Chuỗi phản ứng hóa hữu cơ(hay)

(66)
CO
2
HOC-CHO [o] (54) CH
2
– CH
2
+Cu(OH)
2
(C
2
H
5
O
2
)
2
Cu Ag CH
3
-CH(OH)-COOH [C
6
H
10

O
5
(ONO
2
)
3
]
n
(-(CH
3
COO)CH-CH
2
-)
n
+NaOH(65) (- CH
2
-CH-)
n
+[O] (56) (57) + CuO,t
0
OH OH C
12
H
22
O
11
.CaO.2H
2
O axit lactic trixen lulozơ
t

0
,xt,p (64) ÷ polinylic HOOC-COOH Axit oxalic (55) (53)+H
2
O/NaOH (67) +AgNO
3
/NH
3

dd Xanh thuốc súng không khói
CH
3
COOCH=CH
2

Ag
2
C
2
$

OH
(59)

(58)

H
2
/Pd

C

2
H
4
+ KMnO
4
C
2
H
4
Br
2
(-CH
2
-CH-O–)
n
+CO
2
(68) (69) ezin Tơ viscozơ +HNO
3
/H
2
SO
4

+HCl +[O] +HCN CH
2
=CH-CN (49) +dd Br
2
poliete C
12

H
22
O
11
+I
2
(128) (129) (130)
C
2
H
5
OCH=CH
2
(63) +AgNO
3
/NH
3
(60) Nitrin acrylic +H
2
O/H
+
(71) (70) mantôzơ (127) tinh bột +NaOH ,CS
2
(62) (61) C
2
H
4
Br
4
C

2
H
6
(51) xt:Cr
2
O
3
/600
0
C 170
0
C, H
2
SO
4
+CaO.2H
2
O [C
6
H
10
O
5
]
n
H
2
SO
4

CaCO
3
+Br
2
t
0
,p (48) (50)+Cl
2
/as C
2
H
5
Cl (72) C
12
H
22
O
11
(126) +H
2
O/H
+
[C
6
H
7
O
2
(OH)
3

]
n
(1) t
0
+C
2
H
5
OH (9) CH
2
=CH–Cl (-CHCl-CH
2
-)
n
(52)+H, Fe/HCl +HCl(62) sac cazôzơ(đường mía) H
2
O/H
+
(125) (124)
CaO (5) (10) C
2
H
2
Br
2 +HCl
+H
2
,Ni.t
0
(49)

P.V.C
+NaOH (63) +H
2
O/H
+
CH
2
OH-(CHOH)
4
-COONH
4

(2) +C +Br
2
(7) (8) <– CuO/300
0
C (47) amonigluconat

+H
2
O CH º CH +H
2
O,HgSO
4
(6) CH
3
CHO +O
2
,Mn
2+

CH
3
COOH

+ O
2
,men C
2
H
5
OH men zimaza C
6
H
12
O
6
+AgNO
3
/NH
3
(131)
CaC
2
(3) AXETILEN 80
0
C (4) ETANAL - H
2
, xtđb (138) AXITAXETIC (73) RƯỢU ETYLIC (123) GLUCOZƠ 32
0

C (122)
+HCl (12) +Na +Na (121) (132)+H
2
/Ni,t
0

C
6
H
12
(11) +C /C
6
H
6
+CO,H
2
O (15) +CuCl
2
NaHSO
4
(46) (45) CH
3
COONa
CaO/NaOH

(74)
CH
4
+Na C
6

H
7
(ONa)
5
O (120) CH
2
OH-(CHOH)
4
-CH
2
OH
(44)+HCl (76) Chú ý Rượu sobitol
+H
2
/Ni(13) C
6
H
6
CH
2
=CH-COOH CH
2
=CH-C ºCH CH
3
CH(OH)-SO
2
Na (77) C
2
H
5

ONa * xt: xúc tác quang hợp,+H
2
O
Axit acrylic +CO
2
+ H
2
O (39) (66)Cu(OH)
2
xt:Al
2
O
3
140
0
C, H
2
SO
4
(78) * as: ánh sáng (119) +AgNO
3
/NH
3

+Cl
2
askt (14) +Br
2
khí C
6

H
5
OH
+NaOH
,
Na(38)
C
6
H
5
ONa 460
0
C C
2
H
5
OC
2
H
5
* askt:as khuyết tán CO
2

(16) CH
3
Cl +Na(19) Fe, xt t
0
,P +NaOH (43) +n HCHO , (42) (CH
3
COO)

