Tải bản đầy đủ (.doc) (106 trang)

Chế tạo màng ZnO tạp chất (In,N) bán bẫn loại p bằng PP phún xạ magnetron DC, kh.sát các yếu tố ảnh hưởng đến cấu trúc, tính chất điện và tính chất quang của màng bán dẫn loại p

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Lu 1
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
 !
"#$%
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1.1 Tổng quan về màng mỏng dẫn điện trong suốt 10
1.2 Vật liệu ZnO 10
/012345-.
//678494:;28;45-.<
1.3 Cấu trúc vùng năng lượng của ZnO 17
1.4 Tính chất điện và quang của ZnO 18
&=0>4?@9-.A
/&=0B19;@9-./%
"#/$/A
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2.1 ZnO pha tạp loại p 28
2.2 ZnO pha tạp nitơ (ZnO:N) 30
//JK;@9L4M7N0123@9OP;-.$<%
///JK;@9L4M7N=0B19;@9OP;-.$<
//<&Q;B19ROSTU;2VW8OP;-.$</
2.3 ZnO đồng pha tạp donor – acceptor 34
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H"#HHHXYIZ&[.<A
\P8&10
Lu 2
3.1 Khái niệm về phún xạ 38
3.2 Phún xạ magnetron phẳng 38
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<//018?O9;^28L_;<`


3.3 Các phương pháp đo 40
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<<<HJM;L6L>8977
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<<!HJM;L6L4h1]49YiY[j!
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<<lHQ6m;7Jn;49Yl
<<AHJM;L9cLLo4cLUD9c]9;JM[1^2p82die9q9^24;
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4.1Quy trình chế tạo bia gốm dẫn điện ZnO pha tạp In 53
4.2 Hệ tạo màng trong quá trình phún xạ 55
4.3 Các bước chuẩn bị trước khi phún xạ tạo màng 61
<(162V]y7>Wk
</(162V]y7e49k/
<<6eT2=e49r>Wk/
4.4 Kết quả và bàn luận 64
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DANH MỤC CÁC BẢNG
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z;>SL9 L4M 98œ qU;26q:4829 6 94:;eN28;
OP;˜™
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98‡+jr9^L824M>5>>Jne6d{784L7JK;\oa>Jn]^O
J7PL9LL‚Š;wO†>=7P;4‚O;7Jn;9d^71;>58Ÿ;nL
Š28;O;45-.Jb9P;J‰;•qWnL@94MP8
28;OP;˜!k™w˜!l™
HJM;L6L>z;L9L>ž>Jn•O3;U46Ld†;PW8
PU;OP;-.$i+wje6d{784L˜k™&1a4N28;U;2V2Nw
3;U4 O•4d‘;744?;4NŠ1‚JK;@9|7?q=
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~2j
f;J‚JK;@9aW1T4?>S>W07Jn;784L@9OP;
\P8&10
Lu 9
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e6e{784Le“;LJM;L6LL3]O9;^28•9D89c9caNc1Uc9D
JMD;>Ncoc121cw4coc>4N9F=0B19;1D9O9F;e9cdoƒ7894L&4WL
†‚44?MŸ9=0>4?@9OP;Mc4U;4N1NDJ91$
b Nc98e49;UcO-.L99L+i4d41OjMc4Mc4qUc47JM;L99LJFb
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b &4WL†q‚8674‚JK;@9|7?q=
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~2jMD4R1OŠ>S
q691
b •9D89c‚JK;@9aW1T4?>S>NDo;98oc7JM;1D9O9F;
b J•>š1Nc984NcL]1cd4NDLb-.}bs49Fq9D89c>JMF;>2J;
+b>ND>9c;49coc7JM;1D9O9F;e9cdoƒ7894L
b 6qWB1‚@93;U4>Jn]6>ŽU;B196LŒL>84?>4$
LŒL>8LQ21aRB19b4wLŒL>8LQ4h1]49YiY[jwL^cL>8LQ
6m;7Jn;iZsjwLŒL>8LQL6B19;HwLŒL>8977wLŒL>8eT
Of4dgwLŒL>8eRdPae“;LJM;L6Lsa71w>8>‡2J;+b@9OP;>Jn
82N>Ws4749F>e4N79FL^cL>86];Jn[1^2p82di[sj
\P8&10
Lu 10
CHƯƠNG 1:
TỔNG QUAN VỀ VẬT LIỆU ZnO
1.1 Tổng quan về màng mỏng dẫn điện trong suốt
•5‘O`%lwq4•Ÿ;e6868>š14NROP;8]49dO41O
id.j28;1Td{>4?w>ž••L6245qU;;‘;Rq¡1;4NŠ1
f;JW874?1•Ÿ;=0>S>68Pas•;49;RT7Jn;
;4NŠ1P•e4W>Q487•@9q¡1W8OP;e“;4R1LJM;
L6Lq6917POSO4Š;8•L6245@9OP;O:;d{>4?
28;1TVWwOP;O:;d{>4?28;1T7P>T4Jn;;4NŠ1>ša3
ŽP13>Jn204R1•B19oO@96Lg;=;4?O2NW;4•4
74?1-.•q‚;d{>4?Jq4O784J;7428;1T28;‹;
q‚q4WJ60>4?OU48>‡>45OPaOPOP;28;1Td{>4?•
204R1Š;d†;J$‚Oe4Wq=w4?>4?2K28;1T8y9QO6ae9aw
OP;m>4?wOP;m4h1>4?‘w;JM;L‚]4?8y9Qw6

PLš0L†7¢7•9828;?14?O‡2‰4w>4?•28;1T8
OPV45Ž457:;ijwZŸ1Mi.ZjwOPVL79O9wL4
O‡2‰4d•92Ns4U>ŽV—
1.2 Vật liệu ZnO
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8
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4Nw-.20dh928;d1;dŽ9]=P9>Jn28;d1;dŽq4RO˜™
-.7PnL0e6d{9401y++b+w7Pe6d{784•>S2S;‹;
0O7•Z;•<<l^wK4?>SLg;•41a5OŠ_;w45e0>_;
J•;P•OS2†B19;¢&45-.28;1Tw0L124N;KeJ•
•;7•M<l%Ow•44W10¤/%%APqU;d{>4?K>4R1q4?eV
J‰;˜™
\P8&10
Lu 11
;8P429w45-.g•=6L>4?P4?m4?9awJK;6L
d†;-.P8L4284f;>9;>Jn^8>1Q444R1Lg;=;4?O
2NW;4•4
1.2.1 Cấu trúc tinh thể ZnO
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\P8&10
Hexagonal wurtzite Zinc blende Rocksalt
Hình 1.1 012345-.
Lu 12
\P8&10
Lu 13
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1.2.2 Các loại sai hỏng trong tinh thể ZnO
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\P8&10
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;8P4678494:;q52Nw28;45f;z4OST94:;
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\P8&10
Lu 15
Hình 1.4.as94:;>J‰;Hình 1.4.b s94:; e4N
Jaw28;45-.z46Ž2=2T;8]aP6;1aNy
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S6q6>50a>Jn4?8P6q1aW7P6L‚Š;
•9¢K4V4?8P6q1aW••oe“;]‚a296L‚Š;
•9¢q1aW>T4•44?8P6q1aW28;02mL‚41o
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