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Nghiên cứu tổng hợp, cấu trúc, tính chất một số dãy phức chất của platin(II) chứa safrol, safrol khép vòng và amin (TT)

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:j8:`:T/l::/idd/0kPf:C
/•/NRdd€3/?S3//9::j8UVd?@T/l::/idde34/fTkPf:C
f?y./`Hj/%H/5"&>(/z"(,^"dHr(>,./,\"a
W3kW0dS23o^1mv34kPf:T/P=34T/`Td/0Ž3hfSde34/fTT/l::/id/8S3/^3
UwS:j8Th8dS3'(:/l8?8uONh~/ŒT;}34Šd
B
h
B
'8uF(
B
‹'C(;5kq34/X:=:/x:/N
T/Y3l34:/01y3/78+Šdh
G
'8u(‹'WC(d/53/CC
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T/l::/id:=Th8dS3:/l8?8uONh;58US3mR34transŠdh
B
'8u('&U(‹'m>1W(FT/l:
:/id:=Th8dS3/8S3/^3:/l8?8uONh~/ŒT;}34Šd
B

h
B
'8uF(
B
‹BGT/l::/id:=
Th8dS3:/l8?8uONh~/ŒT;}34;58US3mR34Šdh'8uF('&U(‹'m>1   ;5 p(C
M
/53/T/W3:i0dOp::j8:`:T/l::/idk>kPf:o`:kX3/3/QT/@S/fTT/P=34T/`T
?ƒ:~zZY3U•34o`:kX3//5UhPf34340123d@T/^3d€:/T/e•"T/e•
T/eT/e
F

FG
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k=3dS3/d/yC
/g343ŒdkVk`N;qU“d:i0dOp::j8:`:T/l::/idk>kPf::/l34US3/h56

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mtTONdN3/78'8uF(T/@SdO€~/ŒT;}34;wSd'(3/QhS23~xdGd^Ur08•:j8
3/7U8hh1h;5hS23~xd”;wSM:j83/^3Zt3•t3/8S340123d•:hNk734;8SdO}h5
:W03@S4Sg8/8S3/^3C
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3/7U8hh1h:}38US3|;XdO€transk@S;wS3/7U8hh1hC
„:`:T/l::/idm>1;5p?8uONhmtTONdN3/78'8uF(T/@SdO€~/ŒT;}34
;wSd'(3/QhS23~xdGd^Ur08•:j83/7U8hh1h;5hS23~xd”;wSM:j83/^3
Zt3•t3:}38US3|;XdO€cisk@S;wS3/7U8hh1hC
7d/yT/^3ZS[d/8S:i0/s3/U58US3|;XdO€cis;5;XdO€transk@S;wS3/`3/
8hh1hmv8;5NT/e
F
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mR34/8Sk…34T/^3:i0mR34C
>d/•kV:d€3/dxZ5N:j8FGT/l::/idk@S;wSAm}34dxZ5N034d/PC+xdr0Y
:/Nd/i1:`:T/l::/idkq0:7~/Y3]34l::/x?vT/`ddOSy3:j8FBM/N“:Am}34
dxZ5N034d/PC“:ZS[d:`:T/l::/idWQ&>pe:7/NRdd€3/OidUR3/k@S;wS:`:
m}34dxZ5N034d/PkPf:d/•;wS4S`dOXME–F—4˜UhC
e?G"x""dH2
 0Ž3`34…UZ8T/W36T/W33VSm034:/€3/'FDGdO834(d5ShS[0d/8U~/YN'‰
dO834(;5T/W3T/nhn:'FB‰dO834(Cnd/y6
VSm034:/€3/:j8h0Ž3`34…U6GdO834U|kW0BGdO834de34r083BGdO834d/v:
34/S[U;5:`:T/P=34T/`T34/S23:l0‡FdO834~xdr0Y;5d/YNh0Ž3BdO834~xd
h0Ž3FdO834m83/Un::`::<34dOs3/:j8d`:4SYCN53ZVT/W3351:7AM/s3/;5MA
ZY34C
5ShS[0d/8U~/YN6‰†d5ShS[0dON34k7:7F†d5ShS[0dSx34-S[dM†d5ShS[0dSx34
&3/Bd5ShS[0dSx3448C
/W3T/nhn::j8h0Ž3`34…U6T/e•"T/e4SY3k…T/^3d€:/3/S[dT/e
T/e
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FG
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*•$T/eO81k=3dS3/d/y~xdr0Yd/•/NRdd€3/kV:dxZ5NC
/ h.D{FwW
=hPf:;qT/l::/id:=~SU;5;qd/0@:Th8dS3:/g8dOX034d/Pds3//s3/de34/fT;5
34/S23:l0:`:T/l::/id:=~SUTh8dS3'(NhtuS3ZY3:/idhS23~xd;5d€3/:/idT/e:j8
:`:T/l::/idTh8dS3'(NhtuS3C
A
/ h.8|}K=~==•€w
`::/id34/S23:l0dON34h0Ž3`3kPf:de34/fTd/tN?=k…|/s3/BCFC
8u6?8uONh//mU6/™3/fTm034U<S†*



