đề thi thử đại học lần 3 của trường chuyên quảng trị

so
cD
-
ET
euANc
rRI
rnUoNG
THPT
cnuYnn
t 0
euV
nON
on rul
THUDAI
HOC
rAN
IIr
NAM
HQC
2012-2013
MONHOAHQC
Thdi
gian
lhm
bdri:90
phrit. MA
DE
THI
003
ni6t H= 1 He=
4, C=

12
,N=
14, O=
16, Na= 23,
Mg=24, Al=21;
'
Cl=
35,5, Ca=.40, Fe
56, Cu= 64' Ag:
108,
Ba=
137
oEnAr
I
ciu 1: Trong mQt
c6c nu6o o6
hod tanb
mol
ca(HCo3)2 vi
b
mol
Mg(HCo3)2, o6
tdm mAm nu6c trong
c5c
cAn ding V
lit nudc v6i hong,
ndng dQ
p
mol/lit.
Bi6u thfc

li0n hQ
gita
V v6i a,
b,
p
li:
A.V=(a+b/2p.
B.V=(a+2b)/p.
C.V:(a+b)p.
D.V=(a+b)/p.
Ciu 2:
Cho m
gam
X
g6m
Fo, FeO,
Fe:O+, FezOg vdo 400
ml dung dich HCI
2M,
sau
phin
img
thu
iluo.
c
2'24
lit
Hz
(dktc),
dung dich

Y, vd 2,8
gam Fe kh6ng taq, Gi4 tri
m ld:
A.22,4
8.30,0
c.27';2
"
D.25,2
c6u 3:
Tyrosin
c6 c6ng thr?c
p-HO-C6Hr-CHz-CH(NHr)-COOH.
Cho 0,1 mol
Tyrosin t6c
dgng v6i 300m1
dung
dlchNaOH
lM thu
d,rg" dung dlch
X. 56 mol HCI cirn
dnng irc
phAn ring vria ttri v6i
dung dloh
X ln
A, 0,2 mol
B. 0,3 mol
C. 0,4
mol
D. 0,1 mol
CAu 4: X c6

vdng benzen
va
iO
CtpT
ld CqHrOz. X
tdc dgng vdi durig'dleh
brom
thu dugo
chAt Y c6 c6ng
thrlc
ph6n
trl
ld csHeozBrz.
M[t kh6c, cho
X tic dgng vdi
KHCO: thu
du.c mu6i Z
c6
cTPT
li CeHTO2K
Hdy cho bi6t X
c6 bao nhiOu
c6ng thfc cAu t4o
?
A.5
8.3
c.4
D,6
Cflu 5:
Ti6n

hinh
c6c thf nghiQm
sau,
c6 bao nhiOu
thi nghiQm
thu
dugc
ttit
tua
(l)
Sqc
khf H2S
vdo
dung
dich
FeSO+
(3)
Spc khf
CO2
(du)
vdo
dung dich
NazSiOr
(5)
Nh6
dung dich
NHr
d6n du vdo dung
dich Alz(SO+)r
(2)

SUc
khi
H2S vdo dung
dich
CUSO+
,
/
(4)
Spc
khi
COz
(du)
vdo
dung
dich Ca(OH)z
V
(6)
Sgc khf
H2S vdo
dung dich
Fez(SOq)3
'''
(7)
Nh6
t*
tu dung
dlch Ba(OH)z du viro
dung
dich A12(SO4):
(8)

SUc
Cz}{+
vdo
dung
dich
KMnO+
I
A.6
8.5
c.4
D,7
Ciu 6: Dung
dich
CHTNHz
co khe nAng
phan
rmg
voi t6t cd cric
ch6t trong
dly irdo sau
cl6y?
A. FeCl:,
H2SOa,
CH3COOH,
HNO2.
B.
C6HsqNa,
HzSOr,
CHgCOOH,
HNOz.

C.
C2H5OH, HzSO+,
CH:COOH, HNO2.
D' Na2CO3, HzSO.r,
CI{rCOOH, HNO2.
CAu 7:
Thriy
phdn
109,449
mantozo trong m6i truong
axit
voi
hiQu suAt
phdn
r?ng
il4t 60% thu
tluoc h6n hqp
X.
Trung
hda
h6n hop
X bing NaOH thu itu-o. c h6n hgp
Y. Cho Y t6c dgng
vdi dung dlch
AgNOTNH: du <lun
n6ng thu ducr.
c m
gam Ag k6t tria. Gi6 tri ctra m ld:
A. 110,592gam
B.

