Đề thi thử đại học môn Hóa học trường chuyên ĐHSP Hà Nội 2011 lần 5 doc

I.
pIIAN
{]ItrtJNG
CIIO'r'A'f'
CA
'l'fti
Stltl:
(40
cliu, tit'cfiu
I
tlin
ciiu
40)
Ciu l: Cho
clr-urg
clich circ mu0i
sau:
NallSor;
Nal{Cor;
(NI.l'r):So'r:
NaNO;:
Nar(lol:'/n('h:
('LrSor
Cl-lrCOONa. 56
dLrng clicli
c6
gi6
tri
pFI
>
7 ld

L.2.
I].
3
C,4
t).5.
C'iu
2: X la ho.p
ch6t hlLl
co mach
ho
(chita
C,
I-1, O)
c6
pli6n tir
tihOi
bang
90
clvC.
(lho
X
iltc
cltntl,-i vrii
Na c1-r
thLr clLla-c
so mol
I12 bapg
sd
mol
X

phan ilng.
Miit lihac
X
co lchzi
udng
phhn
iLng
vtir Nall('Or.
Sir
cOng lhfrc cAu 1ao
co th6
c6 cira
X
lzi
h.4.
l]. 3.
c.
-5.
I).
2
.
Ciiu
3: l-lodr
tal
ltet
7
,2
gam
hSn
hgp

X
gorn
Al
v2l
K
vdo
[00m]
dr-urg
dich
l l('l
1 M thLr
cluo-c 3.3(r
lit I
I'
(clktc).
fhdnh
phl'no/o
khOi
lLrgng
Al
c6 trong
X
ld
t\.79.69'2o.
B.
15,0%.
(:.
18,75%.
l)' 35'0(%'
Cffu

4:
Mqt
h6n hop
g6m
hai axit
cacboxylic
uo, clon
clr[rc. mach
ho
ke tiep
nhaLr
troug
cirr.rg
clay
cl0ng
cling.
I-Ay
m
garr
h6n
hop r6i
therr
vdo
clo 75
ml
clung
clich NaOII
0,2M.
D0
trurtrg

hoii
lLxrng
NaOil
con
dr-r cAl
th€rn vdo
25rnl clLng dich
FICI
0,2M.
C0
car.r
dung
dich
sau ltl.ri
trung
hoit thu
cltLo-c
1.0425
garn
chat ran khan.
Cong thiic
phdn tircira
hai
axit
lAn
h'ro-t
ld
TRU'ONG
DrrSP rrA
NQI

'I'ITUONG'TIIP'I'
CII
UYEN
Md tti: 251
I)E
1'III 1'IIU'l)AI
IIQC
LAN
1'lliJ'V
NAM
2(il I
MON
IIOA
IIOC
Thi'i
ginn
ldm
hdi:
90
Phtit
B.
CI{rCOOl'l
va
Crl.lsCOOI
I
D. CrlITCOOI
I vd C,rlle(lool
I
ll. chr-r ki
4. nh6m

Vlll/\.
D. chr-r
ki 4, nh6m
llA.
l].
(l?l'l5cl
iO
vzi
f l(ll lO.
D.
ICrong
co
nghiOrr
\-s
((
{
\
aa
It
+
3
.]3
,
Ciiu 5:
I-loh tan
hodl todn h6n
ho.p
X
(g6ni
x

mol
Fe,
y
mol
Cu,
z mol
FerOi
vz\
t
mol
lrcrOr)
trong
clrtng
cllch l-lCl kh6ng
thAy co khi bay
ra
khdi
binh,
dung
dich thu duoc
chi chfLa
?
uiuOi.
MOi
cltran tie
giira sir
mol cdc
chAt trong h6n h-op X
ld
A.x

ry-:27.12t.
B.xr
y 221
31.
C.x
ly=.\ztt. l).x
ty
'/.t
t.
{liiu 6: Ion M2'c6
tong
s6
hat
proton, notron,
electron
ldr 80
trong
do sd
hqt
mang
diOn
nhi0tr
lion
sd
lral
khong
rrang
cli6n ld 20.
'l'rong
birng

tLrAn
l.roiur
cAc
nguy€n io
hoa iroc.
rlguye
n t0 M
thudc
A.
I"lCOOIl
vd CI-I:COOLI.
C. Czl
IiCOOH
vd Crl'lzCOOI I.
A. chu lii
4.
nh6m
VIIIB.
C.
chr-r hi 3, nhom VlllB.
A.
CIhCIIO
vd
llCllO.
C. CrllrCI-lO
va I-lCl
IO
Cf,u 7:
'l'r6n
3.36

gam
ancleirit
don
chirc
X v6'i
rn6t
ancleiiit
ilon chitc
Y
(Mr
>
Mv)
16i thCm
lilLtic
v;iti
tlc
cluo-c 0,1
lit clung
cych
Z
v<i'i t01g
ndng
dd
cdc anciehil
id 0,8M.
'l'h€rl
tLt'
iiL citrng
clich AgN0;/N1
{

r
ilrt t'iio
clur-rg clich Z
r6i ti€p hdrnfu
cl16
n6ng
dOr-r
phAn
frLrg
hoi\n todn
thu
dtLcrc
21.(r
gam
Ag. Oong
t]riLc
ciitt
tilr
cira X
vai
Y lAn h-Lo1 lir
c6u 8: Cho
tirng chat: Fe,
Fe(OFI)2,
Fe(Oi-l)r,
Ire3o4,
Irezo.i,
rc(No;)2.
lre(NO:):,
|eSOa,