A
6†SmONoSr0S3NhS3'WQIpe(š
W1,h56
B&US3NT1OSmS3'B
B
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B
('D( NOT/NhS3'NO('q(
Btd1hr0S3NhS3'Bt‘0('W8( "SUtd1h8US3't
B
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B
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B
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A

D
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B
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B
('Wf( "Std1h8US3'•d
B
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B
('D(

B&US3Nd/S8•Nh'•('WeIpE( S:hN/to1h8US3'e( ThN83ShS3'Dh/
B
('8(
B&US3NZt•Nd/S8•Nh'_d•('WEIpq( STtOSmS3'ST('E( TNd83ShS3'D/
B
('f(
B&US3NAUtd1hZt•Nd/S8•Nh't_d•('WqIpo( o;m;p-Nh0SmS3'BšGšDt/
B
('eIEIq(
B&US3NAUtdNoSZt•Nd/S8•Nh't*_d•('WopQ( UšT&3S•SmS3'GšDt*/
B
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8?D?m./!3"""/0(7
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B
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B
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A
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G
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B

D

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G
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T/`TU<dYdON34:`:d5ShS[0:/0123~/YNC
8?D?D?m./!31G,XM,ML•=(2
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G
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B

D
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G
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B
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'•('We(š B&US3NZt•Nd/S8•Nh'_d•('WE(šB&US3NAUtd1hZt•Nd/S8•Nh't_d•(
'Wq(šB&US3NAUtdNo1Zt•Nd/S8•Nh't*_d•('Wo(C

8?8?8?m./!33/a""/0(•=(2P<HURPQ9F,R‚PWQR
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8?8?f?m./!33/a""/0(•=(2P<HURPMR‚2PWnR
+Šdh
G
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8?8?e?m./!33/a""/0(•=(
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G
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B
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B
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B
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D
'8u(
B
'
B
Š
B


D

B
(‹›B+h
2.3. Nghiên cu tng hp phc cht cơ kim hai nhân safrol
khp vng-Pt(II) (B0)
8?f?D?./,\"a( h.(""dHWC&*,W.
f
B+Šdh
G
'8u(‹›D&4*
G
œŠd
B
h
B
'8uF(
B
‹›D&4h›B+*
G
›B*
G
8?f?8?./,\"a( h.(""dHWC&*,<2
8

B+Šdh
G
'8u(‹›3h
B

œŠd
B
h
B
'8uF(
B
‹›+h›+3h
G
›Bh
8?f?f?./,\"a( h.(""dHWC&*,L
B+Šdh
G
'8u(‹œŠd
B
h
B
'8uF(
B
‹›B+h›Bh
 +*›hœ+h›
B
*
8?f?e?./,\"a( h.(""dHWC()%./…/!3O.1;,H2"%29 *"
B+Šdh
G
'8u(‹ Šd
B
h
B
'8uF(

