DE HDC b CK1 2010 2011

Dtrro HoADAr( r;oNcR,loriiiiiiiiir noi ri,
NcAyitri:15r20tt
.
D6lhic650ciu Thsisjo tim 6ailni:6sDhir

*"_*,"*,_;:,i::,,:"J.^,,.*,
.,
Hil,h.fJT.Ti;:1tl"Ti#illx,.*

hr
\.,.'
{iL
.',
"l;.#,i:;i:#,ilff
""
Hd,,*',H.}:.#iffil:::

"ffil'',',*

ChAnphuog jn d,ing:Marphin ungrqrr, ruc6
^ u ' . 0 C i r h i f rd n ! b f n r h r Cenn h n o\ iA b i € n
b'in ( dmpi $6nE phurhu6.nhi€tdd.kn,t!I!
nhcldarhihrngsoc6nbingK, !a:

al To8_lophrntugm
c h i | a n\ a d u n C
m o rl t u n q
b ) S dp h t nr t g r m ! h ; t b h n s m o r t r d u , e m 6 r
c) sd pnrntt Czmchijrh hon! OOOSLIDSfro

r) chdalhc.kct ltr6n&qc

cnoi phuheaf,iriDg d!,tnsit,6! kiqn,rrcn!
s,j
ra( chflvu, chrLn;oco en&oDi
tonnhir?
ll) H:srkt
l 2 r .s o { k )
(lJ SonkJ
rl ctrir I

P h ALi t n gN : i L r + O 1 k ) = 2 N O ( t )\,l | . O L l a n e
nrn 'j rrenerhijcenbansr/., adi,rn,np sE
u n gl a nk h i a p d u n C cbr .i € nD h a D s a u :
l)Dincxnot&.
2 )N d ni o .
r l T r n s n h ' q r d 0 . 4 J C d mi n a i r h e D h a u
ne .
i ) l

c) Kh6nExAcdinh du@
Chonphuongjn tt,inE.Ctc phrnnnqdrcrd5\
danEd rmnefir c,inbinco 25oC
r) N:(k)+o,(k) = 2NO(k)
a#>0.
2) N:(]()+lH,(k):2NrbG)
AHo<()

c 6 r f i i d u d o r n p h i n f n * \ a r Ar \a k o h a r l r i t n
ronhd nncrdoT, i.iu 6 nhiftdodor; co
DAG"

2)^Co<-40kJ

3)MCco(r)= Co,(k)+Mco(r)drl>0.
4 ) I , ( k rH
+ ) l k=r l H t ( U
^rf
Crn btugcuophdna.n8nAodt.h chuyfnmanhnhi!
heo (rr.u thurnkh,d6,s rnoihdnh(id4 val,ne
rpsuitchun€
a ) T r e g r h acr a nM n Ct h o n C
lhrrdd,rheorhui
Ch neukhonA(o di€ukr-!nbei nsoaLna!
rhi,

Chqnphuda AnrrttrgrNAngdOnotantd:

b) T@cfilican dng h tucthdi.ot6cdo
ohAi
ns urn h,lns6r dophrnrnSnahirh\r
ry (
Knuru0ngg'ila.rc chn ph.1n
dne\s sanphJi


phdn'tngldkh6ngddi d niftg itiAukienben
c) rrincrharcsnbansb nsnsdti od.tdlluy d6r
t h i d i n s d pd a n c n h 4 r b ; n s k h d n s .
dr ot4nC rhl cdnblnCphrnhgh@ hacktr6ng
rutha cdrhiiuthurntdnchiiunChch.

c-uMy
chonphuon8,n atdng;Biaurhic toin hoocia dtnh
luirRaoutr
tr.odans(vdikJ hin!,,j nshrh sol
haynehiem
ddnC
cUadue dich).
=
dT
kCM
(cv nangdOnoD
t
b) dT = rcN (cNndngdOdms iuqns)
c) ^ | = kcn (cm ndnsii6 noton).
IT = kc* (c%n6nea0phinrrn)
c!ud)
Channhhng6ndung sod6cA(pinhoeld6ng

