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I
Lutz F. Tietze, Gordon Brasche, and
Kersten M. Gericke
Domino Reactions
in Organic Synthesis
Domino Reactions in Organic Synthesis.
Lutz F. Tietze, Gordon Brasche, and Kersten M. Gericke
Copyright © 2006 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
ISBN: 3-527-29060-5
II
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III
Lutz F. Tietze, Gordon Brasche,
and Kersten M. Gericke
Domino Reactions
in Organic Synthesis
IV
The Authors
Prof. Dr. Dr. h.c. Lutz Tietze
Inst. f. Organische Chemie
Georg-August-Universität
Tammannstr. 2
37077 Göttingen
Dr. Gordon Brasche
Inst. f. Organische Chemie

Georg-August-Universität
Tammannstr. 2
37077 Göttingen
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statements, data, illustrations, pro cedural details or
other items may inadvertently be inaccurate.
Library of Congress Card No.:
applied for
British Library Cataloguing-in-Publication Data
A catalogue record for this book is available from
the British Library.
Dr. Kersten Matthias Gericke
Inst. f. Organische Chemie
Georg-August-Universität
Tammannstr. 2
37077 Göttingen
Bibliographic information published by
Die Deutsche Bibliothek
Die Deutsche Bibliothek lists this publication in the
Deutsche Nationalbibliografie; detailed bibliographic
data is available in the Intern et at
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© 2006 WILEY-VCH Verlag GmbH & Co. KGaA,
Weinheim
All rights reserved (including those of translation
into other languages). No part of this book may be

reproduced in any form − by photoprinting,
microfilm, or any other means − nor transmitted or
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permission from the publishers. Registered names,
trademarks, etc. used in this book, even when not
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considered unprotected by law.
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Printed in the Federal Republic of Germany
Printed on acid-free paper
ISBN-13: 978-3-527-29060-4
ISBN-10: 3-527-29060-5
V
Table of Contents
Introduction
1
Classification
7
1 Cationic Domino Reactions
11
1.1 Cationic/Cationic Processes
12
1.1.1 Cationic/Cationic/Cationic Processes
33
1.2 Cationic/Pericyclic Processes
39

1.3 Cationic/Reductive Processes
42
2 Anionic Domino Reactions
48
2.1 Anionic/Anionic Processes
48
2.1.1 Anionic/Anionic/Anionic Processes
104
2.1.2 Fourfold and Higher Anionic Processes
135
2.1.3 Two- and Threefold Anionic Processes Followed by a Nonanionic
Process
142
2.2 Anionic/Radical Processes
156
2.3 Anionic/Pericyclic Processes
160
2.3.1 Anionic/Pericyclic Processes Followed by Further Transformations
185
2.4 Anionic/Transition Metal-Catalyzed Processes
191
2.5 Anionic/Oxidative or Reductive Processes
194
3 Radical Domino Reactions
219
3.1 Radical/Cationic Domino Processes
223
3.2 Radical/Anionic Domino Processes
224
3.3 Radical/Radical Domino Processes

225
3.3.1 Radical/Radical/Anionic Domino Processes
252
3.3.2 Radical/Radical/Radical Domino Processes
253
3.3.3 Radical/Radical/Pericyclic Domino Processes
272
3.3.4 Radical/Radical/Oxidation Domino Processes
273
3.4 Radical/Pericyclic Domino Processes
275
4 Pericyclic Domino Reactions
280
4.1 Diels−Alder Reactions
282
Domino Reactions in Organic Synthesis.
Lutz F. Tietze, Gordon Brasche, and Kersten M. Gericke
Copyright © 2006 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
ISBN: 3-527-29060-5
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