B
‹›B+h›Bh
8?f?E?./,\"a( h.(""dHWC()%./…/!3O.1;,VM(%9 *"
B+Šdh
G
'8u(‹ Šd
B
h
B
'8uF(
B
‹›B+h›Bh
8?f?q?./,\"a( h.(""dHWC()%./…/!3O.1;,,%VH9 *"
B+Šdh
G
'8u(‹ Šd
B
h
B
'8uF(
B
‹›B+h›Bh
8?e?m./!33/a""hj,1HU)%2j/k3&l.g=(PR(ƒC&>H1,#k%PO„AR
8?e?D?m./!33/a""/0(•=(2P<HU9DRPW1R‚PD oR
Šd
B
h
B
'8uF(
B

‹›B&UœBŠdh'8uF('&U(‹
&U6ONT1h8US3'D(š"SUtd1h8US3'8(š"Std1h8US3'f(šS:hN/to1h8US3'e(š
STtOSmS3'E(šNOT/NhS3'q(š_t3•1h8US3'o(C
8?e?8?m./!33/a""/0(•=(P<HU9DRPMR‚2PQR
Šd
B
h
B
'8uF(
B
‹›Bt3œBŠd'8uF('t3(‹h
8?E?m./!33/a""hj,1HU)%2j/k3&l.g=(PR(ƒC&>H1,(/h1PO„AR
e34/fTT/l::/idŠdh'8uF('&U(‹'D Q(d/tNT/P=34dOs3/T/Y3l34?806
•d
B
h
B
'8uF(
B
‹›B&UœBŠdh'8uF('&U(‹
&U6&3ShS3'D(šThN83ShS3'8(šTNm83ShS3'f(šo;m;p-Nh0SmS3'eEq(š
UšT&3S•SmS3'oQ(C
8?q?m./!33/a""/0("hj,1HU)%2j/k3&l.g=(PR(ƒC&>H1,O[&l.
PO„ApR
8?q?D?m./!33/a""/0(•=(2P<HU9DRPW1R‚PpD pfIpE pQR
 Šd
B
h
B
'8uF(

B
‹›B&UœBŠdh'8uF('&U(‹
&U61OSmS3'pD(šB&US3NT1OSmS3'p8(š‘S3NhS3'pf(šB&US3Nd/S8•Nh'•('pE(š
B&US3NZt•Nd/S8•Nh'_d•('pq(šB&US3NAUtd1hZt•Nd/S8•Nh't_d•('po(š

B&US3NAUtdNo1Zt•Nd/S8•Nh't*_d•('pQ(C
8?q?8?m./!33/a""/0(•=(P<HU9DRPQ9F,R‚PpeR
 Šd
B
h
B
'8uF(
B
‹›B'†*‘0S(œBŠd'8uF('†*‘0S(‹›Bh
8?o?./,\"a"0()i"&>(c/"/0(
8?o?D?"3/ h.3/3V"[/(/>/3/7"""/0(
8C/P=34T/`T?ƒ:~zZY3U•34
ZC`:kX3//5UhPf343Pw:~xddS3/
:C`:kX3//5UhPf34Th8dS3'd(
8?o?8?"3/ h.3/33/:(c"//,'6,
8C/P=34T/`TT/e•"'•3tO41mS?TtO?S;tO81?Tt:dON?:NT1(
ZC/P=34T/`TT/^3d€:/3/S[d
:C/P=34T/`T•
mC/e/…3434NRS'(
tC/e:V34/P|34d{/Rd3/^3'
F