Chanlhuog tu dnn8:
Qu, trirn chuycnpn! rin ihdnhphahoi c6:
a) ^H>0,as>0
b) AH<0,IS<0
c) ^H<0.^s>0
d) atl>0,as<0
Chonph@netnduDgMoJdo oH hoartt6nsdua
vaovi-:cdohieudignrhi s,*, diin (uc s ;;n
beohoAKct: Pq Hs I He:cltr I Kct baoh@io6 &;
dioncrc 6niljnha =+ q268V)v, diencm hydr!:
P! | H: I aim I H+(dunsdlchdn do oH) Havlinh
pHcnadungdich

o2s!C n6uhieudi€i lh3crjahai
iliin cuc nlr tr 0.564V.

r E i . o 5 0r b . p h . nr n 8 o ^ y h @ k h i :

= zn(NorrrddJ
zn(r), PbrNo,):(dd)
+ pbk)
K C i O , l J+d 2r c r c l r ( d +
d rT O K O H ( d d l :
?KC(dd)+ zK,co4(do + 5r:o
o{-)PqPb(Nor)1
z,(Nor)rlz(+)
(-)PtKCIO3
' r(Ct,KOH]Clctr,
K:C()1,KOHIP(+)

lrKhr quJ6nb mir hcddnsth-:\ad;do nhjL
2) DunSdichN.Cl0,tM tdhqd6npftC_viJoDs

b)(-)znlznoor)r]lphNor)rlpb(+)
3) Ruqu€glic vn nulrctd hadi drd.
(-)Pr(ctor,
Kcl,KoHlcrclr,KlCror,KOHpl(+)
4) Ha nhirrd6nC
ben

rcngt6 hodungdinunev6
c
d

c
o
i
r
i
+
c
a
o
l
r
r
+
c o : G )l ah i h o
o (-)znlz(Nor),lPb(Nor
),lPb(+)
5) II; ph,n rlns: Hct(dd) + NaoH(dd)+ NsC(dO
( )Ptiocrr,K,crcr,KoltiKclor,KcLKo4p(+) ' H r O l ? r d u d r h t r (
h i l nt u n gn h i * t r d s t i ( b n t j
k
/
n
,
.
.
c
h
n
h
i

c
0
.
h
i
i
a
hikm
o( PblPbNo,),
zn(+)

Pnoo,):
(-)Prcrcrr,K1cro,,Kor!Kclo,,Kct,Kol{p(+)
O ddu r,rn riEuchujnrA nhierdd).A.dr.h.ohin
nne H,([) + t O.(k)= H:o(k] phN,m nor time
n]riEr
24l,84[J rud!] suyrs.
I ) Nllier ti61chry lieu chudnd nhield6 d6 cnakni
hyd@D -2.41.34k1/mol
2)Nhiib!lhdnh tieuchuancnanoinu6rd dhiar
d'i d6 ld -241,3,tkJ/mot
] ] J l l c uq s n h i i t c Dp h r nn E t E i d n h i c r d d dLoi
4) Nenerr, Bli€nkdtH otA120,92rJlmot

b) 1,3,5

ChonphuongAndnng:Chophinins o\v trdoMtr

+ K N o ,+ H z o- M n o : + k N d , + K o

\Mng"
(dn
bin8phrnlne mn Neuh€s6rtr HrOrr I
rhih-;sddrhSrm. KMno. \lKNo: tln ljal Ja.

C h p n p h u d g ndnu n g H
: i e uh g n h , q ,( k r o r
phd ngddidu kiEndinAapb,ing
rr rdnsnxi-;L
bo rh;nhs,1nfim r ran!nri{ qo


z r T d n nt sn r c r d 6 r d sDc, ! h r rd i ur v b n e n h i e r
dor(hdycrcen phdh
I Tdnenrnsttrqs ,EnkdLmns .A(ch;tdiu @
'"":i'!s

I'o"crie"
k 'k-s.* *" ph;.

