. CH
3
CH(NH
2
)COOH.
C. CH
3
(CH

2
)
4
CH(NH
2
)COOH. D. HOOCCH
2
CH
2
CH(NH
2
)COOH.


LTĐH Tổng hợp Hữu cơ

5

Câu 69. 
3
-CH=CH
2,
CH
2
(OH)CH
2
(OH), NH
2
-CH
2

-COOH, CH
2

 
A. HO-CH
2
-CH
2
-
2
-CH
2
-COOH. B. HO-CH
2
-CH
2
-
3
-CH=CH
2
.
C. CH
2

3
-CH=CH
2
. D. CH
3
-CH=CH

2

2
-CH
2
-COOH.
Câu 70. 
  len (3), (4),
  -6,6 (7).

A.(2), (3), (4), (6). B. (1), (2), (5). C. (1), (4), (6). D. (2), (3), (5), (7).
Câu 71. 
3
)
2
CHCH(OH)CH
3


A. 2-metylbuten-1. B. 2-metylbuten-2. C. 3-metylbuten-1. D. penten-1.
Câu 72. 
7
H
8

A. 2. B. 3. C. 4. D. 5.
Câu 73. 
n
H
2n -2

O
2


A. axit acrylic. B. axit metacrilic. C. axit oleic. D. axit linoleic.
Câu 74. 


3
COOH. B. CH
3

2
H
5
COOH.
C. C
2
H
5

3
H
7
COOH. D. C
3
H
7

4

H
9
COOH.
Câu 75. 
3
H
4
O
2
, C
3
H
6
O
2
, C
4
H
6
O
2
, C
4
H
8
O
2

không 
A. C

3
H
4
O
2

4
H
8
O
2
. B. C
3
H
4
O
2

4
H
6
O
2
. C. C
3
H
4
O
2


3
H
6
O
2
. D. C
3
H
6
O
2

4
H
8
O
2
.
Câu 76. 

 
A. C
3
H
5
(OOCC
17
H
35
)

3
. B. C
3
H
5
(OOCC
17
H
33
)
3.
C. C
3
H
5
(OOCC
17
H
31
)
3
. D. C
3
H
5
(OOCC
15
H
31
)

3
.
Câu 77. 

A. pentan. B. xiclopentan. C. 2- metylbutan. D. 2,2-
Câu 78. 




 phenic, axit picric, axit axetic, axit propionic.
Câu 79. 
8
H
14
O
4


3


A. CH
3
OCOCH
2
CH(CH
3
)CH
2

COOCH
3
. B. CH
3
OCOCH(CH
3
)CH(CH
3
)COOCH
3
.
C. CH
3
OCOCH
2
C(CH
3
)
2
COOCH
3
. D. CH
3
OCOCH
2
CH
2
CH
2
CH

2
COOCH
3
.
Câu 80.  


A. H
2
N-CH
2
-CH
2
-COOH B. CH
3
-CH(NH
2
)-COOH C. H
2
N-CH
2
-COO-CH
3
D. CH
2
=CH-COO-NH
4

Câu 81. 
2



2

2

3
sinh
ra A
A. HCOOCH
2
CH
3
B. C
2
H
5
COOH C. HOOC-CHO D. HOCH
2
CH
2
CHO
Câu 82. 
4
H
6
O
2



2

o




A. CH
3
-COO-CH=CH
2
. B. CH
2
=CH-CH
2
-COOH. C. CH
2
=CH-O-CH
2
-CHO. D. CH
3
-CH=CH-COOH.
Câu 83. 
n
H
m
O
z

A. m = 2n + 2. B. m = 2n + 1. C. m = 2n  z. D. m = 2n + z.

Câu 84. 
cb


A. 0,155 mol B. 0,55 mol C. 0,645 mol D. 0,845 mol


LTĐH Tổng hợp Hữu cơ

6

Câu 85. 
2
SO
4

o


2
SO
4

o



A. X: CH
3
CH

2
OH 43,39%; Y: CH
3
CH
2
CH
2
OH ; Z: CH
3
CHOHCH
3

B. X: CH
3
CH
2
OH 33,39%; Y: CH
3
CH
2
CH
2
OH Z: CH
3
CHOHCH
3

C. X: CH
3
CH

2
CH
2
OH 43,39%; Y: CH
3
CH
2
CH
2
CH
2
OH Z: CH
3
CH
2
CHOHCH
3

D. X: CH
3
CH
2
CH
2
OH 33,39%; Y: CH
3
CH
2
CH
2

CH
2
OH Z: CH
3
CH
2
CHOHCH
3

Câu 86. 
A. Poli(vinyl clorua) B. Poliacrilonitrin C. Polimetylmetacrylat 
Câu 87. không 
A. 
2
SO
4

o

B. 
C.  
D. 
2

Câu 88. 
 
2


2


4

2

Câu 89. 
2


2
 

A. C
n
H
2n  1
CHO B. C
n
H
2n
(CHO)
2
C. C
n
H
2n + 1
CHO D. C
n
H
2n  2

(CHO)
2
.
Câu 90. 
 
 
Câu 91. 
C
2
H
6


C
2
H
5
Cl

C
2
H
5
OH

CH
3
CHO

CH

3
COOH

CH
3
COOC
2
H
5


C
2
H
5
OH

A. 2 B. 3 C. 4 D. 6
Câu 92. 
2

2


 B. X l



Câu 93. 
   

Câu 94. 
2
O/NH
3

A. axetandehit, butin -1, eten B. axetandehit, butin -2, etin
C. natri fomiat, vinylaxetilen, etin D. natri fomiat, vinylaxetilen, eten.
Câu 95.

-NH
2


A. H
2
NCH
2
COOH B. H
2
NCH
2
CH
2
COOH C. CH
3
CH
2
CH(NH
2
)COOH D. CH

3
CH(NH
2
)COOH
Câu 96. 
2


A. HOOC-CH
2
CH
2
-COOH B. C
2
H
5
COOH C. CH
3
-COOH D. HOOC-COOH.
Câu 97. 
6
H
6
O
2

 
A. 3. B. 4. C. 1. D. 2.
Câu 98. 
A. 5. B. 4. C. 3. D. 2.

Câu 99. 
2
H
5
OH, CH
3
CHO, CH
3

3
COOH b
A. 
2
SO
4
. B. Ag
2
O/NH
3

2
SO
4
.
C. Cu(OH)
2
 D. 
2
SO
4

.
Câu 100.   anken  polime.

5
H
12

A. 3. B. 4. C. 5. D. 6.
Câu 101. 
2
H
6
, C
2
H
4
, CH
3
CHO, CH
3
COOCH=CH
2

C
2
H
2
 X  Y  CH
3
COOH.