FG
‘_*•$ž(
uC/e3/S’0oRdS8k=3dS3/d/y

8?o?f?/B1Ol/%6((c/,//5"
`:T/l::/idWDW8WfWEWqWQ8oQpDp8pfpekPf:dSx3
/53/d/•kV:dxZ5NC
/ h.f?L†Fw‡‡wˆ
f?D?m./!3&>"0()i""dH3/a""/0("hj,1HU)%29=(PR9H1,P‰JWR
f?D?D?,rj,'&>j](Š$(m./!3
`:8US3:7m034hPf34T/@SdO€UVdd`:mn34;wS+Šdh
G
'8u(‹d/tNr01h0Žd
Y3//P|34trans/S[0l34trans:j8NhtuS3hw3/=3:j8h

;s;Ž1?Y3T/ŸU:j8T/Y3
l34? :7:i0dOp:trans6
-wS8US3h56B8US3NT1OSmS3'B
B
1(d/0kPf:WDšBUtd1hr0S3NhS3'Bt‘0S(
d/0kPf: W8‹T
A

D

B
'DT/
B
(d/0kPf: WfšB8US3Nd/S8•Nh'•(d/0kPf:
WešB8US3NZt•Nd/S8•Nh'_d•(d/0kPf:WEšB8US3NAUtd1hZt•Nd/S8•Nh't_d•(d/0
kPf:WqšB8US3NAUtdNoSZt•Nd/S8•Nh't*_d•(d/0kPf:WoC
-wS8US3†/SmONoSr0S3NhS3~/Sd`:mn34;wS+Šdh
G
'8u(‹d/y/S[3m034hPf34

T/@SdO€Bd/0kPf:WQd/tNT/P=34dOs3/T/Y3l34GCB6
-wST/@Sd•h5tdSht3mS8US3d/0kPf:T/l::/idWn6

-wS8US3h5dtdO8UtdSht3mS8US3d/0kPf:T/l::/idWDC6
`:T/Y3l34GCF GCDkq0kPf:dSx3/53/|kSq0~S[33/S[dkVT/}34d¡h[UNh
WC6&US3d{F6FFkx3F6FBdON34m034U<Std83Nh;53Pw:C+xdr0YkPf:d7Udƒd|
ZY34GCFC
_Y34GCFCVd?@d€3/:/id:j8:`:T/l::/idWD WDC
f?D?8?N"[/(/>/3/7"dH""3/a""/0(O„AW
H?=/ h.3/3Œ"j•#$1Ž.
`:T/l::/idkq0kPf:dS3/:/xkx3~/S:/NUVd;[d493m013/idC
#?N"[//>12 !.=(I/>12 !. *"j]((,/
`:T/l::/idWDW8WQWnWDCkPf::/p34d<So`:kX3//5UhPf343Pw:~xd
dS3/d/tNUn:BC‰CFCZC+xdr0Y:/Nd/i1:`:T/l:kq0~/<34:/l83Pw:~xddS3/C/l:
:/id WQk>kPf:o`:kX3//5UhPf34dd/tNUn:BC‰CFC:C/tNd/v:34/S[U/5U
hPf34ddON34WQh5GA†Gˆd€3/d/tN:<34d/l:Šdh'†*


A
('8u(‹h5GAGDˆC
"?=/ h.3/3pN
/e•":j8WQ:/Nd/i1d¡h[ˆ340123d•h˜dd€3/d/tNd/v:34/S[Uh5E†˜FC
¡h[h˜dd€3/d/tN:<34d/l:dh'†*‘0S('8u(;5dh
B
'8u('†*‘0S(hW3hPfdh5
F˜F;5B˜FCSq0k7:/Nd/i1†/SmONoSr0S3NhS3k>ZXmtTONdN3/78;5T/@SdO€~/ŒT
;}34;wSd323|T/l::/idWQ:/¡:7UVd340123d•hC
O?=/ h.3/3p<K<Pp2M"()%3)HA%,tH(,%KH<3M"()%1M()AR
/e:j8WE:/Nd/i1T/^3d•~/@S:j8WEh5M‰‰T/•/fT;wS4S`dOXd€3/
;wS:`:k…34;X/5UhPf34hw3;53¢U4Sg8