Clrondtp Andung Chonguldnrogaivjnicraoh i
o ' r n c r -{rr ) ( g d mm o h : n hA s n h r t . o
s!i!duns

"
ai.r rctto. o,oorNr"a
die".lr.(:) Gonr_ra,rr

A e M U n gd o n g d u n d
g i ( h A E l q 0 , t N r .D ; i ! , J L

nCudn rd ndy16

O Diencu! (t ) cd kdr dja Aa
b) Qui trlnhoxyh6axry m;€n

chonphrt bidudnng:phAnimed 25oc
I,Rr+lH:(kr = 2NHr(ll!6aco,c--12_9kl
I mh,Ke6
diu kienieu churn25!c.choR=

Chgnphudg Anatfrg: Choquarrinhdi6ncuc:
N o ; 1 d d+) ) r l d d r + l . = N o r t t )+ t H : O i r )
f r r @ Br l n hN q n d 6 trd i q u r E i ndha c h o d 2 s 0 C

i)
C"

istc

diCnatong
cnapin d 25oCB 0 , t 3 v .

cds th6ry s5dCuc6thuocd.h cud.s d6 Lr.
r) Thi knu,nhidtdo.kndiu@;rifls
b) Thadhsdp nhierdo,
""inr;e
c) Enircpi,kh6rtuqns,\6mol
d ) T 1 6 d a r q d p , e n b nl hpe,n c h
H c F n r 5 5n s m c rb % h t u c d d m c h u c( M =
r , , v a on u ( j t h ud u 0 c5 0 r n t d u ndgi c hc op H= t l ] .

nhd0phin ty cLtobeo nt|

e, e=eo+o.osets-+lNo;lH.f
[No,lH'I
rr q=o'ro,o:qrn
P*o,

{N9,1-.
", o=e'*o.osor"
lNo;lHI

'r o(i'n3 nhi-+d0T apsuirho,b,o hoacid dutr!
n ' t i r @ r ed u n 8 do hi g h F hb L arnd , , o n ! L l o

+o,o5,c#i*$
c i o n p h r o n e , na | t i t r g . c hI om o t l h r r d r etnl A $
'ao nu6.rhj.b.0.3motb,ditn /ym ion,!ej
hesrj

o O0 eidn uoS d6'llp5uerho,bio hda{uadlns
m d i r c t r C d d e d n bh r n s n i n ed O
n h a nm o r o t ;
hdacia n6tdunsdichtdns
vronhigtd0cdadunEdich.
Chanphudng6ndflg; TUhaiDhAn
i.na:
(l)A+B=c+D
Aril
( 2 )C + D = E + f
AH1

T h i e t l o p d ma. n g d f t h h ^ ] t . ( u a p h ati r e A

ra dinhd6rh,) d3r;nrrcpirrcd!ouatrtnhndn
d i n cn h i +lrm o t M rm e r a t n l u , t a ; n , Jl a; nm


1033
a) sirn29i5mv
Choc6cdungdichnudc beng cdaC6HrrO6,
NaCl,
M8Clr.NaPol. BiAtchungcn.unS
ndngdOmotan
vddd.di-Jn
) qua(N.DuorNaC. MgctrvaN,rpol
d € ub r n s O ( u n c de u k f n r p a l | n E o dni ,h f r
tlo s6ir'jacdcdungdch rh.od4 ftn o d{! diam

c) Itng29,5Dv
Chonphmg 6ndnhg;
Chocdcphrnftg rry ra ddieuki€ntieuchdn:
phd. Ltngki6ng xdy ra tu phntd moi nhie(d,i.

d) Kh6nec6qtry
luat

1)C6ngthtciinhc6nedtnndA=AnRTchidnnc

2)c.H(k)+ 6qG) + 4co,(kt+ 4H,O(k)

dH'<0, phtnlhg xAynru ph6tdmoinhietd6.

i)cacor(r) r Cao(r)+CO,(k)
^Ho>0,
phin (fnaxay E 4! phdrd nhiotii6 cao.
4) scl(k) + %q(k) + Scb(k)
^Hu < 0.
phdnnngxeyB tu pbdrAnhi€rd6rhlp.

2) Trcnertuamghgpdng quAr,thi cungcip chohe
dais tichmotluds nhielQlhi totn bOluglgnhior
Q se.hi ldmlanenoi nlngcnahe
l) Biin rhiCnn6inrnC!na phin ng hoaha(chtnh
li hle! ng nhin LUaphanns dOrone drauk dn

d) Khrlnec6 caudnng
Chonphtrmgrn dnng:PhrnnlgHrq(O +
H,O(C)
+ 4qG) rdanhie!vAyphrnrhg ndym:
.) AH<0rAS>0; G<0
0 6t b e x A y . a
tv ph6rd nhierd0 dunrg.
0tASc6lhexAym
ru phal d nhj& il6 rhtrog.
0; S>0;Ac>0
kh6ngthdxdy
F tu phrr d nhierdothu&8.
d) AH<0jAS>0t c>0
ki6ngth€xat
'
E t pb6la nhie!d6rhrdlg.

