thi thử hoá chuyên Bắc Ninh lần 1 năm 2014

Trang 1/6 - 899
SỞ GD&ĐT BẮC NINH
TRƯỜNG THPT CHUYÊN BẮC NINH
Tổ: Hóa học
(Đề thi gốm 06 trang)
ĐỀ THI THI THỬ ĐẠI HỌC LẦN 3 NĂM 2014
MÔN: HÓA HỌC
Thời gian làm bài: 90 phút;
(60 câu trắc nghiệm)
(Ngày 03/03/2014)


Mã đề thi 899
Họ, tên thí sinh:
Số báo danh:

H = 1; C = 12; N = 14; O = 16; Na = 23; Mg = 24; Al = 27; S = 32; Cl = 35,5; K = 39; Ca = 40; Cr = 52; Mn = 55; Fe =
56; Ni = 58,7; Cu = 64; Zn = 65; Br = 80; Ag = 108; Sn = 119; Ba = 137; Pb = 207.
I. PHẦN CHUNG CHO TẤT CẢ THÍ SINH (40 câu, từ câu 1 đến câu 40)
Câu 1: 
6
H
10
O
5

X + 2NaOH

Ct
0
2Y + H

2
O; Y + HCl



Z + NaCl
 
2
?
A. 0,15 mol. B. 0,075 mol. C. 0,1 mol. D. 0,2 mol.
Câu 2: sai 
A. 

B. 
C. 
D. 
Câu 3: 
- 
2

- 


A. C
2
H
4

2
H

2
B. C
3
H
6

3
H
4
C. C
4
H
8

4
H
6
D. C
3
H
6

4
H
6

Câu 4:      
2
O) sau: H
2

N-CH
2
-COOH; HOOC-CH
2
-CH
2
-CH(NH
2
)-
COOH;H
2
N-CH
2
-COOK; HCOOH; ClH
3
N-CH
2
-
A. 4 B. 3 C. 6 D. 5
Câu 5: 

A. MgCO
3
+ CO
2
+ H
2
O 

Mg(HCO

3
)
2
B. Ca(HCO
3
)  CaCO
3
+ CO
2
+ H
2
O
C. CaCO
3
+ CO
2
+ H
2
O  Ca(HCO
3
)
2
D. CaO + CO
2
 CaCO
3

Câu 6: 
A. 
B. 

C. 
D. 
Câu 7: 
C
4
H
6
O
2
C
4
H
6
O
4
C
7
H
12
O
4
C
10
H
18
O
4
X
2
+ Y

1
+ Y
2

1
 ; Y
2
không

A. X
1
 B. X
3

C. X
2
 D. X
4

Câu 8: 

A. 
B. 
C. 
D. 
O
2
, xt
+Y
1

, xt H
2
SO
4

+Y
2
, xt H
2
SO
4

+H
2
O, xt H
+

X
1

X
2

X
3

X
4

Trang 2/6 - 899

Câu 9: 
Ni
2+


dm
2

3
.
A. 0,066cm. B. 0,033cm. C. 0,066mm. D. 0,033mm.
Câu 10: 
2
O
3
, Fe
3
O
4


2
SO
4


2
 
A.  B.  C.  D. 
Câu 11: 

2
, Cu(OH)
2
, Ni(OH)
2
, Zn(OH)
2
, Al(OH)
3


3

A. 3. B. 5. C. 4. D. 2.
Câu 12: 
-
A. 6 B. 7 C. 8 D. 9
Câu 13: 
A. 
3

2
SO
4
-
B. - 
C. 
D.
-bromanilin.


A. 2. B. 3. C. 5. D. 4.
Câu 14: 
2
SO
4


4

A. 
B. 
C. 
2

D. 
Câu 15:  
-amino-4-
-Val-

A. 7 B. 9 C. 6 D. 8
Câu 16: Este X no,   mch       bc.   0,1 mol X 
        dung  c  trong  cha 0,22 mol Ca(OH)
2
th vc k ph X  dung dch NaOH thu c 2 ch hu    
  t  nhau.    ng c oxi trong 
A. 37,21%. B. 53,33%. C. 43,24%. D. 36,36%.
Câu 17:  
2
, MgCl
2

, Na
2
SO
4
, MgSO
4
, CaSO
4
.