US3
•M‰A;5
U8o
•M†‰C-Ž1WET/•
/fT;wS:<34d/l:mv~Sx36Šdh
B
'
FE

FE
*
B
('


A

B
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_Y34GCB†C€3/S[0

FG
:j8:`:8US3dON34T/l:De q
δ
'TTU(
f?e?q?=/mp<J&>"0()i"j/;..,H"dH""3/a""/0(O„A
/e*•$:j8:`:T/l:DeEqIQ:73/g34;^34S8N:/l34US3/
:/N:i0/s3/cis:j8:/p34C
O23:=?|T/^3d€:/d/53/T/W3d€3/d83T/e
F

FG
;5T/e*•$
:/p34d<Skq34/X:i0dOp::j8:`:T/l::/idD Q3/P/s3/GCDGC
•/f?ef?0()i""dH""3/a""/0(D•Q?
f?E?m./!33/a""/0("hj,1HU)%2j/k3&l.9=(PR(ƒC&>H1,O[&l.
PO„ApR
f?E?D?,rj,'&>j](Š$(m./!3
+/S:/N:`:8US3mX;}34d`:mn34;wSCd8:\34d/0kPf::`:T/l::/idk=3
3/^3C-wST1OSmS3'1(d/0kPf:pDš8US3h5B8US3NT1OSmS3d/0kPf:p8šr0S3NhS3
d/0kPf: pfš†/SmONo1r0S3NhS3'†*‘0S(d/0kPf: pešB8US3Nd/S8•Nh'•(d/0
kPf: pEš  B8US3NZt•Nd/S8•Nh  '_d•(  d/0  kPf: pqš  B8US3NAUtd1hZt•Nd/S8•Nh
't_d•(d/0kPf:pošB8US3NAUtdNo1Zt•Nd/S8•Nh't*_d•(d/0kPf:pQkq0|
mR34cisC
f?E?8?N"[/(/>/3/7"dH""3/a""/0(O„Ap
O23T/e•":j8p8;5pe:/Nd/i1d¡h[ˆ340123d@h˜dd/tNd/v:34/S[U
:j8p8h5E†B˜F;5:j8peh5~/<34:7hC+xdr0Y351~/`T/•/fT;wS:<34d/l:
:j8p8h5Šdh'8uF('B
B
1(‹;5:j8peh5Šd'8uF('†*



A
(‹C
/id'mU( FF FB FG FD FM FA F‰
D‹D
¨
'8( FDF†B FGEE‰šFB‡‡G FBF‰E FBMB†šFB‰BM FBF‰E FGEE‰šFB‡‡G 
e‹e
¨
'8( FDEMF FB‡‰G FGF‡F FBMAD FB‰GG FBFB† F†G‡
E':( FG‡E‰ FBE‰G FG‡‡F FBABB FB‡DF FF‰E‰ BFG†
q':( FGADA FGEFE FBEEE FGMEB FBEE FGEFE BE‰M
BG
O23T/e~/@S:j8p8:/Nd/i1T/^3d•~/@S:j8p8h5D†‰3¢U4Sg8
US3
•D†D
;5
U8o
•D‡FT/•/fT;wS:<34d/l:Šdh'
FE


*
B
('
M

A

B

(‹C
+xdr0Y:/Nd/i1po:7~/@ShPf34T/^3d••MMM3¢U4Sg8
US3
•MMD;5

U8o
•M‰ET/•/fT;wS:<34d/l:mv~Sx3Šdh'
FE


*
B
('




B
*(‹C
f?E?f?=/m/-..%6,&>"0(6%""3/a""/0(O„Ap
+xdr0Y:/Nd/i1|:`:T/l::/idpD£pQd'(T/@SdO€;wS8US3r083Sd=mX;}34
U5~/<34r083/7U
B
k…34d/QST/@SdO€;wS?8uONhr083/`3/8hh1hC
f?E?e?=/m
D
K&>"0()i"""3/a""/0(O„Ap
`:TONdN3:j88u;58US3dON34:`:T/l::/idpD£pQ3/PkPf:hS[d~2dON34
ZY34GCGBGCGG;5GCGDC
_Y34GCGBC€3/S[0:j8:`:TONdN3†‡;5FE:j8pD£pQ