A. 4. B. 3. C. 2. D. 1.
Câu 102. C
4
H
8
O
2
 - 
A. 3. B. 4. C. 5. D. 6.
Câu 103. 
+ CuO + O
2
+ CH
3
OH trùng hợp


LTĐH Tổng hợp Hữu cơ

7

X  Y  D  E  

A. CH
3
CH(CH
3
)CH
2
OH. B. CH

2
=C(CH
3
)CH
2
OH.
C. CH
2
=C(CH
3
)CH
2
CH
2
OH. D. CH
3
CH(CH
3
)CH
2
CH
2
OH.
Câu 104. 
1- 
2- 
3- 
4- 
3


2
SO
4
-
5- -bromanilin.

A. 1, 2, 4. B. 2, 3, 4. C. 1, 4, 5. D. 1, 3, 4.
Câu 105. Cho 

A.  B. 
C.  D. 
Câu 106. 

A. metyl propionat. B. metyl panmitat. C. metyl oleat. D. metyl acrylat.
Câu 107. 

A. HCOOH. B. CH
3
COOH. C. C
2
H
5
COOH. D. C
2
H
3
COOH.
Câu 108. 

1) X, Y l 

3) t. 

A. (1), (2). B. (2), (3). C. (3), (4). D. (1), (3).
Câu 109. -
2
SO
4

o

o


A. 5. B. 6. C. 8. D. 9.
Câu 110. 
4
H
10
O, C
4
H
9
Cl, C
4
H
10
, C
4
H
11


A. C
4
H
9
Cl, C
4
H
10
, C
4
H
10
O, C
4
H
11
N. B. C
4
H
11
N, C
4
H
9
Cl, C
4
H
10
O, C

4
H
10
.
C. C
4
H
11
N, C
4
H
10
O, C
4
H
9
Cl, C
4
H
10
. D. C
4
H
11
N, C
4
H
10
O, C
4

H
10
, C
4
H
9
Cl.
Câu 111.  CH
2
=CH
2
+ KMnO
4
+ H
2
SO
4
 (COOH)
2
+ MnSO
4
+ K
2
SO
4
+ H
2
O

A. 5 : 2. B. 2 : 5. C. 2 : 1. D. 1 : 2.

Câu 112. 
5
H
10
O
2

2
SO
4

o


A. CH
3
COOCH
2
CH
2
CH
3
. B. CH
3
COOCH(CH
3
)
2
. C. HCOOCH(CH
3

)C
2
H
5
. D. HCOO(CH
2
)
3
CH
3
.
Câu 113. 
2


n t
o


A. C
2
H
4
. B. C
4
H
4
. C. C
3
H

4
. D. C
2
H
2
.
Câu 114. 

3



Ba(OH)
2

A. CH
4
, C
2
H
4
, C
2
H
2
. B. C
3
H
8
, C

2
H
4
, C
3
H
4
. C. C
3
H
8
, C
2
H
4
, C
2
H
2
. D. CH
4
, C
2
H
4
, C
3
H
4
.

Câu 115.  CH
2
=CH-Cl (1) ; CH
3
-CH
2
-Cl (2) ; CH
2
=CH-CH=O (3) ; CH
3
-CH=O (4).

A. 1, 2, 3, 4 B.3, 4, 2, 1 C. 3, 4, 1, 2 D. 4, 3, 2, 1.
Câu 116. 
Z


A. 3. B. 6. C. 5. D. 7.
Câu 117. 
X + H
2
 X + O
2
 
4
H
4
O
4
+ 2H

2
O.

A. Y : CH
3
OH ; Z : C
2
H
2
O
4
B. Y : C
2
H
4
(OH)
2
; Z : H
2
CO
2

C. Y : C
2
H
5
OH ; Z : C
2
H
2

O
4
D. Y : C
2
H
4
(OH)
2
; Z : C
2
H
2
O
4



LTĐH Tổng hợp Hữu cơ

8

Câu 118.  
3
H
8


1

1


1

1


A. propanol--2 B. propanol--1
C. propanol- -1
Câu 119. 
1


1

1


2

3

2


2

3


2

CH
2
CH
2
CH
2
OH B. CH
3
CH
2
COO
3
CH
2
CH
2
OH
C. CH
3

2
CH
2
OH D. NaOOCCH
2

3
OH.
Câu 120. 


c. 
 
Câu 121. 

2

2

2


1

1

1


A. HCOOH
3
NCH
3
B. CH
3
COONH
4
C. CH
3
CH
2

COONH
4
D. CH
3
COOH
3
NCH
3

Câu 122. 
8
H
14
O
4

a) C
8
H
14
O
4

1
+ X
2
+ H
2
O. b) X
1

+ H
2
SO
4

3
+ Na
2
SO
4

c) nX
3
+ nX
4
-6,6 + nH
2
O d) 2X
2
+ X
3

5
+ 2H
2
O
X (C
8
H
14

O
4

A. HCOO(CH
2
)
6
OOCH B. CH
3
OOC(CH
2
)
4
COOCH
3

C. CH
3
OOC(CH
2
)
5
COOH D. CH
3
CH
2
OOC(CH
2
)
4

COOH
Câu 123. 
HOOCC
6
H
4
 
A. Nilon-6,6 B. Capron C. Lapsan D. Enang.
Câu 124. 

 
 
Câu 125. 
2
HO
n
<
2
CO
n

 
 
Câu 126. 
5
H
8
:
A. 10. B. 11. C. 9. D. 8.
Câu 127. 

2

2


2

C=12)
A. CH
2
=CH
2
. B. CH
2
=CH-CH
2
-CH
3
.
C. CH
3
-C(CH
3
)=C(CH
3
)-CH
3
. D. CH
3
-CH=CH-CH

3
.
Câu 128. 
A.  6,6. B. 
C.  D. visco.
Câu 129. 
3
H
7
O
2

A. 5. B. 8. C. 7. D. 6.
Câu 130. 
2
O/NH
3

2

2


A.  B. 
C.  D. 
Câu 131. 
3

2
SO

4



A. [C
6
H
7
(OH)
3
]
n
,

[C
6
H
7
(OH)
2
NO
3
]
n
B. [C
6
H
7
(OH)
2

NO
3
]
n
,

[C
6
H
7
OH(NO
3
)
2
]
n
.
C. [C
6
H
7
OH(NO
3
)
2
]
n
,

[C

6
H
7
(NO
3
)
3
]
n
. D. [C
6
H
7
(OH)
2
NO
3
]
n
,

[C
6
H
7
(NO
3
)
3
]

n
.
Câu 132. 
C
2
H
5
O-H (1), CH
3
CO(O-H) (2), HCO(O-H) (3), C
6
H
5
O-H (4), R-C=CH-H (5), R--H (6)

A. 1 < 4 < 3 < 2 < 5 < 6. B. 5 < 6 < 1 < 4 < 2 < 3.


LTĐH Tổng hợp Hữu cơ

9

C. 4 < 1 < 3 < 2 < 6 < 5. D. 6 < 5 < 4 < 1< 2 < 3.
Câu 133. - 
A. 1. B. 2. C. 3. D. 4.
Câu 134.               

A. 
B. 
C. 

D. 
Câu 135. 
6
H
14


A. 2. B. 3. C. 4. D. 5.
Câu 136. Phenol không 
A. Na. B. HCl. C. NaOH. D. 
2
.
Câu 137. không đúng 

A. H
2
xt Ni, t
0
. B. K
2
ZnO
2
. C. Ag
2
O/NH
3
. D. Zn.
Câu 138. 

Y/X

= xx 
A. 1 < x < 1,36. B. 1,36 < x < 1,53. C. 1,53 < x < 1,62. D. 1,62 < x < 1,75.
Câu 139. 