A. dd CaCl
2
; dd (NH
4
)
2
CO
3
. B. dd (NH
4
)
2
CO
3
;

dd BaCl
2
.
C. dd BaCl

2
; dd Na
2
CO
3
. D. dd BaCl
2
; dd (NH
4
)
2
CO
3
.
Câu 18: Cho 400 g
3


3


A. 0,27M. B. 1,2M. C. 0,7M. D. 0,13M.
Câu 19: 
+
; 0,5 mol Ca
2+
; 0,3 mol Mg
2+
; 1,5 mol HCO
3

-
; 0,4 mol
Cl
-


A. Na
2
CO
3
. B. HCl. C. Ca(OH)
2
. D. Na
2
SO
4
.
Câu 20: 
H
2
N-CH(CH
3
)-CO-NH-CH
2
-CO-NH-CH
2
-CH
2
-CO-NH-CH(C
6

H
5
)-CO-NH-CH(CH
3
)-COOH.

A. 
Trang 3/6 - 899
B. 
C. 
D. 

-amino ax
Câu 21: 

3
/NH
3

0,35 gam H
2
. 
A. 8,66 gam. B. 4,95 gam. C. 6,93 gam. D. 5,94 gam.
Câu 22: 
3
O
4


3




A. 268,2gam. B. 368,1gam. C. 423,2gam. D. 266,9gam.
Câu 23: t    x gam    hai axit cacboxylic hai ch mch   u
m  kt i C=C trong  t thu c V   CO
2
  y mol H
2
O. Bi 
 i     
A. 28/55(x-30y) B. V=28/95(x-62y) C. V=28/55(x+30y) D. V=28/95(x+62y)
Câu 24: 
+

-
 

+

-


A. 
B. 
C. 
D. 
Câu 25: 
amoniclorua, ancol benzylic, p-


A. 7 B. 5 C. 6 D. 4
Câu 26: 

A. 

B. 
C. 

D. 
Câu 27:     
3
COOH, CH
2
=CHCOOH, CH
2
=CHOOCCH
3
, CH
2
OH-CH
2
OH,
C
2
H
5
OH, HOOC(CH
2
)
4



A.  B.  C.  D. 
Câu 28: 
3
)
2
, Fe(NO
3
)
3
, Mg(NO
3
)
2




A. 12,88 gam.

B. 18,68 gam.

C. 31,44 gam.

D. 23,32 gam.

Câu 29: 
2
S

2
O
3

2
SO
4


2
S
2
O
3

2



2
S
2
O
3

A. 10
-2
 B. 10
-1
 C. 2,5.10

-3
). D. 2,5.10
-2

Câu 30: 

A. Cu(OH)
2

B. 
3

C. du
3
/NH
3

4
.
D. Cu(OH)
2

Trang 4/6 - 899
Câu 31:  : Al, S, O
2
, Cl
2
, SO
2
, Fe

2+
, Cu
2+
, HCl, HNO
3



A. 7. B. 6. C. 5. D. 4.
Câu 32: 
n
H
2n-2
O
2
không 
A. 
B. 
C. 
D.  
Câu 33: đúng?
A. 
2
H
5
Br, KOH, C
2
H
5


B. 
2
H
5


C. 
2
H
5
OH, CH
3
CH
2
CH
2
OH, CH
3
CH
2
CH
2
CH
2

D. Cho HNO
3

Câu 34: 
A. NO

2
, CO. B. SO
2
, HCl. C. N
2
O, CO
2
. D. CO
2
, SO
2
.
Câu 35:             


A. 6 B. 7 C. 8 D. 5
Câu 36: 

2

2


3
trong NH
3


A. 64,8g B. 16,2g C. 32,4. D. 21,6g
Câu 37: 

2

2
CO
3


2


A.  B.  C.  D. 
Câu 38: 

2

2


A. C
3
H
8
O
2
 C
3
H
6
O
2

B. C
3
H
8

3
H
6
O
2
C. C
3
H
8

3
H
2
O
2
D. C
3
H
8
O
2

3
H
4

O
2

Câu 39: 
2
SO
4
0,1M; Cu(NO
3
)
2
0,1M, Fe(NO
3
)
3

0,1M .  , 0,69 , 


( ). 