_Y34GCGGC€3/S[0GMA;5‰:j88uT/@SdO€|pD•pQ
_Y34GCGDC€3/S[0TONdN3:j8:`:8US3mX;}34dON34:`:T/l::/idpD•pQ
/id'mU( &US3 FB FG FD FM FA F‰ F† 
B
/0(
PO1R
†8 †Z ‡ FEtrans FEcis
pD
pD
Y
'Z(
BADmš
2
JF‰
B‰†m
G‰Gmm
2
JF‰š
3
JMM
D†AUšMFEU
2
J
PtH
‰M
G‰‰m
3
JFGM
GA‡m
3

JMMš
3
J
PtH
‰M
p8'8( B‰GU
G‰‰mm
2
JFAMš
3
JA
D‰MU
2
J
PtH
‰M
G†Gmš
3
JFG
2
J
PtH
A‡
G‰Gm
3
J‰Mš
2
J
PtH
A‡

pf'8(
B‰š
2
JF‰
3
J
PtH
FFE
G†Dmm
2
JFAMš
3
JMM
D‰MU G‰MU
G‡Bm
3
JFEM
pe'8(
B†Dmš
2
JF‰
3
J
PtH
†‡
GAFšmm
2
JFAMš
3
JA

D†AU
2
J
PtH
‰M
G‰Emš
3
JFGMš
2
J
PtH
AM
DBGm
3
J†š
2
J
PtH
‰B
pE'8(
BADmš
2
JF‰
3
J
PtH
FEE
G‰Bm
2
JF‰

D‰‰U
2
J
PtH
‰M
G‰Dm
3
JFGM
G‰Mmš
3
J†
2
J
PtH
‰M
pqPHR
BAMmšBAAm
2
JF‰š
3
J
PtH
FEE
G†BmšG†Bm
2
JF‰
D†‡UšDA‡U
2
J
PtH

‰M
G†GmšG†Gm
3
JFGM
G‰FmšG‡Bm
3
J‰š
2
J
PtH
‰M
po'8(
BADmšBA†m
2
JF‰š
3
J
PtH
FEE
G†BmšG†Bm
2
JF‰
D†‰UšDA‰
U
2
J
PtH
‰M
G‰‡mšG‰‡m
3

JFGM
GA‡mšG‡Em
3
J‰š
2
J
PtH
‰M
pQ'8(
BAMmšBA†m
2
JF‰š
3
J
PtH
FEE
G†BmšG†Bm
2
JF‰
D††UšDA‰U
2
J
PtH
‰M
G‰‡mšG‰‡m
3
JFGM
G‰EmšG‡Fm
3
J‰š

2
J
PtH
‰M
/0(
PO1R
G M A ‰8 ‰Z
pD
pD
Y
'Z(
AAF?
AA‰?
 A†D?šA‰†?š
3
J
PtH
G† M†F†?šM†DG? M†B?šM†M?
p8'8( AMD?  ‰EE?š
3
J
PtH
DFM M‰†mš
2
JF M†Emš
2
JF
pf'8( AAE?  ‰E‡?š
3
J

PtH
DF M†Fmš
2
JF M†G?š
2
JF
pe'8( AM‡?  ‰EA?š
3
J
PtH
GD M†Gš? M†Gmš
2
JF
pE'8( AMG?  A‡‡?š
3
J
PtH
ME M‰‡mš
2
JF M‰‰mš
2
JF
pq'8( AMA?šAM‰?  ‰E†?š‰ED?š
3
J
PtH
ME
M†F? M†E?
po'8( AMM?šAM‡?  ‰E‰?š‰ED?š
3