138,24gam
C'82,944garn
D'69,l2gam
CAu 8: Hdn
hqi X
gdm
etilen
glicol,
ancol etylic, ancol
propylii
vi
hexan trong d6
si5 mol hexan
bing s6 mol
etilen
glicol
cho m
gam
h5n hgp X kic dgng vdi,N,a
du thu duo.
c 0,4032 lit
I{z
(ttktc).
M}t kh6c d6t m
gam
h5n hqp X can 4, 1664
lit 02
(tlktc).
Gi6 tri cria m li :
l

A.2,384
B. 1,788
c.2.682
D.2,235
dung dich
Z
vit
5,376lft
(<Iktc)
h6n
htry cua
NH4NO2
vi
NH+NO3
)
.
Co
A.
20,58
8.32,57
c.32,68
D.
20,84
,
trong
cl6 s6
mol
cria ion
Cl- le
0,07. Cho

ll2
CAu 10: Dung
dich
X chfra c6c ion: Ca'*, Nan,
HCO; ve
Cl-
C6u 9:
Cho
m
gam
Al t6c dpng
v6i dung dich.HNO3
lodng du
thu
dugc
hqp khf
X,Y c6 ti kh6i
so vdi
hidro
le
16
l
nitit X,
Y ld sAn
phAm
phdn
can dung
dich Zthu dugc
8,3m
gam

mudi
khan.
Gi6 tri
cua m
lir:
dung dich
X
phin
img v6i dung dlch
NaOH
(du),
thu tlugc
2
gam
k6t t[a. Cho
l/2 durl,g dich
X cdn l4i
phA.n
img voi dung dich
Ca(OH)z
(.du),
thu ttuo. c 4,5
gam
k6t
tira.
MAt kh6c,
n6u tlun s6i
tl6n c4n
dung d[ch X r6i
nung d6n kh6i luqng

kh6ng d6i thi thu
ttuo. c m
gam
chdt
rrn. Gi6tri ota
m ld
A.
5,48
8.8,625.
c.
6.865.
D.6,645
ciu 11: S9c 4,48
lit khi
co,
(dklc)
vdo 2 lit dung dich
h6n hqp Ba(oH)
r2xmol/l
vd NaoH
x
mol/I.
Sau khi
c6c
phAn
rlng xAy ra hoin
todn
thu dugc 19,7
gam
klit tua. Gi6 tri cia x li:

A.0,025.
8.0,025 hogc 0,03.
C.0,025 ho{c
0,02.
-D.0,03.
Ciu 12:
Cho c6o
ch6t :CH3-COOH:N-CH:;
AI(NO:):; NaHS;
KzSO:;
(NII+)zCo:;
H2N-CH2-COOH;
Zn(OH)z;AlzO:.
56
ch6t dAu t6c dyng dugc
vdi dung dich HCI vi
dung dich NaOH ltr:
A.5
8.7
c.6
D.4
Ciu 13: Khi nung
butan v6i xrrc t6c
thlch hqp d6n
phdn
ung hoAn
todn thu dugc
h5n hq'p T
g6m
CH+

CrFIr,
CzH+,
CzHo,
C+Flr, Hz
vi
C+Fls. E6t ch4y hoin
toan h6n hqp T thu duo.
c 8,96 lit CO:.
(do
d
dk.rc) vd 9,0
gam
H2O' Mit kh6c,
hdn
hqp T
hm
m6t mdu vua h61
19,2
gam
Br2 trong dung dlch nudc brom.
PhAn trem
vd
s6 mol oua
C+[Ie
trong
T
li:
D.
8,33370.
Trang l/5