A. CH(COOCH
3
)
3
. B. CH
3
CH
2
OOC  COOCH
2
CH
3

C. C
2
H
5
OOC  CH
2
 COOC
2
H
5 .
D. C
2

H
5
OOC  CH
2
 CH
2
 COOC
2
H
5.

Câu 140. 
A. Cu(OH)
2
. B. 
2
.
C. DD CuSO
4
. D. 
Câu 141. 
2
H
3
COOH, HCOOCH
3
, C
2
H
3

COOCH
3


A. CaCO
3
 B. dd Br
2
, dd Ag
2
O/NH
3
. C. dd Ag
2
O/NH
3
, Zn. D. dd NaOH, dd Br
2
.
Câu 142. uen  X  Y  p-

A. HNO
3

2
SO
4
 B. Fe, CO
2


2
.
C. Cl
2
, HCl, NH
3
, dd NaOH. D. Fe, HCl, NaOH, HNO
3

Câu 143. 


A. HCOO-CH
2
-CH
2
-COO-CH
3
. B. HCOO-CH
2
-CH
2
-OOC-CH
3
.
C. HCOO-CH
2
-CH
2
-OOC-C

2
H
5
. D. CH
3
-COO-CH
2
-CH(OOCH)-CH
2
-OOC-CH
3
.
Câu 144. 
A. dd NH
3
. B. dd H
2
S. C. dd H
2
SO
4
 D. dd H
2
SO
4

Câu 145. 


A. HCOOH, CH

3
OH, HCOOCH
3
. B. CH
3
COOH, CH
3
OH, CH
3
COOCH
3
.
C. CH
3
COOH, C
2
H
5
OH, CH
3
COOC
2
H
5
. D. HCOOH, C
3
H
7
OH, HCOOC
3

H
7
.
Câu 146.  

A. AgNO
3
/NH
3
. B. HNO
3
/H
2
SO
4
. C. Cu(OH)
2
 D. I
2
/CCl
4
.
Câu 147. 

A. dd Br
2

4
. B. dd Br
2


2
O/NH
3
.
C. dd HNO
3
 D. 
2
O/NH
3
.
Câu 148. 


A. 7,725 gam. B. 3,3375 gam. C. 6,675 gam. D. 5,625 gam.
Câu 149. C
4
H
8
O
2
a b 

2
O/NH
3
a b 
A. 5; 1. B. 6; 2. C. 4; 1. D. 7; 2.
Câu 150. 



LTĐH Tổng hợp Hữu cơ

10

A. CH
2
=CH
2
, CH
2
=CHCHO, C
6
H
5
CHO. B. CH
3
CHO, HCOOH, HCOOCH
3
.
C. CHCH, CH
3
CHO, HCO-CHO. D. HCHO, CH
3
COCH
3
, HCOOH.
Câu 151. 
.   

Câu 152. Axit axetic CH
3

A. CH
3
CHO, C
2
H
5

6
H
5
Cl. B. C
2
H
4
, C
2
H
5

3
OCH
3
.
C. CH
3
CHO, CH
3

COOCH
3
, C
2
H
5
OH. D. C
2
H
5
OH, C
2
H
5
Cl, CH
3
CHCl
3
.
Câu 153. 
3
CHO, C
6
H
12
O
6




3
/ NH
3
.  .  D. Cu(OH)
2
.
Câu 154. 
2
H
5
O)
n

 
A. HO-CH
2
-CH(CH
3
)-CH
2
-OH. B. CH
3
-CH
2
-CHOH-CH
2
OH.
C. HO-CH
2
-CH

2
-CH
2
-CH
2
-OH. D. CH
3
-CHOH-CHOH-CH
3
.
Câu 155. 
 
 
Câu 156. 
. B 
Câu 157. 
6
H
10
O
5
) :
A. 56. B. 57. C. 58. D. 59.
Câu 158. 
A. C
6
H
5
OH, C
2

H
5
NH
2
,CH
3
COOH. B. CH
3
NH
2
, C
2
H
5
NH
2
, CH
3
COOH.
C. C
6
H
5
NH
2

3
NH
2
, C

2
H
5
NH
2
. D. (C
6
H
5
)
2
NH, (CH
3
)
2
NH, NH
2
CH
2
COOH.
Câu 159. 


A. NH
2
CH
2
CH
2
C OOH. B. CH

2
=CHCOONH
4
. C. HCOOCH
2
CH
2
NH
2
. D. NH
2
CH
2
COOCH
3

Câu 160. 

C
2
H
2
A B D C
6
H
5
NH
2



A. C
6
H
6
, C
6
H
5
NO
2
, C
6
H
5
NH
3
Cl. B. C
6
H
6
, C
6
H
5
Cl, C
6
H
5
NO
2

.
C. C
6
H
12
, C
6
H
6
, C
6
H
5
NO
2
. D. C
6
H
6
, C
6
H
5
NO
2
, C
6
H
4
(NO

2
)
2
.
Câu 161. 
A. tinh b-6,6 B. xenl-6,6.
C. PE, PVC, polistiren. -6,6.
Câu 162. -2-en-1-
 B. CO
2
. . 
2
.
Câu 163. 

2
. B. Na, NaOH, CaCO
3
. C. Na, H
2
, NaOH. D. CaCO
3
, Cu, NaOH.
Câu 164. 
xit axetic. 
 
Câu 165. 
3
H
6

O
2


A. CH
3
CH
2
COOH . B. CH
3
COOCH
3
. C. HO-CH
2
CH
2
CHO D. HO-CH
2
COCH
3
.
Câu 166. 
A. axit lactic. B. axit axetic. C. axit fomic. D. axit glutamic.
Câu 167. 
2

C:
A. CH
3
COOCH=CH-CH

3
. B. C
2
H
5
COOCH=CH
2
. C. HCOOCH=CH-CH
2
-CH
3
. D. CH
2
=CH-COO-C
2
H
5
.
Câu 168. -
A. 3. B. 4. C. 5. D. 6.
Câu 169.  C
2
H
6

2
H
5

2

H
5

3

3
COO
3
COOC
2
H
5

2
H
5
OH
 
A. 2. B. 3. C. 4. D. 5.
Câu 170. 

A. butan. B. 2-metylpropan. C. 3-metylpentan. D. 2,3-
Câu 171.   
(Cho H = 1; C = 12; O = 16)


LTĐH Tổng hợp Hữu cơ

11


A. 3. B. 5. C. 2. D. 4.
Câu 172. 
3

2

3


A. HCHO. B. CH
3
CHO. C. CH
2
=CH-CHO. D. OHC-CHO.
Câu 173. 

A. 2. B. 4. C. 3. D. 5.
Câu 174. 
2
SO
4


A. 50%. B. 62,5%. C. 75%. D. 55%.
Câu 175. Cho c

3

2


3


A. HCOOCH=CH
2
. B. CH
3
COOCH=CH-CH
3
. C. CH
3
COOCH=CH
2
. D. HCOOCH
3
.
Câu 176. 
A.  B.  C.  D. 
Câu 177.  



A. H
2
NCH
2
COO-CH
3
. B. H
2

NCOO-CH
2
CH
3
. C. CH
2
=CHCOONH
4
. D. H
2
NC
2
H
4
COOH.
Câu 178. Cho 50ml du
3

2

NH
3
thu




A. 0,10M. B. 0,20M. C. 0,01M. D. 0,02M.
Câu 179. 
A. CH

2
=CH-COO-CH
3
. B. CH
2
=CH-COO-C
2
H
5
. C. C
2
H
5
COO-CH=CH
2
. D. CH
3
COO-CH=CH
2
.
Câu 180.  X  Y  CH
3
COOH. 
A. CH
3

3
CH
2
OH. B. CH

3
CH
2
OH 
3
CHO.
C. CH
3

3
CHO. D. CH
3
CH
2

2
=CH
2
.
Câu 181. 