J
PtH
ME M†F? M‰‡?
pQ'8( AMA?šAM‰?  ‰E†?š‰EM?š
3
J
PtH
ME M†B? M†E?
BD
pD
pD
Y
P#R
†‰Dmm
†AEmm
3
JAM
4
JFM
‰AGmm
‰DDmm
3
J
α
AM
3
J
γ
‰M
†EBdd

‰†A
3
J‰M
4
JFM
‰AGmm
‰DDmm
3
J
α
AM
3
J
γ

‰M
†‰Dmm
†AEmm
3
JAM
4
JFM
  
p8
PHR

A†Mmm
3
J†M
4

JF
‰MAU
3
J‰
4
JFM
A‰BU
3
JA
4
JFM
†E‰mm
3
JMM
4
JF
 
ADB
ZOC?
pf
PHR
‡F‡
ZOC?
‰‰AU
3
J†
†AMm
3
J†
†FAm

3
J†
‰‰‡r
3
J†
4
JF
†EB
d
3
J†
‡FM
ZOC? 
pe
PHR
†DGm
3
JDM
‰ABmm
3
JDM
†MBm
3
J†M
‰FMm
3
J†
‰MMd
3
J†

‰FE
m
3
J†
 
pE
PHR
 
‰FMm
3
JD
A‰Mm
3
JD
   ‰BAZOC?
pq
PHR

†EFm
3
J†
†FMm
3
J

‰BDd
3
J†
‰BDd
3

J†
‰DGd
‰DMd
3
J†
‰‰Dm
‰‰Mm
3
J†
 
‰‡FZOC?
‰‰‰ZOC?
po
PHR

‰††m
3
J

†EBm
3
J

‰BMm
3
J†
‰BMm

3
J†


‰MD?
‰MD?  BG‡?
‰‰‡ZOC?
‰AA
ZOC?
pQ
PHR

‰‡Em
3
J

†EDm
3
J

‰EDm

3
J†
‰EDm

3
J†

‰GA?
‰GM?  G†D?
‰‰FZOC?
‰M†

ZOC?
f?E?E?=/m
Df
KI3/m/H,"/,r&>"0()i"""3/a""/0(O„Ap
_Y34GCGM:/Nd/i1dON34:`:T/l::/idpD£pe?vo0id/S[3kW1kjFEd€3/S[0
:8:ZN3:j8?8uONhC
{;S[:T/^3d€:/|dO23:/p34d<S~xdh0Ž36ON34:`:T/l:m>1pd'(T/@SdO€
;wS?8uONh;{8Z¢34hS23~xdZ8d^U;wS3/7U•8hh1h;{8Z¢34hS23~xd 
σ
;wS
340123d•M:j8;}34d/=UC
_Y34GCGMC€3/S[0
FG
:j8?8uONhdON34:`:T/l::/idpD£pe 'TTU(
_Y34GCGAC€3/S[0
FG
:j8:`:8US3dON34:`:T/l::/idpD pe
δ
'TTU(
/id'mU( 
F

B

G

D

M


A







FE
pD'Z( FDBDM FDD‡G FED†‰ FDFGF FBDFG FFGMF ‡‡MG G‰A‰ †‡EM ABBD
p8'8(
FDG‡B FDAB† FEMDM FDF‡‰ FB‰G† FFBA‡ FEEM‰ G‡ME ††‰B ABAA
pf'8( FDGM† FDM‰B FED‡† FDEME FB‰‰M FFDEM FEEEE G‡FA FEM‡M AFEE
pe'8( FDDE‡ FDA‰M FEM‰‰ FDGBE FB‡B† FFBA† FEEAG G†G‡ ‰‡‰‡ MAGD
/id'mU( &US3 FB FG FD FM FA F‰ F† F‡ BE
pD
'Z(
FMED‡
FD‡†‡
FBAB†
FBDGE
FG‡EF
FGA†A
FBAB†
FBDGE
FMED‡
FD‡†‡
   