-
Ma
eC
ttri
OO:
A.16,670
.
8.9,091Yo.
c.22.22%.
ciu
l4:
Diiy
c6c
dung
dich
ndo,
sau
d6y.
khi
itiQn
ph6n
(rliQn^cp
tro,
ming
ngdn)
c6
sg
tdng
pH
cria

dung
dich
A'
NaoH,
KNoTKCI'
n
N3gu,
i-agra,
Hdi.*t.H"so"
rcr,
r.r.ft]l
il1rt'i,
,i6i,,
rNo,.
:ii"l::Sli:^i""s"ri,8,:.3Tloi:l-t'rsoo'ioane'aoir'u"iii".9""r.0.'".n
*.
Tryn*
"i"
iJu
"r,a,
sau:
AgNo3,
A. 6
*";'
**or.
KJ,
ttrS.
s6,
cndt
tec

dsng
vdi
dung
dich
X
ld:
!:.1 lu: J'"q
*"
oung
apr"#xc,9;_,,51yri*,
"39tr,1
Nu,co,,
veo"rrt;"l^"
"cooNHn,
,r(2er2e7.
(NH4)'?so3'
cHroH
vi
AsNo3'
Hev
cho
bict
dun;
Jlni
ii6iii"
a*,
tr'Ec
v6i
bao
nhi6u

dung
dich
rong
diau
kiQn
tlrichhqp?
n"
-'*"*"-*="'"':".:ttacovngouqcvdibaonhi6udung
A"
l0
8.9
.
c.
11
D.8
ru.il-,ffsff#,lfl
fr
"ru*ff
Hi:"r$ggt*r+,ro,n.roan-uor*snskhrAvuadnkft
her
HrSoa
giem
xu6ng
cdn
44%o.
ptrariui'#i.r-;;'#::J1T
l"/,
P^p,thtr
vao
8'8

sarn
dd
HzSor
98%
rhi
dd
axit
A-
1429.
"Liin
trnm
the
tich
cq
mng
f'5"
r'o[iilf'ff,thu
vdo
8'8
etn
ai
fi's
cau
18:
cho
c6c
dung
dich
':::ygf,
roo,,

*.5,,'i,ilb!_I,,qt,Al?(sgd?
lr;ft",
.
chen
cdu
.ring
A.
C6
3
dung
djch
ldm
qui
tfm.
h6"^y"h
-'
-
-'";.,'cO'lroung
O;"t
tr{c
dung
vdi
HCI
C.
c6
3
dung
dich
tric
dung

v6i
NaoH
il.
ii
i o*g
oi"h
tdm
qu'
tim
h6a
d6
cau
19:
Hdn
hsp
X
sdm axiia*etic,
etyr
axerat
vd
#,ri
"i._*,
ch9;n
gam
hon
h'p
X
tdc
dgng
vira

ttri
vrli
i"HH
*ifj*JiglujY;"u19*'
g{*'
l';*.ilril
gam
hdn.ilqp
X
"d;V
ii
ii,rao,o
sau
'6
cho
A.
re,60
rrr
".1t
oi;n,)"o"
au
*riv
fhe,1yngl""c
;i;h6;40j
r".n.
[1u
oi
cda
V
rd:

ciiu
20:
cho
oan
bdne
*"
r*"i'1{,_rar;:
ro,
(k)
+
;,'df #
.co
(t)
*
",&rt
aru
trl
"
,
o
Khi
hQ
dang
d
."eng
th6i
cin
u4'e'
tr"
co"e

'itii,
o""e
i;
ve"
e
:""i(,1
,#,
,iirir.,
uo,
rr^l'ri,r,
mQr
ruqng
hoi
:ffi',['#il
rlp
sult;
(4)
ding
chdt-xric
d,'?iii'#''ioTidl,e
co,.
rric
dQng
rdm
cen
blrng
chuy.n
dich
theo
_

A" (l),
(5)
B.(5)
Cf,u
2l:
Cho
10,0g
lit (rlktc)
hdn
hgp
khf
X
hdn
ho-p
Y
chi
chtra
:
iria.*urUon.
Ti
khdi
hqp
X
r ^ _9.Q\
(3),
(4)
D.
(l),
(3),
(5)

g6m
CzHz
vd
H3
{l
qll
6ng
chfa
xnc
;#
Nt,;ung
n6ng
thu
dusc
cta
Y
so
v6i
He
ld
7,125
.
ffnn
%
th61in'",i"
CzHz
trong
hdn
A.36,73
B.^4-4,44

c.
+s,ss
D.
62,25
;
c6u
22:
Dung
dioh
X
chuao,03-mol
cusoa,
o,oz
,no]
ri"tso;)3-vd
0,08
r"r
H'crriic"
hrirnh
triQn
phin
dune
ll'"i
A,li:j:,',t'ril-H;
i',:l
;T
ff.;laTti;c$:iliT;o'i;o
aoi,e
dii"
s,;i