A. 4. B. 1. C. 3. D. 2.
Câu 182. 
2

A. 
B. 
C. 
D. 
Câu 183. 

7
H
8
O
2


2
c

A. CH
3
C
6
H
3
(OH)
2
. B. HOC
6
H
4
CH
2
OH. C. C
6
H
5
CH(OH)
2

. D. CH
3
OC
6
H
4
OH.
Câu 184. 

A. 9. B. 12. C. 15. D. 18.
Câu 185. 
HOCH
2
-CH
2
OH (X); HOCH
2
-CH
2
-CH
2
OH (Y); HOCH
2
-CHOH-CH
2
OH (Z);
CH
3
-CH
2

-O-CH
2
-CH
3
(R); CH
3
-CHOH-CH
2
OH (T).

2

A. X, Y, Z, T. B. X, Y, R, T. C. Z, R, T. D. X, Z, T.
Câu 186. -

A.  B. -
C.  D. -6,6.
Câu 187. 
A. CH
2
=CHCOOCH
3
. B. CH
2
=C(CH
3
)COOCH
3
. C. C
6

H
5
CH=CH
2
. D. CH
3
COOCH=CH
2
.
Câu 188. 
A.  B.  C.  D.
Câu 189. 
A. etylclorua B. etylen C.  D. ehitaxetic
Câu 190. 
A. 
B. 


LTĐH Tổng hợp Hữu cơ

12

C. 
D. 
Câu 191. C
3
H
4
O
2

; C
4
H
6
O
2
; C
3
H
6
O
2


A. C
3
H
4
O
2

4
H
6
O
2
B. C
3
H
4

O
2

4
H
8
O
2
C. C
4
H
6
O
2
D. C
3
H
4
O
2
Câu 192. 

A. 2 B. 6 C. 8 D. 4
Câu 193. 
2

2

A.  B. 
C.  D. 

Câu 194. 
2


3

A. R-CH
2
OH B. C
n
H
2n+1
CHO C. C
n
H
2n+1
CH
2
OH D. R-CHO
Câu 195. 
A. CHO B. C
2
H
4
O
3
C. C
2
H
3

O D. C
2
H
5
O
Câu 196. 
xa
A. C
3
H
9
O
2
N B. C
4
H
9
O
2
N C. C
3
H
7
O
2
N D. C
2
H
7
O

2
N
Câu 197. 
7
H
9
NO
2


A. HCOOC
6
H
4
NO
2
B. H
2
N-C
6
H
4
COOH C. C
6
H
5
COONH
4
D. HCOOC
6

H
4
NH
2
Câu 198. 
2


A. isopentan. B. buta-1,3- C. etylxiclopentan. D. neoheptan.
Câu 199. c :
a.) CH
3
COOH + CaCO
3
 b.) CH
3

c.) C
17
H
35
COONa + H
2
SO
4
 d.) C
17
H
35
COONa + Ca(HCO

3
)
2


A. 2 B. 1 C. 3 D. 4
Câu 200.  

A.  B. 
C.  D. 
Câu 201. 
A. 2 B. 1 C. 4 D. 3
Câu 202. 
A. 
Cu(OH)
2
B. 
C. 
D. Tinh 
Câu 203. 
2
H
2
, C
3
H
6
, C
2
H

6

2
O.

2


A. 50; 20; 30 B. 25; 25; 50 C. 50; 16,67; 33,33 D. 50; 25; 25
Câu 204. 
A. Na B. Dung d
3
/NH
3
 D. Cu(OH)
2
.
Câu 205. 
2
(1) ; 
3
/NH
3
(2) ; H
2
/Ni, t
o
(3) ; H
2
SO

4


   
Câu 206. 
99,67 
   
Câu 207. 
Ankan 
A. C
2
H
6
B.

C
3
H
8
C. C
4
H
10
D. C
5
H
12
Câu 208. 
3
H

9
O
2


2
. 

A. HCOONH
3
C
2
H
5
; C
2
H
5
NH
2
B. CH
3
COONH
3
CH
3
; CH
3
NH
2


C. HCOONH
3
C
2
H
3
; C
2
H
3
NH
2
D. CH
2
=CHCOONH
4
; NH
3



LTĐH Tổng hợp Hữu cơ

13

Câu 209. 
NH
2
-CH

2
-COOH (1) ; ClH
3
N-CH
2
-COOH (2);
NH
2
-CH
2
-COONa (3) ; NH
2
-(CH
2
)
2
CH(NH
2
)-COOH (4);
HOOC-(CH
2
)
2
CH(NH
2
)-COOH (5).

A. (3) B. (2) C. (2), (5) D. (1), (4).
Câu 210. 



2
SO
4
B. Cu(OH)
2

2

3

Câu 211. 
 caosu isopren (2),   

   
Câu 212. 
2

2


. 
 
Câu 213. 
1) Phenol -
-C
2
H
5
-OH.



2
H
5


2

6
H
5

6
H
5
OH

.


   
Câu 214.  axit sau:
1) CH
3
-CHCl-CHCl-COOH 2) CH
2
Cl

-CH

2
-CHCl-COOH
3) CHCl
2
-CH
2
-CH
2
-COOH 4) CH
3
-CH
2
-CCl
2
-COOH

A. (1), (2), (3), (4) B. (2), (3), (4), (1) C. (3), (2), (1), (4) D. (4), (2), (1), (3).
Câu 215. 


A. HCOOCH
2
-CH=CH
2
B. HCOOCH=CH-CH
3
C. CH
3
OOCCH=CH
2

D. CH
3
-COOCH=CH
2


Câu 216. m gam CO
2

A. C
2
H
6
B. C
3
H
8
C. C
4
H
10
D. C
3
H
6

Câu 217. 
4
H
7

O
2


A. HCOO-CH
2
- CHCl-CH
3
B. CH
3
-COO-CH
2
-CH
2
Cl C. HCOOCHCl-CH
2
-CH
3
D. HCOOC(CH
3
)Cl-CH
3

Câu 218. 
X
< M
Y


2

:
A. 50; 50 B. 20; 80 C. 33,33 ; 66,67 D. 80 , 20.
Câu 219. Cho buten-
2
SO
4

170
o

A. Buten-1 B. Buten-2 C. butadien-1,3 D. 2-metylpropan
Câu 220. không 
A. 
4

B. 
2

C. 
D. 
2
.
Câu 221. 
A. CH
3

2
SO
4


o

B. C
2
H
5

o

2

C. , CO
2

D. 
2

2
, Ba
Câu 222. 
2

2


2

  
 
Câu 223. 

