Nghiên cứu cải tiến quy trình điều chế dung dịch siêu oxy hóa và ứng dụng trong khử trùng nước thải bệnh viện (Luận án tiến sĩ)
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-------------------------------
- 2018
-------------------------------
Chuy n ng
M
:
62 52 03 20
1.
PGS.
2.
PGS.
trong Khoa
Khoa
-
,
PGS.TSKH
-
m
C
Nam)
,
,
ANK (Activated Neutral Anolyte)
BOD (Biochemical oxygen Demand): N
COD (ch
oxy
DNA (deoxyribonucleic acid): axit nucleic
EPA (
FEM (flow-through electrolytic module
HAAs (Haloacetic acids): Axit Haloacetic
MB-
-11
MDL (
MQL:
Direct Current): N
ORP (Oxidation reduction
OSHA (the Occupational Safety and Health Administration)
PAC (Poly Aluminum Chloride
QCVN:
SMEWW (Standard Methods for the Examination of Water and Waste
Water):
.
electrochemistry)
Supowa (Super-Oxidized Water): D
TOC (Total Organic Carbon): C
THM: trihalogen methan
VK: V
PA
PC
........................................................................................... 6
................................................ 6
...................................................... 6
.................................. 19
............................ 25
............................................... 32
................................................. 32
.............................................. 36
..................................... 37
............................... 37
........................................................... 38
......................................... 40
...... 41
.......................... 46
............................................................................... 46
..... 46
1.1.
1.1.1.
1.1.2.
1.1.3.
1.2.
1.2.1.
1.2.2.
1.3.
1.3.1.
1.3.2.
1.3.3.
1.3.4.
2.1.
2.2.
2.2.1.
............................................ 46
2.2.2.
................................................................................... 51
.................................. 52
........ 54
2.2.3.
2.2.4.
2.3.
..................................................................................... 54
2.3.1.
55
2.3.2.
BOD5
2.3.3.
amoni,
......... 56
............................................................................................................... 59
2.3.4.
2.4.
2.5.
3.1.
3.1.1.
............................................................................................................... 59
........................................................................................ 60
....................................................................................... 61
.............................................................. 65
.............................................................. 65
............................................................................. 65
3.1.2.
catolit
............................................................................................................... 75
3.1.3.
3.1.4.
3.2.
3.2.1.
3.2.2.
3.2.3.
3.2.4.
3.3.
..................................................................... 83
...................................................................................... 91
supowa..... 92
................................................................................. 92
...................................................................................... 96
................................................................................ 97
...................................................................................... 98
................................................................................................................... 99
3.3.1.
3.3.2.
3.3.3.
............................................. 99
......................... 113
.................................................................................... 129
..................................................................................................130
................................................... 132
........................................................................................... 134
..............................................................................................................................12
..............................................................................28
................................................32
.................................................................................36
......................................................................64
...............................................71
........72
.....................................81
..................................................................................................................................................81
c
......84
..................................................................91
-11 ........................................................95
..........................................................................................98
9.
coliform
...........................................................................................................................111
10.
...........................................................................................................................112
......................................................................................................120
..................................................121
3
................................................................................................................................................123
3
..................................................................................123
......................124
3
..................................................................................124
15.
...............................................................................................................................7
ng cong th
a m t ch
22
............................................................................................................................................12
-11................................................................................13
.....................19
............................................................................................................21
o
.................22
-30-ECO-C ..........................................................23
ts
u ch anolit c
AWA-D-
2.1.
2
.......26
.............................................................27
29
-ANK-PRO-01 ........................................................................47
-11 ................................................................................49
...........................................................................................................................56
4
+
...............................................................................................................56
5
...............................................................................................................57
..............................................................................................................................57
.........................65
2
.......................................................................67
.....................................................................................................................................68
..............................................................................................................68
................70
.....................71
................................................73
ng c a s
d
n c a dung d ch catolit
9
..............75
10.
s
catolit
..77
1.
..................................................................................................................................................77
12
....................................78
3
.................................79
4
o
................80
5
...............................85
6
............................86
7
................88
8
19
..........................................................94
20.
.....................................................................94
1
xy
-11 ...........95
2
......................................................................................................96
3
11.................................................96
4.
.............................................................................................................................................99
5.
...............................................................102
6.
..105
7.
+
NH4
.........................................................................................................106
8.
BOD5
.....................................................................109
9.
c
.........................................................................................................111
30
.......................................114
1
....................................115
2
................................................................................................................................................116
3
..117
4.
...........................................119
5
.................................................126
36.
..............................................................................127
1
-
,
-
-
M 3 [1-9]. Cho
-
-
un MB-11
2
-
-
- oxidated water,
-11
Tuy
-11
un MB5
,
natri hypoclorit (NaOCl), hay canxi hypoclorit (Ca(OCl)2) [10]
nhi
ra, d
clo
halogenmethanes
[11-14];
3
[10]
1
O2, O3
[15].
:
+
:
-
+
-M;
;
4
+
h
.
+
:
h
h
, pH
+
.
-
-
-
-11;
5
-
supowa
N
o
,
,
40%.C
6
1.1.
1.1.1.
1.1.1.1.
[16,17]
25
anolit
[9].
[18]
minh
[1]
:
7
[19].
[17,20]
1.1)
1. S
[18]
t
o
o
: HClO, ClO-, Cl , HO , HO2 , H2O2, 1O2, O , Cl2, ClO2, O3
8
o
o
[21].
o
[1]
[ ]
9
[3]
1
10
d),
a),
a).
-
2.
[21]:
-
[16].
c
a
-
[20]
11
[7].
[3].
1.1.1.2.
[22].
su
12
[23]
STT
1
~45
tan- mg/L)
2
~300
~500
3
> 800
> 800
4
pH
6,5
5
6,5
5
S
3V).
-
-
An
a,
3.
b,
-3 (a)
(b) [21]
,
13
-11 [21]
4.
-
-
BT1-00
oxy trong
2-x
2
Ru-Sb, Ir-Ru-T
8
b
V
-11
[24]
14
[25].
1.1.1.3.
.
o
cao c
o
, 1O2, H2O2, O22-, HO2 , HO , ClO- v.v...[26]
,
ng o
[16]
H2O2 + Cl-
[Cat(MPO)]
HOCl + OH-.
(1.7)
2O2
2
anion, O2- - superoxit-anion, HO2 -
- anion hydroperoxit, O22- - peroxit, HO2- anion
hydrogen peroxit
H2O2 + OH-
HO2- + H2O
(1.8)