A, ii,!
,,"r,
ru,i
tn,
aso"
E
A.
t,456
t*
vi
t,68
mm
B.1,008
lit
vd
2,48
uum
C.
1,003
lt,
u.".
a:L6^
ryo
D.
I,456
tit
vd
1,92 gam
ciiu
23:

H6n
hep
x
edm
|
,*g
yl
r
*r."".
6r,"'ite"lu."g."
i,toi
mn,
titi"l
"i"
rr€n phan
rimg
hoan
;"rt'l,l"tffi*,[T"Jo*JTl.kltFe
at
J
H;i;;i
I
[ia-"""u
odi
*rffi;
todn
y
r6i
cho
s6n

thdnh.
c6ng
thrirc
,0"
,
;',u.lli#6i1uqng
btnh
dpng
nudc
v6i
,-G
,i";
#;i'
"i
"o
r
s
gam
k6t
tua
rao
A.
CsHro
vd
CsH',
q.C2Ft6
vd
C2FIa
C,
Callle

vd
CaHs
D.
C2Hs
vd
C3FI5
Clu
24:
-CJro
cr{c phuong
trinh
phan
,ing
.uu-,
v!
v1'r
l.
AI(NO3)
+
NaOH
du
+
&.*
t:_*
"
3.
Cl2
+
NH3(khf)
du

_+
X5
+
X6
2.
fNaA(OH)4
I
+
HCI
du
+
X:
+
X.
.
V
+.
r"
iagtjOr
au
+Xu
+
Xr
.u"1?r1'ul1
n*
"hat
crla
Al;
x'
h

t'qp
"h6t
",i"
i'.,
vaiil,
xr,
xr,
x.
na
xr,rr"o
thr
tu
thuoc
day
nio
hbng
'
A'
[NaAl(OH)q
];
Al(OH)r;
N]l+_Cl;
Nz;
Fe(NOr)z
U.
tNa1J!.O-p+-l;
AlCt:;
HCI;
Nu;
Fe(No)3

c.
Al(orDr;
Atcl:;
NHaCt;
N:;
re0.lti:l:
'
-"'
i.
fr+,(oH)r
l;
Atclr;
NH+C,;
Nr,
Fe(No:):
ciu
25:
cho
h6n
hop
M* Ar
"r
F"
"i:
gyrr-gi"rr
eei'o'rr,frophan
,:mg
ho#
toa;ir,i,'a'.is
"r,6t

"i"
X
vd
duns
dich
Y.
Cho
dung
dich
i
re"_
ayng
v,:,i
NaO'g
au
ti
airg-rct
tua
Z.
Nung
Z
trong
k{r6np
kt6ng
it6i
thu
tt_usc
tr6n
hqp
r cfid

r
"r,a,
"i"
u,i
*""
ii
llr'a?:
ii:;li"*,'i.vl
or'.
".
"/,'il1i
ill.:
f:f."
"nu".*.iJ*1*
t'h6r
tuq"!
c.
Mfl,
Fe3*,
Ag*.
ceu
2e:-crro
z,q
c;',
hu"
nT^T^qli,
i,".or
u*
.noo"5da",,t}
5t

ff;ung
n6ng
(phnn
rmg
hodn
toan)
sau phdn
ung
rh6v
thoi
t'ong
chdi
.in giam
r,z
gun,.
ajh;on
hgp
sriur phdm
o,o
dgng
v6i
AgNo3
du
trong
NH3,
<lun
n6ng
thu
dugc
m gam

Ag.
pi6-hi
pnf
tfr
"ta
mia,
-
,/
A-64,8
n.n,e/
''
a:s;.i
ciu
27:
Trong
car
"rrdt
ouiai,
.i
bao
nhieu
ch6t
m;'iillr.r,at
ao
"o
*c
on?"4*?,e,
da
2
mor