7
H
8



LTĐH Tổng hợp Hữu cơ

14

dd. NaOH,t
o
-NH
3
; -H
2
O

C
2
H
5
OH, H
2
SO
4
đ,t
o

-H

2
O
H
2
SO
4
đ,t
o

-Na
2
SO
4

A. 4 B. 5 C. 6 D. 7
Câu 224. 

o
-23
o

A. C
2
H
6

4
H
12
O

2
B. CH
3
CH
2
CH
2

3
OCH
3

C. C
2
H
5

3
OCH
3

2
H
4
O
2

Câu 225. 
8
H

10

X
 
 OH 2

 
trunghop
polime.
A. C
6
H
5
CH
2
CH
2
OH B. C
6
H
5
CH(OH)CH
3

C. CH
3
C
6
H
4

CH
2
OH D. C
6
H
5
CH
2
CH
2

6
H
5
CH(OH)CH
3
Câu 226. 
3
au:
A. 
2
SO
4

B. 
2
.
C. 
4


3

D. 
3

3.

Câu 227. -
A. n-
2
 B. Buten-
C. Buten-clorua D. Butadien-
Câu 228. 
A. 
B. 
C. 
D.  
Câu 229. 
propanol-1(I); sec-butylic(II); etanol(III); 2-metylpropanol-1(IV);
2-metylpropanol-2(V); metylic (VI) n-butylic (VII).

 B. II, III, V, VI  
Câu 230. 
7
H
8

2

A. 4 B. 5 C. 6 D. 7

Câu 231. 
3
CH(OH)CH
3
(2), H
2

3

A. 1<2<3<4 B. 4<3<1<2 C. 2<4<1<3 D. 2<4<3<1
Câu 232.  :

X Y Z C
2
H
5
OOCCH(CH
3
)NH
3
HSO
4
.

 :
A. CH
3
CH(NH
2
)COONa B. CH

3
COONH
4

C. CH
3
CH(NH
2
)COONH
4
D.CH
3
CH(NH
2
)COOH
Câu 233.  : 1) CH
2
O
2
; 2) C
2
H
4
O
2
; 3) C
3
H
6
O

2

 :


2
H
5



Câu 234. 
4
H
7
ClO
2
 :

2
H
4
(OH)
2
+ NaCl.
 :
A. CH
3
COO-CH
2

-CH
2
Cl B. Cl-CH
2
-COO-CH
2
CH
3
C. CH
3
COOCHCl-CH
3
D. Cl-CH
2
-OOC-CH
2
CH
3

Câu 235.  :

2
.

2


6,5
o


 :
A. HOCH
2
CH(OH)CHO B. HCOOH C. OHCCOOH D. HOOCCOOH
Câu 236.  :
Na (1) ; C
2
H
5
OH (2); Cu(OH)
2
(3) ; H
2
(4) ;
Ag
2
O/NH
3
(5); O
2
(6), ddNaOH(7) ; Na
2
CO
3
(8) ;
CH
3
COOH (9).
 :
A. 1, 2, 3, 4, 5, 6 B. 3, 4, 5, 6, 7, 8 C. 4, 5, 6, 7, 8, 9 D. 1, 3, 4, 5, 6, 9



LTĐH Tổng hợp Hữu cơ

15

Câu 237. 
3
H
6
O ; C
3
H
6
O
2
; C
3
H
4

3
H
4
O
2

    

2

  :
A. X: C
2
H
5
COOH ; Y : C
2
H
5
CHO ; Z : CH
2
=CH-COOH ; T : CH
2
=CH-CHO
B. X: C
2
H
5
CHO ; Y : C
2
H
5
COOH ; Z : CH
2
=CH-CHO; T : CH
2
=CH-COOH
C. X: C
2
H

5
COOH ; Y : C
2
H
5
CHO ; Z : CH
2
=CH-CHO; T : CH
2
=CH-COOH
D. X: CH
2
=CH-COOH ; Y : C
2
H
5
CHO ; Z : C
2
H
5
COOH; T : CH
2
=CH-CHO
Câu 238. 
3
CH
2
COOH (X
1
) ; CH

3
-COO-CH
3
(X
2
) HO-CH
2
-CH
2
CHO (X
3
).
 

3
) ; Na
2
CO
3

1
) 
2
)
B. 
3
) ; Na
2
CO
3


1
) 
2


)
C. 
1
) 
2
) 
3
).

2

1
) ; Na
2
CO
3

1
) 
3
) ;
Câu 239. 
2
H

2
-

A. C
2
H
2

6
H
6

6
H
3
(NO
2
)
3

6
H
3
(NH
2
)
3

6
H

3
(NH
2
)
3

B. C
2
H
2

6
H
6

6
H
5

6
H
5

6
H
2
(NO
2
)
3


C. C
2
H
2

6
H
6

6
H
5
NO
2

2
C
6
H
2
Br
3


Câu 240.  Anken (C
n
H
2n
) + KMnO

4
+ H
2
O 
n
H
2n
(OH)
2
+ KOH + MnO
2
.


B. C
n
H
2n
(OH)
2

2

- 

Câu 241. 
4
)
2
SO

4
(5), 

A   D
Câu 242. 

 
2
, Br
2


2


2
O/NH
3


Câu 243.  
2
SO
4


A. C
n
H
2n+1

OH B. RCH
2
OH C. C
n
H
2n+1
CH
2
OH D.C
n
H
2n+2
O
Câu 244. 
A: Axit metacrylic B: anilin C: axit formic D: axit axetic
Câu 245.  Mg (1); ddNaOH (2);  C
2
H
5
OH (4), ddBr
2
(5) 
:
   
Câu 246. 
A: Li
B: Li
C: Li.
D: Lipit 
Câu 247. 


A:.Magie  C.  D. 

Câu 248. 
A. C
2
H
4

2
H
3
 


2
.
.
Câu 249. 

2

2
O.

2
.
(III): t

(V): B




LTĐH Tổng hợp Hữu cơ

16

-OH):
   
Câu 250. 
propanol-1(I); sec-butylic(II); etanol(III); 2-metylpropanol-1(IV);
2-metylpropanol-2(V); metylic (VI) n-butylic (VII).

