Kien thuc trong tam HHC12
Bạn đang xem bản rút gọn của tài liệu. Xem và tải ngay bản đầy đủ của tài liệu tại đây (296.54 KB, 14 trang )
Nguyễn Văn Mơ KTCB Hóa 12NC
I.
• HS biết
!"#$%&
- '()*&+,-#-.'()*&/0
• HS hiểu
- 1#2%&34
- 1#)56*%&7)*&!$2"8%&'()*&
II.
- 9+$" 0 !):,2%&"!
- ;,33<=>#&"$34
A.
III.
&(<?@9%&<?1@@93A<?@BC:" 0
1DE1F"!,GB1@@BCG
R C O R'
||
O
− − −
EHBBCI()&3JD7!KB<L")F
M8IN-#JG
R C O C R '
|| ||
O O
− − − −
R C X
||
O
− −
EOG&F
R C N R '
|| |
O R ''
− − −
P")&- 9&#&&- P
IV. !"#$%&'()(
Q%&&-"R#S(TUV3&(!<W&>#,
X"8D%&U!&-&<WI#(=*&3JD<=J$
")QY! H&7JD&) H
V. !*+&'()(
1. ,-./
!"#
)D) !
Z
&-G B1@@BC[9
\
@
]
\ ^
9 +@
ˆ ˆ ˆ ˆ ˆ†
‡ ˆ ˆ ˆ ˆˆ
B1@@9[BC@9
)D) !
Z
3&_!G B1@@B
C
[X&@9
]
\
9 @
→
B1@@X&[B
C
@9
`,J*G B1@@BC
]
^
aP9
ˆ ˆ ˆ ˆ ˆ†
‡ ˆ ˆ ˆ ˆˆ
B19
\
@9[BC@9
2. ,-012'3
$%&'()$*+(
19
\
b19c1@@c19
d
[9
\
]
X
→
19
d
c19
\
c1@@c19
d
,-."
1
Nguyễn Văn Mơ KTCB Hóa 12NC
0
3
t ,xt,p
2 3
3
COOCH
|
n CH CH COOCH
(
|
CH
= − →
2 n
CH C )−
3
|
CH
VI. 4
1. )(&''$ 19
d
1@@9[E19
d
F
\
1919
\
@9
]
\ ^
9 +@
ˆ ˆ ˆ ˆ ˆ†
‡ ˆ ˆ ˆ ˆˆ
19
d
1@@19
\
19E19
d
F
\
[9
\
@
2. )(&'($ 1
e
9
f
c@9[E19
d
1@F
\
@
→
19
d
1@@1
e
9
f
[19
d
1@@9
Phenol Anhiđrit axetic Phenyl axetat
3. )(.56 7$628"956 :
3 2
0
(CH COO ) Zn
3 3 2
t
CH COOH CH CH CH COO CH CH
(Vinyl axetat)
+ ≡ → − =
B.
I. ;*</"=$
aT0T#!<)$3IJD.&&) H &#)
#DT#!JD6g
ah34)
134)%&-)H&-&3-(<Ii#(=*&3Ejk\1"$
\^1FJD6E&-34F)-)&()&-(-)
11%&<L$G
19
\
19
19
\
@ 1
@
B
k
@1@
B
\
@ 1
@
B
d
)"<G
B
k
B
\
B
d
I()&32l<L7JD
B
k
B
\
B
d
I&#E34)#FKJ&#E342F
B
k
B
\
B
d
E34)mn"8FKJDE34UR#gF
1&-34 o7G
1
kf
9
dk
1@@9G&-&1
kp
9
dk
1@@9G&-
1
kp
9
dd
1@@9G&-1
kp
9
df
1@@9G&-&)
2
II. !"#$%&'3>
III. 134Y! HJD&) H&)#DT#!
IV. q"8 o34"8rL)mEnF34grL
UER#F
V. !.'+&'3>
1. !"#,(/+0,12340
VI.
19
\
19
19
\
@ 1
@
B
k
@1@
B
\
@ 1
@
B
d
[
9
\
@
19
\
19
19
\
@9
@9
@9
[
B
k
1@@9
B
\
1@@9
B
d
1@@9
]
9
[
2. 4'"5(67`,-&
s
()&&!JD#t
VII.
19
\
19
19
\
@ 1
@
B
k
@1@
B
\
@ 1
@
B
d
[
X&@9
19
\
19
19
\
@9
@9
@9
[
B
k
1@@X&
B
\
1@@X&
B
d
1@@X&
3. 08,(93
VIII.
19
\
19
19
\
@ 1
@
1
kp
9
dd
@1@ 1
kp
9
dd
@ 1
@
1
kp
9
dd
[
d9
\
X`
19
\
19
19
\
@ 1
@
1
kp
9
df
@1@ 1
kp
9
df
@ 1
@
1
kp
9
df
4. :;
IX. uR#n"8g"L6# o<WJ<t#E 0DnFX#(=
6I"D1b1rI&-JD)343t@O9E@O9F3r-JDJ2=
-3t6%(2v0&"<W
O
?
?
XI. @ABCDEFG:@4HF
XII.
I. ;
• <0=71#)56*%&0&3")&
• 0> 7
XIII. 1<&)6*0&&)"&&)
&&&)=#3L#
XIV. j#20)=g"%&5
XV. jJl"t#2%&0&3")&
II.
XVI. w$11%&0$ !):<&
XVII. xy>#&6
630&3")&
XVIII. ;,30&3")&
XIX.
I. 2I
1. D$JK
L
@
ME
:
L
N
XX. 3?@A/A$B
XXI. ;#_!
z
11#
{
&
Z
G
XXII. 19
\
@9 ? 19@9 ?
19@9?19@9?19@9?19@
XXIII. <?@A/A$&5
XXIV. u&
{
&
{
Z
z
&&
{
&
Z
G
XXV.
@
19
\
@9
9
9
@9
@9
9@9
9
9@
9
@
19
\
@9
9
@9
9@9
9
9@
9
OH
H
XXVI. |?#_! }?#_!
XXVII. 9&&
{
&
Z
(
z
=
s
#(=
s
z
&
&#D>#&&
{
!
s
XXVIII. X
z
?@9!
s
{
)~
z
D
z
k
{
&
Z
?@9&-&
2. O2JK
L
@
ME
:
L
N
XXIX. 3?@A/A$B
XXX. 11#
{
G
XXXI.
19
\
@9 19@9 19@9 19@9 1 19
\
@9
@
XXXII. <?@3
C
&(
D
E(F
C
$G$3
C
$(HI8+D"#J&3DK
XXXIII.
@:@
E
@:@
E
uEF•)#_
α•)#_
β•)#_
3. ''2JK
ME
@
EE
:
MM
N
XXXIV.
9
@9
9
9
@99
@9
19
\
@9
9
@
@
19
\
9
19
\
@9
@9
9@9
9
@
@
9@
XXXV. α;#_!β€)#_!
OOOw•
4. 3PKK
L
@
MQ
:
R
N
N
XXXVII. 38v0%&\2
&&)&_!&
XXXVIII. 3?#H ,
H
$$
L
33/0M(NO
XXXIX.
XL. @SETMCấu trúc của amilozơ
XLI. <?#H ,
H
$3/0M("P$0
XLII.
XLIII. @SETECấu trúc của amilopectin
5. U($$J
XLIV. O#_! < 2 J4
JD6