NhdrunggiordunedichNtrF0,tM \do I trd!ng
d i r hL h t al i o n g s mB a / ' ! a | 0 ' ' o n e m C a r '
rhi: (Chobiertioh sdian crlafloruacanxivi flotut
barilrn luqlbing t. l0 r0rvd L I ojrl.
!) Ket $a cal, xut hientudc.
b) Kh6nglic dinh duor.
c) K€r hja BoF?xuiit hienrudc.
d) CA2 ka da xuiir hidnd6nsrhoj.
,
.) D0 iliin ly a li mothanss6khonsphvdNOc
b) DOdiln ly atuc knindnsdric'trchardi€nty
c) Chi cd nnnnshgp chdtion khi hnala ronc
d) Dd di6nIy o c6$d t&r ho L

rhin lhe:2A(k) + B(0)= 3c(r) + D0<)6:
r) Kh6nsdwdo6nduqcdiu cnadS

Thgdi6ncsc c!. bacd 25!Crhayd6i nlu lh6 nAokhi
phabadcduncdichnu6i baco{a diSncrc l0 !in?

choe:.,.,,"..=0,77vv, q1,,.,s,..
=+o,r5v.
Tinhhitrss6ctnbingd 2socc'laphtnrns
2rerldd)^+snrldo : 2Fe,'(dd)
+ si41dd)


** **
;fl#

:"-xL"_."k1ilX
il"JH
a) $mt.hr,,knibh
1 6dr ah n c t 0 0 ; r n u d d
c

Chonpnmg r! dttrg:Tinh ,1S:,,oiaphen

O s6hot cht khtrantijid.lMs l|nnrdcditidu

c)

=
]Mts/rl+Corki 2Msolrr+c(s4.
a'€rsk(r/morK,.,ja
cac(htr:Ms(r),

r00etudc
:ddiijil!:H'jionlant6rdarbne

[4eqnuclgr)];

t 6 b d n cl l , 2 t 4 :

d) s6nt.h:i1uilant6idarbig loooeiudc
d

") f;i';1d''"J,a'r a'0"gia4 '"9' o6'"u"

chanphu@e

ai.t,tns:rrnh ^H:r .uaphrnns.
+,O,lk)=Hro(kj
( h o b r..Hr .,nl kr in
t us, l ntei e n[ a r( k m o , o r f c , r d m :

' ff iit'"T;ilrT,1ff
ilJ":'.lii
:il"Tt

c,aeh;n6ne(incnhucrc
\rnehrn(,)a
;l1m
c) Hjiuhe nh'ir.ra morphdn
unsdodd ju kidn
osngrp b6ngbidnthi& cn: eirmDriAHr hEr
rns nhdrc'taphrnhs dood,;u kdn dri;!
trch

.,iliil.l?,jiff
il;il?i:n:f,5*
d'5i,
kh6ne
%ocach
ehurhuoc
",q;t
lffisurhbnc

:lTJtfliil :iJ,.:tii:1""3
;1ifli ilff

'":1."""4
PillPt, do
" "hre,"."

r ) Bra'thr€n
rhi daiinhifi daf,caprj o#n njno
,trqnE
cuahC!6 re rudo chur6nrhhhrinect
,.h khrqu,Einhiay reko,s diiu k -{ daf,a;hir

@34p.

z)Cdng,.6.h Drir.lcr( cdnennhB (n!oa,
!ru
ans.h,hE:jp q5r nsoai)kh/ h-"chq;n r;hre
Dordru dEnrransrh,cu6i.
3)-Thddsncdpcia
hACdhd6n trcn!ouatrjnhtu
d a nb i d n ( ' l a h e
arTronch€cd irp. qudtrtnhltr M) ,r
s;n l,enrLJ/

j;
S,if;
8i::li#i:
:li,l",iT,
4H!i,"&illi
clnscnuod Bshchrrtu rcne tooopnudcco:
r;&
mngo. crr:rnay.angual to .unr

, ) K h d nd
e 0d d t i 6 u d L
; nh.