2
Cu CH
2
=CH-CH=CH
2
CH
2
=CHCl-CH
3
Cao su buna H
2
Ag
C
6
H
6
Cl
6
C
6
H
5
Br +HNO
3
/ H
2
SO
4
+ dd Br
2

(41)C
2
H
5
OH/H
2
SO
4
+H
2
/ Ni,t
0
(79) +Cl
2
,as(118) +NaOH,t
0
(117) AgNO
3
/NH
3
(133
)
6.6.6 (17) (40) (116) +AgNO
3
/NH
3

+HNO
3
/H

2
SO
4
+CH
3
Br+Na (18) OH OH CH
3
COOC
2
H
5
CH
3
–CH
2
-CH
2
-CH
3
CH
2
=CH-CH
3
HCOONa HCOOH
(80) (115) H
2
SO
4
loãng
+H

+
,Fe/HCl(20) C
6
H
5
NO
2
C
6
H
5
CH
3
O
2
N NO
2
Br– –Br Cl
2
/askt (81)

crackinh xt,H
2
SO
4
H
2
O/H
2
SO

4
+NaOH (114)

(21)

toluen +Ca (
83
)
H
2 81)
Al
4
C
3
C
(91)nước,t
CO
ZnO(113)
+KMnO
4
(134)
C
6
H
5
COOH +KMnO
4
NO
2
(32) Br

$ CH
2
Cl–COOH (CH
3
COO)
2
Ca (84) (112) +H
2


axit benzoic +CH
2
CHBr+Na(22) Axitpicric (trắng) (37) +NH
3
CaO, 300
0
C 170
0
C

CH
4

clo,as (111)
CH
3
Cl
+NaOH (136)
CH
3

OH
oxi,Cu,xt(135
HCHO
(23) (88) (98) +O
2
/ NO,xt
CH
3
+HNO
3
/H
2
SO
4
P.S + nHCHO NH
2
-CH
2
-COONH
4
CH
3
-CH(OH)-CH
3
C
2
H
6
(33) CH
3

-CO-CH
3
(86) +H
2
/Ni,t
0

1500
0
C (97)

CH
3
COONa

t
0
,xt.trùng hơp (100)
O
2
N NO
2
C
2
H
3
Cl+Na(24) C
6
H
5

CH=CH
2
phenolfomandehit H
2
SO
4
l ,chưng cất (87) CuO,t
0
+NaOH CHºCH (-CH
2
-CH
2
-)
n
CH
2
-CHO


t
0
,xt,p

stiren

OH OH OH NH
2
-CH
2
-COOH CH

3
-CH(ONa)-CH
3
+H
2
/Ni,t
0
(96) (95) t
0
,xt OH
T.N.T
NO
2
CH
2
-CH -CH
2
– - CH
2
– Na /NaOH (35) CH
3
CH
3
140
0
C, H
2
SO
4
(89) CH

2
=CH
2

trùng hợp (94)
CHºC-CH=CH
2


½ (25) (26) n (34) +HCl
CH–O–CH
CH
2
=C(CH
3
)–COONa

+HCl ,(99)


C
6
H
5 n


C
6
H
5

NH
3
Cl NH
2
-CH
2
COONa CH
3
CH
3
+ Na (90) t
0
,p,xt,(93) CH
2
=CH-CCl=CH
2

polistiren +C
4
H
6
,t
0
,p NH
2
+NaOH
+HCN ,xt (103)
CH
2
=C(CH

3
)–COOH (-CH
2
-CH=CCl-CH
2
)
n

-CH
2
-CH=CH-CH
2
-CH-CH
2
-

O
2
N NO
2
(30) +HCl (36),+NaOH (C
6
H
5
NH
3
)
2
SO
4

(91) +CH
3
OH cao su clorôpen CH
3

½
NH
2


H
2
SO
4
nguội

CH
2
=C(CH
3
)–COOCH
3 xt,p,

t
0

(92)
C- CH
2

C
6
H
5
n (28)
NO
2


Br

Br

$


NH
3
Cl-CH
2
-COOH C
6
H
5
NH
3
HSO4 (31) +H
2
SO

4
COOCH
3 n

(27)
Cao su buna –S +HNO
3
/H
2
SO
4
Br
2
(29) Br (trắng) t
0
, xt,p(137)(tạo chuỗi polipetit) (-NH-CH
2
–CO – NH- CH
2
–CO -)
n
C
6
H
5
NH
2
plexiglasses
SƠ ĐỒ PHẢN ỨNG HOÁ HỮU CƠ

B
iên
so
ạn:

L
ê
Ng
ọc T
ú

.
(
0
915469911
-
037856028