NaoH.
(l)
cH:coo-ceHs
(z)
crsN-*i,cooy+^
11
ctcH,ai-si-
i+liio-iJn
iri,l"oii'
"
G)rHzN-cH:coo-cH3
(6)
cr-cH,coo_'cir,cr
rffi? r,L,i,iyii'i'#,i,:6i'io_HN_cH2cooH
Trang
2/S
-
Ma
dra
thi
003
Ciu 28: Cho
c6o
phan
rmg sau:
(a)
KMnOr+HCld{c t khiX
O)
FeS
+I{2SOalodng

+
khiY
(c)
N}I+HCO:+Ba(OH)2
+
khiz
(d),KhiX+khiY
+
r'inR+khiE
(e)
KhiX+khlZ
+
LhiE+khic
Trong s5 cric khi
X, Y, Z, E, c 6 tr6n,
c6c khi tric dpng voi
dung dich NaOH d ttidu kiQn rhuong
td
A,X,Y,E B.X, Y,E,G
C.X,Y,
G D.X,Y,Z,E
CSu
29: Cho c6c ch6t sau : axit
acrilic, metylmetacrilat,
vinylaxetat,
phenol,
anilin, etylfomat,
axit bezoic. C6
bao
nhi6u

ch6t
t6c dqrng duo.
c
vdi
ci dung dich
NaOH vd nudc brom
?
-
A.6
8.3
c.4
D.5
Ci\ 30:
Thriy
phdn
h6t I luqng
pentapeptit
trong
m6i trudng axit thu tlu. c 32,88
gam
Ala-Gly-Ala-Gly;
10,85
gam
Ala-Gly-Ala; 16,24
gam
Ala-Gly-Cly; 26,28 gan
Ala-Cly; 8,9
gam
Alanin
cdn lqi li Gly-Gly

vi
Glyxin.
Ti lQ s6 mol Cly-Gly:Gly
Id l0: I . T6ng
kh6i luqng Cly-{ly
vd Clyxin trong h6n hqp
sdn
phdm
li:
A.29,7
8.27,9
c.
28,8
D.
13,95
CAu 3l:
X vd
Y tlAu
h d6n xu6t
",ia
benzen
c6 c6ng
thric
phdn
trl ld CaHroOr. X t6c
dpng voi
dung
dich
NaOH
theo ti lQ mol nx:

nNusH
=
1 : l Cdn Y
tric dungvSi dung
dlch NaOH theo tj lQ
mol ny: nNuon
=
1 :2.
C6ng
thilc cdu t4o
thu
ggn
cira
X ve Y
lA
A. CH3-O-CHz-CoH+-OH
vd CH3-COO-CoHs.
C. CH3O-CHzCoH4-OH
vd CzHs-C6H3(OH)2.
Cflu
32: Cho scl
dO
ph6n
ftng:
+NaoH
>
(xz)
+
c2H4(oH)2
CH3COOH

*t,"'
>
(X)
-je-+
1yr)
C6c chdt
Xp
vd Xz l6n
lugt ld:
A. CH3COOCHBTCH2BT
vd OHCCHzOH
C. CH3COOC2H3
vA OHCCH2OH
CAu
33r
Cho ankan
X t6c dpng vdi
clo thu cluo. c 53
gam
h6n
hqp c6c ddn xu6t clo
(mono
vd diclo). Khi HCI
bay
ra
tlugc
h6p thy hodn todn bdng
nu6c sau d6 trung
hOa bing dd NaOU *r4y
t6n h6t SOO ml

dd
NaOH
2M.
Xric dlnh c6ng thrio cia
X?
A. C:Hs
B.
CH4
C.
C2H6
D. CaHls
CAu
3-l:
Tron
g
citc
phan
img
sau,
c6
bao nhi6u phAn
fng
tgo
ra
don chAt
?
(a)
Cho khi
03
t6c

dr,rng
voi dung
dlch KI.
(b)
NhiQt phan
amoni nitrit.
(c)
Cho CUO
t6c dpng
v6i NH3
dun n6ng.
(e)
Cho
khi
NH3
t6c
dgng vdi
khf Cl2.
(h)
Spc
khi
Cl2
vdro dung
dich
HBr.
B. CHr-O-C6Ha-CH2OH
vd
CzHs-C6H3(OH)2.
D.
CH3-C6H4-COOH