   
Câu 251. 
A.  B. 
2

C. 
2
SO
4
 D. dun
Câu 252.  1) amoniac, 2) anilin, 3) p-nitroanilin, 4) p-aminotoluen, 5) metylamin, 

A. 1<3<2<4<5<6 B. 2<3<4<1<5<6 C. 3<2<4<1<5<6 D. 6<5<1<4<2<3
Câu 253. 
4
H
7

ClO
2
 :

3
CHO + NaCl + H
2
O.  :
A. CH
3
COO-CH
2
-CH
2
Cl B. Cl-CH
2
-COO-CH
2
CH
3

C. CH
3
COOCHCl-CH
3
D. Cl-CH
2
-OOC-CH
2
CH

3
Câu 254. Ch
11
H
20
O
4

-
A. C
2
H
5
OOC-(CH
2
)
4
-COOCH(CH
3
)
2
B. C
2
H
5
OOC-(CH
2
)
4
-COOCH

2
CH
2
CH
3

C. C
2
H
5
COO-(CH
2
)
4
-COOCH(CH
3
)
2
D. C
3
H
5
OOC-(CH
2
)
3
-COOCH(CH
3
)
2


Câu 255. 
3
H
10
O
2
N
2

3


A. NH
2
-CH
2
-COONH
3
CH
3
B. CH
3
CH(NH
2
)COONH
4

C. NH
2

CH
2
-CH
2
-COONH
4
D. CH
3
-NH-CH
2
-COONH
4

Câu 256. 
A: anilin B: axit axetic C: Axit acrylic D: phenol
Câu 257. 
A. CaCO
3

2

2
H
2

4
H
4
-


2
H
5
-
C. CH
4

2
H
2

4
H
4
-

2
H
4

2
H
5
-
Câu 258.  
 2) Cu(OH)
2

3
/NH

3

 
2


3
/NH
3

2

3
/NH
3

Câu 259. 
1) HOCH
2
-CH
2
OH 2) HO-CH
2
-CH
2
-CH
2
-OH
3) CH
3

-CH(OH)-CH
2
OH 4) HO-CH
2
-CH(OH)-CH
2
-OH




2


2

2
O
Câu 260. 
4
H
9

A. sec-butylic B. 2-metylpropanol-1 C. 2-metylpropanol-2 D. n-butylic
Câu 261. 
A. etilen, axetilen, benzen, toluen. B. benzen, stiren, etilen, axetilen.
C. etilen, axetilen, stiren. D. benzen, toluen, stiren
Câu 262. không 





Câu 263. 
A. CH
3
-NH
2
; C
2
H
5
-NH
2
; NH
3
; C
6
H
5
-NH
2
B. CH
3
-NH
2
; NH
3
; C
2
H

5
-NH
2
; C
6
H
5
-NH
2
C. C
6
H
5
-NH
2
; CH
3
-NH
2
; C
2
H
5
-NH
2
; NH
3
D. C
6
H

5
-NH
2
; NH
3
; CH
3
-NH
2
; C
2
H
5
-NH
2

Câu 264. A
3
H
5
NO
2 .

   
Câu 265. 

A. 5.10
4
B. 4.10
4

C. 3.10
4
D. 2.10
4



LTĐH Tổng hợp Hữu cơ

17

Câu 266. 
A. Hexacloxiclohexan. in.


- aminocaproic. 
Câu 267. 

A. BCDEA. B. DEBCA. C. ADCBE. D. EBACD.
Câu 268. 
3

3
H
7

2
SO
4


o


A. 4 ete B. 5 ete. C. 6 ete D. 7 ete
Câu 269. 
3
)
2
CHCH(OH)CH
3

A. 2-Metylbuten-1. B. 3-Metylbuten-1. C. 2-Metylbuten-2. D. 3-Metylbuten-2.
Câu 270. 
A. Na.  
2
. 
Câu 271. 
3

3

/O
2

A. CH
3
CH
2
CHO . B. CH
2

= CH - CH
2
 CHO. C. CH
3
- C

C  CHO. D. CH

C - CH
2
- CHO .
Câu 272. 
4
H
7
O
2


A. HOOC-CH
2
CHCl-CH
3
B. CH
3
COO-CH
2
CH
2
Cl. C. HOOC-CHCl-CH

2
-CH
3
. D. CH
2
COO-CH
3
CH
2
Cl
Câu 273. 






   
Câu 274. Polimetylmetacr
A. CH
3
- OOC - C(CH
3
) = CH
2
. B. CH
2
= CH  COOH.
C. CH
2

= CH - COOCH
3
. D. HOOC - C(CH
3
) = CH
2
.
Câu 275. 
3
COOH, C
2
H
5
OH

, CH
3
 
A. CH
3
COOH > HCOOH > C
2
H
5
OH > CH
3
CHO . B. CH
3
COOH > C
2

H
5
OH > HCOOH > CH
3
CHO.
C. C
2
H
5
OH > CH
3
COOH > HCOOH > CH
3
CHO. D. CH
3
CHO > C
2
H
5
OH > HCOOH > CH
3
COOH .
Câu 276. 
3
H
5
O
2
)
n

 
A. HOOC - CH
2
- CH
2
- COOH B. HOOC - CH
2
- CH
2
- CH
2
- COOH
C. HOOC-CH
2
- CH
2
-CH
2
- CH
2
- COOH. D. HOOC -CH
2
- CH
2
-CH
2
- CH
2
-CH
2

COOH.
Câu 277. 
A. CH
3
OH. 
6
H
5
COOH.  D. C
6
H
5

Câu 278. 
2
-

A. CH
3
CH
2
CH
2
OH B. CH
3
CHOHCH
3
C. CH
3
CH

2
OH D. CH
3
CH
2
CH
2
CH
2
OH
Câu 279. C
X C
3
H
6
Br
2
C
3
H
8
O
2
C
3
H
6
O
2
C

3
H
4
O
4,
,

A. propan. B. propen. C. xiclopropan. 
Câu 280. 


C
D
Câu 281. 
A. NaOH. B. AgNO
3

2
. D. HCN.
Câu 282. 
A. CH
3
COOH. B. CH
3
CHO. C. CO
2
v H
2
O. D. CH
2

OH-CH
2
OH.
Câu 283. -
4

2
SO
4


A. 0,12 l B. 0,576 l. D. 0,24 l. D. 0, 48 l.
Câu 284. - 
A. AgNO
3
/ NH
3
. B. Na. C. Cu(OH)
2
. 
Câu 285. 
 
 
subuna Cao
H
Tinhbét
hîp trïng
r-îumen
2
  

64
0
52
0
42
450,
HC
C
Xt
OHHCglucozo
tlSOH
O



LTĐH Tổng hợp Hữu cơ

18

Câu 286. 
A. 2. B. 3. C. 4. D. 5.
Câu 287. 
A. H
2
N-CH
2
-COOH. B. H
2
N-(CH
2

)
2
-COOH. 

-aminoaxit. 
Câu 288. 
3
H
8
O
x

A. 2. B. 3. C. 4. D. 5.
Câu 289. 
4
H
8
O
2

2
H
3
O
2

C
2
H
6


A. axit; B. este ,  D. ancol.
Câu 290. 

2
. . C. CO
2
+H
2
O. D. Na.
Câu 291. 
A. C
2
H
5
OH, CH
3
CHO. B. CH
3
CHO, CH
3
COOH.
C. CH
3
COOH, CH
3
OH. D. CH
3
COOCH
3

, CH
3
COOH.
Câu 292. 
2

A. C
3
H
4
O
4
. B. C
3
H
4
O
4

4
H
4
O
6
. C. C
4
H
4
O
8

. D. C
4
H
10
O
4
.
Câu 293. 