"0,

nrc,

T r n ht h er i c hd ! t r sd i c hl t
) l t c r 4 M c 6 nr h ; r d i c d
ue pnarhanrr
lt{tlugd|ch HCt0,5M

chebphuong6ndnDg:dhotnhietd6 xacdiih.
ph,n ins. S lrr+ o^rlt) = sor (kl L6hrnq
sdcrr
otuC( . = 4,2 t0,. T nhhdncsii.rn bbnir! (!1
t h a nq S S O - . r rt = S o + O r ( k l 6 . u n ! n h r e r d o
r) 4.2.10.


1038

Chonphtrde6ndnns:Ap suithdionecs1d2g3K
h 0 . 1 1 3 6 7 ! h .N A uh o o l d l 5 6 s S "v A om n o 7 d !

csr mlapsuithorbrohoaciad;e dichta
0.1r25,1atri, Heychobidls6nsuye;ni luuhutnb
r rrodS
nh;nFi Si.Chobdrkhortme nauvan

hi
O=16,S=12;C=tz

cu?ldo+ zn(r)= cuo + zn,1dd)

C h oq L . / c "= 0 , 3 3 7 v a9 0 , . , a= - 0 , ? 6 r v . x 6 o
dinhchieucr)aphtnnnBxnya gittohaidi6n c
ftn d dieukienri€nchueniai nniF do2st.
i) Ph{ntng tJ phdrhod.ban tl]eochiauftuin.
b) Phinins tu phdrhodntodnlheochjaunshich.
t) Phnnrnrsknongthexiy r. rheooAnaichidu
O Phan6nsdienn lhuannghich.
Phd.nneH:(k)+ t,(t) = 2H(i) 06hinc s6,en
blneKp.=9OcingnhArde phAn
hEsiditn B
theochi6unao$iapsurt ri6nepbdn
c,laH,,L v,
I II lei llvt lA0:; q45!d 0,1ard.
d P h ; nu n gd r c n g l h r i . i nb i n 8
br Phrnhe di€nm theoctuau
fahich,
o P h Aunn e d L C n r a f i e o ( h i A u r h u q
d) Khdng
fiAdsdoAn
d@ctrmarhairu DhAn
un!
Ctu a6
Chonphudg ,. imng:Chocdcs6lieusau:
l)q'(cJ'rca) = - 2,?9v
2) ao{za2'.En)= -0,764:r'

3) 9'6er'/Fe) = -0,437V
a) a" €erTe?) = + q77! v
cic ohetdtqo sip #p rh€otht rtr tinhknn tdns

ChOnphvonA{n atnDg:

choDhd.tng 2Me(r)+ cc,,(k)= 2Mgo(r)+

cFpi I . PhAntng ndyc6hieuire nhiertia! chuln
AHl{ = -822,7kJ. vi phuog dieDnhiqtdonshda
hoc,phantug n,y o'i $a:
.) li}j6nc q! phrt xny ra & nhiir dOcao.
b) XAyB ru phrt ti moi nhietd0.
o Y€u6 nniql d0Anhhtrdnekn6ngir6ngkd
d) xr), F lU ph6ld nhierd0 @o.
ChAnphu@Erintturg
Tini n6ngddPb4bro h6atunedungdirhKl
0,1M.Biallioh15td ote pbt, biry 1.4xt04
t t3!lo"M
b) l,4xl0rM
cJ 2,4xt0rM
d) 1,2xlOrM
Chonptft biaudnn8: Chopha. nng :
2KI+ zFectr= 2rect?+t:+ 2KCt.
a) Fect bi oxi h6a KI bi knn
b) FeCIrbikh|t.KI h chAtorih6a
c) Fecl3D.htr bi *!q Kr h chjl knu
d) reclr ld chetkhlr,Kt td.hitoxih6a

TinhnhiArd9cu, n8ontuaCOchryrrcn8khonC

$i (20qo
O: \;' 8noqN) rn@rherjch).Luoe o^]

co(k) + ,, odk) - co,(k) ^Hk = _23rkr
Nhiet d6 bandauld 25vC.Nhiil dunchot c'tacric
ohel(rftol() C(coli) = 30 vd c N1d = 27.2

rJ Fe< Fe? < Ca
b) rcr'< Fc.) Fer+<
F e d) zn< ca< Fc < Fe:'
(Cht t. Cah btj cot thi tdbhe dqr e'at thhh di thi)