vd
CzHs-COOCeHs.
B.
CH3COOCzH:
ve
(CHO)2
D.
CH3COOCzHT
vd CH:COOCHBTCH2BT
(d)
Cho khi
H2S
t6c dgng vdi
dung dich FeClr.
(g)
Cho
khi
Cl2
vdo
dung dich HzS
.
(i)
Cho
NaI
trlc dUng
vdi
dung
dich axit H2SO4 d{c,
n6ng.
D. CH3COOH

FeClr,
SOz. Khi
sqc khf H2S
qua
5
dung
(k)
Cho
dung dich
HzOz tric
dpng
v6i
dung
dich
chfa KMnO+
vd
HzSoa
(lodng)
A.6
8.9
c.8
'
D,7
CAu
35: Chdt A c6 c6ng thric.phdn
tri
CaH6O2.
Cho m
gam
A

phan
rmg vtra thi v6i dung
dich ohrla 2
gam
NaOH, t4o ra
4,1
gam
mu6i. K6t ludn
ndo sau
ddy ld dring cho chdt
A
A. A c6
phrin
irng tr6ng bqc nhung
khdng
ldm,m0t mdu nu6c brom
B.
A c6
phAn
irng tr6ng bac
vd c6 lim
m6t mdu nudc brom
C. A khdng
tham
gia
phrin
img
trring bac nhung
c6
ldm

mdr mdu nuoc brom
D. A c6
khd
ndng ldm
tl6i miu
qu!
tim thanh d6
C6u 36: Cho
m gam h6n hqp
X
gdm
Mg, Al, Zn vd Cu trlc dung h6t
voi dung dich HNOr thu du<r. c dung
dlch
Y
(kh6ng
c6 mu6i
amoni) vd I 1,2 lit
(dkrc)
h6n hqp khi Z
(gdm.
N2, NO,
N:O vi NO2, trong tl6 N2 vd NO2
c6
phdn
trdm th6 tich blng nhau)
c6 ti kh6i d6i
vdi heli blng 8,9.
56 mol
HNO3

phrin
fng ld
A.
3.0 mol.
8.3,2
mol. C.3.4
mol.
D.
2,8 mol.
y CAu
37:
Nguy6n tt Y c6 e cu5i cirng
xtip vdo
phdn
ldp
3d, 6 lugng tu
thri
I li
e
gh6p
tl6i.
K6t
lu6n
nio sau
dAy ld sai :
'
A.
56 hi6u ngtt Y li 26
B. C6 4e ilQc thdn
C. Y c6 3

lfn
elootron D.
C6 6 electron
d
.
Cirl
38: Hda tan hodn todn h6n
hqp
gdm
0,1 mol
Al vi 0,15 moi Cu trong
dung dich HNO3
loang thi
thu
duo. c
0,07
mol h6n ho.p
X
g6m
2
khi kh6ng
miu vd dung dich Y. C6 c4n Y
itugc 49,9
gam
hdn trqp mu6i.
S5 mol
HNO:
dd
phin
fng li

4.0,67
B. 0,75
c.0,73
D.0,72
CAU 39: Ddt
chdy
hodn
todn 2,76
gam
h6n hgp
gdm
C,HTCOOH,
qHyCOOCH3,
CHrOH
thu do. c 2,688
lit
'
CO,
(tlktc)
vd 1,8
gam
HrO. MAt khdc, cho2,76
gam
X
phAn
ring vla dfi v6i 3oml
dung dich NaOH
lM,
thu
tlugc 0,96

gam
CHTOH. Cdng
thrlc cria RCOOH
li
A.
C2HsCOOH
B.
C2H3COOH
c. c3HscooH
CAU
40:
C6 5
dung
dich sau
:
Ba(OH)2, FeClz
,
Pb(NO3)2, CuSOa,
dich
tr€n,
c6 bao
nhi6u trudng
hgp co
phAn
f'ng
sinh
ktit
tua ?
A.3.
B. 1.

C,4
D,2,
Trang 315
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MA
dC thi
003