2

2
S0
4
 
4

Câu 294. 
CH
3
COOH + C
2
H
5
OH  CH
3
COOC
2
H
5

+ H
2
O


A. 2,8 B. 3,2. C. 1,2. D.1,0.
Câu 295. 
2

2
H
4


4
trong H
2
0 
2
trong H
2
0

2
trong CCl
4

2
0.
Câu 296.  không 

A. CH
3
COOH + CaCO
3
B. C
17
H
5
COONa + H
2
SO
4

C. CH
3
COOH + C
6
H
5
OH D. CH
3
ONa + C
6
H
5
OH.
Câu 297. 

2
 

2

 
Câu 298. 
2
CO
3


3


2
(CO
3
)
3
. 
3

C. (CH
3
COO)
3
Fe 
Câu 299. H
3

3
NH

2
?




2
.
Câu 300. 
A



Câu 301. 

A. CH
4
. B. CH
3
CH
2
CH
2
CH
3
. C. CH
3
CH(CH
3
)CH

3
. D. CH
2
=CHCH
3
.
Câu 302. 
A. cao su Buna B. P.V.C  D. nilon 6.6
Câu 303. 
A. 1 B. 5 C. 3 D. 4
Câu 304. 
6
H
5
OH, C
2
H
5
OH, CH
3
COOH  CH
2
= CH - 
 B. dd

Br
2
C. CaCO
3


2

Câu 305. 
2
SO
4
, CH
3

A. CH
3
COOH, HCl, H
2
SO
4
B. HCl, H
2
SO
4
, CH
3
COOH
C. HCl, CH
3
COOH, H
2
SO
4
D. H
2

SO
4
, HCl, CH
3
COOH
Câu 306. 
CH
2
= CH
2
, CH

C - CH
3
, CH
2
= CH - C

CH, CH
2
= CH - CH = CH
2
, CH
3
- C

C - CH
3
, benzen, toluen.


2
O/NH
3

A. 1 B. 2 C. 3 D. 4


LTĐH Tổng hợp Hữu cơ

19

Câu 307. 
   
Câu 308. 

A. I
2

2
, t
0
B. I
2

2
O/NH
3

C. I
2


3
D. Ag
2
O/NH
3
, HNO
3
, H
2
(t
o
)
Câu 309. 
A. Cu(OH)
2
, HNO
3
B.
 
243
)()( OHNHCu
, HNO
3

C. AgNO
3
/NH
3
, H

2
O (H
+
) D. AgNO
3
/NH
3
, CH
3
COOH
Câu 310. 
6
H
5
NH
2
, CH
3
NH
2
, CH
3
CH
2
NH CH
3
, CH
3
CH
2

CH
2
NH
2


A. C
6
H
5
NH
2
B. CH
3
NH
2
C. CH
3
CH
2
NHCH
3
D. CH
3
CH
2
CH
2
NH
2


Câu 311. 
8
H
15
O
4
N + 2NaOH

C
5
H
7
O
4
NNa
2
+ CH
4
O + C
2
H
6
O

5
H
7
O
4

NNa
2


-NH
2


C

8
H
15
O
4

A. 1 B. 2 C. 3 D. 4
Câu 312.  
A. 1 B. 2 C. 3 D. 4
Câu 313. 
3
COOC
2
H
5
, C
6
H
5
NH

2
, C
2
H
5
OH, C
6
H
5
CH
2
OH, C
6
H
5
OH, C
6
H
5
NH
3


A. 1 B. 2 C. 3 D. 4
Câu 314. C-
2

A. 2 B. 4 C. 3 D. 5
Câu 315. 


3
/NH
3

A. CH
3
COO - CH = CH - CH
3
B. CH
3
COO - CH = CH
2

C. HCOO - CH = CH
2
D. HCOO - CH = CH - CH
3

Câu 316. 
A. Cu(OH)
2
, Na, NaOH. B. HNO
3
, Fe(OH)
2
, CH
3
COOH
C. Cu(OH)
2

, Na, HNO
3
D. CaCO
3
, Cu(OH)
2
, CH
3
COOH
Câu 317. 
C
6
H
6

X

Y

Z

- OH

NH
2


A. C
6
H

5
Cl, C
6
H
5
OH, m - HO - C
6
H
4
- NO
2
B. C
6
H
5
NO
2
, C
6
H
5
NH
2
, m - HO - C
6
H
4
-NO
2


C. C
6
H
5
Cl, m - Cl - C
6
H
4
- NO
2
, m - HO - C
6
H
4
NO
2
D. C
6
H
5
NO
2
, m - Cl - C
6
H
4
-NO
2
, m - HO - C
6

H
4
- NO
2

Câu 318. 
6
H
5
OH, C
6
H
5
COOH, C
6
H
6
, C
6
H
5
-CH
3

A. C
6
H
5
OH B. C
6

H
5
COOH C. C
6
H
6
D. C
6
H
5
CH
3
Câu 319. 
3

2
SO
4

A. C
6
H
5
COOH B. C
6
H
5
NH
2
C. C

6
H
5
OH D. C
6
H
5
NO
2

Câu 320. 

4


B. Cho HNO
3




Câu 321. 
A. buten - 1 B. buten - 2 C. 2 - metyl propen D. metyl xiclopropan
Câu 322. 
6
H
5

6
H

5
NH
2

 
2

2

2
Câu 323. 
2
, H
2
O, CH
4
, C
2
H
6

A. H
2
< CH
4
< C
2
H
6
< H

2
O B. H
2
< CH
4
< H
2
O < C
2
H
6

C. H
2
< H
2
O < CH
4
< C
2
H
6
D. CH
4
< H
2
< C
2
H
6

< H
2
O
Câu 324. 
2
: nH
2


A. C
n
H
2n
O ( n

3) B. C
n
H
2n+2
O ( n

1) C. C
n
H
2n-6
O ( n

7) D. C
n
H

2n-2
O ( n

3)
Câu 325. 
1

3
H
6
O
2

4
A
3
/NH
3
AgNO dd
3
A
4
SO
2
H dd
2
A
NaOH
1
A    



1

A. HOCH
2
CH
2
CHO B. CH
3
CH
2
COOH C. HCOOCH
2
CH
3
D. CH
3
COCH
2
OH


LTĐH Tổng hợp Hữu cơ

20

Câu 326. 
m
c

: m
H
: m
O
= 3 : 0,5 : 4

2
O 
2
H
4
O

3
COOH 
Câu 327.  Na
+
, K
+
xi
  
2
CO
3

Câu 328. 
3
COOH, C
2
H

5
OH, CH
3
CHO, C
2
H
6

A. C
2
H
6
< CH
3
CHO < CH
3
COOH < C
2
H
5
OH B. CH
3
COOH < C
2
H
5
OH < CH
3
CHO < C
2

H
6

C. C
2
H
6
< C
2
H
5
OH < CH
3
CHO < CH
3
COOH D. C
2
H
6
< CH
3
CHO < C
2
H
5
OH < CH
3
COOH
Câu 329. 
3

)
2
CHCH
2

A. Axit 3metylbutanoic B. Axit 3metylbutan1oic
C. Axit isobutiric D. Axit 3metylpentanoic
Câu 330. 
A. 9 B. 10 C. 7 D. 8
Câu 331. 
A. 1 B. 2 C. 3 D. 4
Câu 332. 