p8
'8(

FM‡MM FFDMM FG‡MM FFDAB FD†FD    
pf
'8(
FMF†‡ FBBFE FG†‡ FB†D‰ FB†FD FGFM FGEE‰ FDM†‰ FGEE‰
pe
'8(
FDAE‰ FBB†G FG‡MD FFDA FFAG‡ FB‡B† FA‡AM FDDG† FGF†‰
BM
_Y34GCGM;5GCGA:/Nd/i1|:`:T/l::/id34/S23:l0:7kW1kjd€3/S[0
FG
:j8
?8uONh;58US3dON34:W0T/@SdO€C
O23T/e
FG
:j8pD:7BZVd€3/S[0UVdZV:7:PQ34kVhw3/=3l34;wS
k…34T/^3cis:7/5UhPf34:8N/=3C_Vd€3/S[0T/n? kPf:otUoŒd|Un:GCAC
 ?91J$K"#=)MNLD;<=J J0
O23T/e*•$:j8:`:T/l:pDIp8IpfIpe&>pE:/p34d<S:\34d/i1:7
3/g34TS:4S8N/SmON:j88US3;wSFEcis;5‡C-Ž1:/p34kq0|;XdO€cis?N;wS
3/`3/8hh1h:j8?8uONhC
O23:=?|T/^3d€:/d/53/T/W3d€3/d83T/e
F

FG
;5T/e*•$
:/p34d<Skq34/X:i0dOp::j8:`:T/l::/idpD pQ3/P/s3/GCD†C
•/f?eQ?0()i""dH""3/a""/0(pD pQ?
f?q?0/•/&>"0O6."dH""3/a""/0(./,\"a
+/S:/N+Šdh
G

'8u(‹'WC(d`:mn34;wS8US3:`:hNRS'&U(d/s?Y3T/ŸUd/0
kPf:h5:`:T/l::/id:7:i0/s3/trans'm>1W(C
 V:/01y3mX://78/9::j8:`:TONdN3†‡;5FE|:`:T/l::/idcis-
Šdh'8uF('&U(‹;5transŠdh
B
'8u('&U(‹kPf:hS[d~2|ZY34GCG‰C
_Y34GCG‰CV:/01y3mX://78/9::j8TONdN3†‡;5FE|T/l:34/S23:l0
 _
Y3 4
GCG‰:/Nd/i1k@S;wSB:“TT/l::/id:•34T/@Sd•~/`::i0/s3/3/PWf˜fpe˜E
:\343/P:`:m>1T/l::/id~/<343/idd/Sxd:•34T/@Sd•3/P34~/`::i0/s3/3/P
8o89Q;5WDWDCd/s?v~/`:ZS[d4Sg8:i0/s3/cis;5:i0/s3/trans:\34
OidO«O534;5:7d€3//[d/@34Cnd/yh56
„:i0/s3/cis6 ©'†8(–B‰TTUš ©'‡(–D†TTUš ©'FEtrans(–©'FEcis(–DETTU
„:i0/s3/trans6 ©'†8(¬GETTUš ©'‡(¬METTUš ©'FEtrans(¬©'FEcis(¬DGTTU
Lc/,' <34d/l: †8 †Z ‡ FEtrans FE-cis
f cisŠdh'8uF('D/
B
(‹ BMF GD† DDG GMM D‰M
Wf transŠdh
B
'8uF('D/
B
(‹ GEB GG† MDA DMM DD‰
pE cisŠdh'8uF('•(‹ BAD G‰B D‰‰ G‰G G‰D
We transŠdh
B
'8u('•(‹ GBD GM‰ M†F D†B D‰E
89o cisŠdh'8uF('&U(‹ BD†BAE GDEGAM DAGD‰‰ GM†GAD G†EG‡D
89Q cisŠdh'8uF('&U(‹ BDFBMF GDGGM‰ G‡ADDG GMBGA‡ GDEG‰M

WD9WDC transŠdh
B
'8u('&U(‹ GEBGGF GDAGAD MGMM†B DD‡D‡F DG‡D†G

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