A. 20 

78,5 gam. B. 20 


55,7 gam.
C. 25,8 

78,5 gam. D. 25,8 

55,7 gam.
Câu 40:  

2

2


2

2

2:
A.  B.  C.  D. 
II. PHẦN RIÊNG [10 câu]
Thí sinh chỉ được làm một trong hai phần (phần A hoặc B)
A. Theo chương trình Chuẩn (10 câu, từ câu 41 đến câu 50)
Câu 41: H  M gm axit cacboxylic X, ancol Y     mol X  hai   mol
 este Z c  ra t X  Y. Cho m ng M      dung dch 
0,2 m mu h
A. HC
3
H
7

OH. B. HC
3
OH.
C. CH
3
COOH 
2
H
5
OH. D. CH
3
COOH 
3
OH.

Trang 5/6 - 899
Câu 42: 
 


2

A. . B. . C. . D. .
Câu 43: 
2

2
2b 

2


2
b 

A. 0,2 B. 0,1 C. 0,05 D. 0,8
Câu 44: 
A. Hai ion Mg
2+

+


+

2+

B. 

C. 
2+
, Ca
2+
, Ba
2+
, Cl
-

3
-



2
CO
3

D. 
3

3

Câu 45:           
propanal, isopren, axit metacrylic, phenylamin, m-crezol, cumen, stiren, xiclopropan. 

A. 9. B. 10. C. 8. D. 7.
Câu 46: 
3
H
6
O
3


2
 không 
A. . B. .
C.  D. .
Câu 47: 
A. Sn + O
2


2
. B. Ag
2
S + O
2

2

C. Fe
2
O
3

3
+ 3H
2
O D. 
2
+ H
2

Câu 48: 
45
o

 ?
A. 0,294. B. 7,440. C. 0,930 . D. 0,744.
Câu 49: 
4
2-

; 0,1 mol NO
3
-
; 0,08 mol Na
+
; 0,05 mol H
+

+
.


A. 15,62 gam. B. 11,67 gam . C. 12,47 gam. D. 13,17 gam.
Câu 50: Cho p ⇌ 
2



C
= 2,25. 
M





1
















 ?
A. 75%. B. 50%. C. 60%. D. 65%.
B. Theo chương trình Nâng cao (10 câu, từ câu 51 đến câu 60)
Câu 51: 
5
H
10


X  C
5
H
9
Br  C
5
H
9
Br

3
 C
5
H
12
O
3
 Y(C
8
H
12
O
6
).
        
3
/ NH
3
, t
0
; Cu(OH)
2
/dd NaOH,t
0
; NaOH, t
0
;
CH
3
COOH (xt H

2
SO
4

0
); CH
3
OH (xt H
2
SO
4

0
); NaHCO
3

 ?
A. 6. B. 3. C. 4. D. 5.
Câu 52: sai?
A. Khi cho C
2
H
2
-
B. .
R


2
-m --

C. 
3

D. 
+

Trang 6/6 - 899
Câu 53: 


2

A. 33,33%. B. 24,23%. C.26,50%. D. 24,30%.
Câu 54: 
2
CO
3

3

H
2
SO
4

2

2
 


A. 34,95 gam. B. 66,47 gam. C. 74,35 gam. D. 31,52 gam.
Câu 55: 
3

ch AgNO
3
/NH
3


A. 21,6. B. 35,95. C. 54,75. D. 40,4.
Câu 56: 
2

H
2
SO
4
 
1

1


3

2

A. 2,24. B. 11,2. C. 8,96. D. 1,12.
Câu 57:     

3
COOCH
2
CH
2
Cl, ClH
3
N-CH
2
COOH, C
6
H
5

HCOOC
6
H
5

6
H
5
COOCH
3
-C
6
H
4
-CH
2


3
CCl
3
, CH
3
COOC(Cl
2
)-CH
3
,
HCOOC
6
H
4
 

A. 7. B. 5. C. 6. D. 4.
Câu 58: 
2
O
3

 
       

A. C
3
H
7

OH. B. C
4
H
9
OH. C. C
5
H
11
OH. D. C
3
H
5
OH.
Câu 59: 
aF
2

2
SO
4
.

2
.

.

2
SO
4





A. 2. B. 3. C. 4. D. 5.
Câu 60: 
(1) Na
2
CO
3
+ dd FeCl
3

(2) H
2
SO
4

3
(PO
4
)
2

3
+ NaCl
(3) ZnS + dd HCl (7) Cl
2
+ O
2

(4) Ca
3
(PO
4
)
2
+ H
3
PO
4
(8) Si + dd NaOH

A. 6. B. 7. C. 4. D. 5.
HẾT
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