Câu 333. Nilon
A. H
2
N(CH
2
)
6
NH
2
B. H
2
N(CH
2
)

6
COOH
C. H
2
N(CH
2
)
6
NH
2

2
)
6
COOH D. CH
3
CH(NH
2
)COOH
Câu 334. 
A. CH
2
=CH
2
B. CH
2
=CHCl C. C
6
H
5

CH=CH
2
D. CH
2
=CHCH=CH
2

Câu 335. 
2

2


 
 
Câu 336.  

0

. 
A. C
2
H
5
OOC-COOC
2
H
5
B. CH
3

OOC-CH
2
-COOCH
3
C. CH
3
COOC
2
H
5
D. CH
3
OOC-COOCH
3

Câu 337.  
2


A. C
2
H
5
COOCH
3
B. CH
3
COOC
2
H

5
C. HCOOC
3
H
7
D. C
2
H
3
COOCH
3

Câu 338. 

A. C
4
H
7
N
2
O
4.
B. C
8
H
5
NO
2.
C. C
5

H
9
NO
4.
D. C
5
H
25
NO
3.

Câu 339. không 
A. 
B. -
C. NH
2
-COOH c
D. 
+
NH
3
C
x
H
y
COO


4
.

Câu 340. 

A. C
2
H
2

3
H
4
. B. C
3
H
4

4
H
6
. C. C
3
H
4

4
H
8
. D. C
2
H
4


4
H
8
.
Câu 341. 
A.  B. 
C.  D. phenol
Câu 342. không 
A. -2-
B. 
C. 
3
.
D. .
Câu 343. 
4
H
6
O
2

A. 9 B. 10 C. 8 D. 12
Câu 344. 
6
H
10
O
4



A. 2. B. 3. C. 4. D. 6.


LTĐH Tổng hợp Hữu cơ

21

Câu 345. 
4
H
6
O
2
. 

A. HCOOCH=CHCH
3
B. HCOOCH
2
CH=CH
2
C. CH
3
COOCH=CH
2
D. CH
2
=CHCOOCH
3


Câu 346. sai?
A. 
B. 
C.  
D. -tribromphenol.
Câu 347. 
3

3


A. CH
3
CHO. B. HCHO. C. C
2
H
5
CHO.

D. C
2
H
3
CHO.
Câu 348. 
2
SO
4


o
C thu

A. metanol, propan-2-ol. B. metanol, etanol.
C. etanol, butan-2-ol. D. propan-2-ol, etanol.
Câu 349.  không phải 
A. 
2
. B. 
C.   D. 
Câu 350. 
A. (CH
3
)
2

3
)
2
CHNH
2
. B. (CH
3
)
3

3
)
3
CNH

2
.
C. (CH
3
)
2

3
)
2
CHNHCH
3
. D. (CH
3
)
3

3
)
3
CNHCH
3
.
Câu 351.  A + B  C + D;
 
D + AgNO
3
  
3
.


A. Br
2
. B. NaI. C. KCl. D. Cl
2
.
Câu 352. 
H
2
O 
2

2


A. CH
3
OH. B. C
2
H
4
(OH)
2
. C. C
2
H
5
OH.

D. C

4
H
9
OH.
Câu 353. 
5
H
8
O
2
, E + NaOH  X 
Br
2

A.  B. 
C.  D. 
Câu 354. 
CH
3
CH
2
CH(CH
3
)CH
2
CH(C
2
H
5
)COOH

A. axit 5-etyl-3-metylhexanoic. B. axit 2-etyl-4-metylhexanoic.
C. axit 3-etyl-5-metylheptanoic. D. Axit 5-etyl-3-metylhexanoic.
Câu 355. 
6
H
5
NH
2
, C
2
H
5
OH, CH
3
COOH, C
6
H
5
ONa, C
2
H
5
ONa. 
A. 2. B. 3. C. 4. D. 5.
Câu 356. 
2
amolH vöøañuû


Nadö


b(mol) H
2
. Cho a = 4b.
không thể 
A. CHC-CH(CHO)
2
. B. CH
2
=CH-CHO. C. CH
2
=C(CH
3
)-CHO. D. (CHO)
2
.
Câu 357. 

2

2

A. HCOOH. B. HCOOCH
3
. C. OHC-COOH. D. OHC-CH
2
-COOH.
Câu 358. 
A
= M

B


A. CH
3
COOH. B. HCOOH. C. C
3
H
7
COOH. D. C
2
H
5
COOH.
Câu 359. 

CH
2
CH
2
O NH CH
2
C
O
NH CH
2
C NH CH
CH
3
O

C
O
n
n n


A. --aminopropionic.
B. etilen glycol, glixin, axit 
C. 
D. 
Câu 360. 
A. CaCO
3
B. CaSO
4
. H
2
O C. Polime D. pozit
Câu 361. không 


LTH Tng hp Hu c

22

A. CH
4
O B. CH
3
CH

2
CH
2
CH
3
C. CH
3
CH
2
OH D. HCOOCH
2
CH
3

Cõu 362.
3
Cl, CO, CH
3
COOCH
3
, CH
3
ONa, CH
3
OCH
3
, CH
2
Cl
2



A. 5 B. 6 C. 3 D. 4
Cõu 363.

A. C
n
H
2n-2k
O
2
B. C
n
H
2n-2
O
2
C. C
n
H
2n-1
O
2
D. C
n
H
2n
O
2
Cõu 364. khụng

6
H
10
?
A. B. C. D.
Cõu 365.
A.
n
H
2n-2

B.
n
H
2n+2

C.
n
H
2n-6

D.
2

Cõu 366.
A.
B. -aminoaxit.
C. -
D.
2


Cõu 367.
A. B. C. D.
Cõu 368.
A.
B.

C.

D.
Cõu 369.

3
trong NH
3


2
SO
4

2
.
A. etyl isobutirat B. metyl metacrilat
C. etyl metacrilat D. metyl isobutirat
Cõu 370. A
4
H
6
O

2


22
oo
H H O
truứng hụùp
Ni,t xt, t
A B C caosubuna



C
A. 1. B. 2. C. 3. D. 4.
Cõu 371. Đốt cháy hoàn toàn hỗn hợp 2 r-ợu no mạch hở, thu đ-ợc 15,4gam CO
2
v 8,1 gam H
2
O. Số mol hỗn hợp r-ợu là:
A. 0,01mol B. 0,05mol C. 0,1mol D. 0,2mol





Cp nht T4/2012

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LTĐH Tổng hợp Hữu cơ

23

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

K







Cuốn sách và giỏ đựng than








- 



- 



- 





- 



khi



- - - 
- - - 

C









“Tôi không bắt buộc phải chiến thắng, nhưng tôi bắt buộc phải chiến đầu đến cùng.
Tôi không bắt buộc phải thành công, nhưng tôi cũng phải nỗ lực hết sức mình.”

Lớp LTĐH môn Hóa Add: Nghĩa Hưng-Vĩnh Tường-Vĩnh Phúc Vi Nhân Nan

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