l;c:(SO.r)r.
IreCO: lAn itrot
phAn
iutg voiilzSOl
cldc, n6ng.
S0
phAn
irng thuQc
loai
phAn
itng oxi
hoil
lthLl
lA
n.5 r]. 8.
c.6
D.7.
glixclol v2l h6n ho1-r
ba
axii
bco: arit
pitrttL:itru.
Ciiu 9:
'l-huy
phdn hoAr-r todn m6t
triglixcLit
(X)
thr-t
cluo-c
zrxit stcalic

vzi
axir
olcic. SO ctdng
phAn
cAtr tao
cLra
X lt'r
A.5
r)1
l), _)
c.4.
t). ?
(jfiu
1{):
'l'rciug
pfiopg tfif
nghiCm
lthi
CO:
cil-roc
cli0r-r
che tiL
(]aCOr
vit ciung
clich
ll('l thirorrg
tri
liri
lilri
liiclrg clolra vA lioi

utitic. I)e thu
clr-ro-c
L'Oi
gAn
nhr-r tinli
l<hi6t.
rrgur.ii
ta
dfrn h5n
hop
l<hi lAn
lll'ot
ilLra
hai
binh clr-tng
cdc clung dich ndo
tt'ong
ciic dr-rng
clich
cluoi dAy
'/
A. NaOll. I l:SO,r
cl4c
ti. NailCOr.
I'lzSOr
clitc.
{1. Na:COr.
Na(ll.
tr)"
I

l:SO
r
rlirc.
Nzr3('O
r.
NIlr.
I ral ttl
tittrg clilt
tittit
Irilr
'
i
Cliu
11:
Ciro
circ
c[At:
CI'lrNIfi,
Cr,llsNIIz.
(CI-lr):NII.
(('{,lls):NiI
r'zi
(thco
chieu
tLr
trhi cluar
phiii)cLra
5 chat
tren
lir

l].
((l(,1
i'):l\l
l. Cct-l;Nl
lz. NI'lr.
(ll
l:N1
1?,
(Cllr)2NFl'
{1.
((lr,i'l:):Nll, NFI:,
Col{sNl'iz,
Ci-l:Ntiz
'
(ClFi3)zNH'
t).
Clr,llsNl.lz,
(Cal-I;)zNtr'I,
NII;,
CII:NFIz'
(CFlr)2NH"
{liiu
trZ:
Cho
cAn
biurg
(rrong
binh
kin)
salr:

CO
(k)
-r
IlzO
(k)
4 2
COt
(k))
'I'rong
chc
y6u
16:
(1) tdng
nhiet
ciQ;
(2)
th€ni
mot
h-rgng_
co;
(3)
th6mrnot
cfturrg
cua he
;
(5)
dirlg.*t
*u.
tdc.
SO

y6'-r
td
ldnr
thay
ddi
c6n bang
cira
hQ
ld
r')
tL.L,
Hz&)
AI{<0
li-rong
FIu;
(a)
gidm
hP suAt
R1
t-e"
J.
D6
pliAn
bi6t
dung
dicl-r
cua
ba
hgp
chAt

trCn'
tt"
4.
,{1
{lAu
tr3:
q<i
3
chAt
htru
co.:
glvxin.
l'ictylaruii1,
axit'glutamic
ct) thc
dung
thLr0c
thLi
lA
rt" Na0l{.
B"
Na.
Cfiu
14:
Llho
phAn
tit
c6c
chAt
sau:

l1
r1t12n CllC la
x'
' '-'-
-
A"5
H\.7
L.0.
C" HCI
I).
quj'tim
Am.
FIIJr,
COz,
Cl{+,
NH:,
Br2,
C2Ha,
Clz,
CzHz'
HCl"
Sd
chAt
md
phdn
tir
1\A
{lf;u
tr5: Ngtroi
ta

ct} th6
diAu
ch6
metanol
tireo
c6c
chch
sau:
(i)
cll,r
-4'? )co-;{ >
cl'l3ol-l
(2)2CLI,|
r
Oz
xrlie+
2CI'I301-I
(3)
crr
,',\"')
rctjci r;er+cFirct
(4)
cHicoocH3
r'NaoItr-ril+cHrcooFl
t
cFl3ol{
'l'rong
c0ng
nghicp.
metanoi

aittcrc
siin
xr-rAt
theo
cAch
n.
(1). (2)
i,A
(i).
i}.
(2), (3)
vri
(4)
t:"(2j
vd
(3).
E]"
(1)
vd(Z)'
ciiu
16;
r)c
tru'g
hoir
ln
garn
ri6n
rrqip
x
g6m rrai

axit
no,
don
chirc.
mach
hd,
k6
ti5p
nhaLr
troirg
ciln-o'
rliiy
clfinu
cllng
cAn
i
00ml
dr-rng
clicli
NaOH
0"3M.
Mar
khac
dern
d6t
ch6y
rn
gam h5n
hqp
X

rdi
cho
tr.rd'
b6 sdrn
pham
cr-ray
lan
ruot
di
qua binh
(r)
dq'g
pzor.
bi'nh
(2) dpng
dr,urg
dich
Koll
duthay
kh6i
h-rong
binh(1)'a*gagan].binh(2)
rang(3,64+a)gam.Thanh
ph|,n%vakrroirr-rqngctraaxirc6s6rig'rye'tii
cacbon
nho
hon
irong
X
li

A'
30.14%.
A1"'33,33oA'
C" 6g'86yo'
ffi"
66"6'/%'
{.iu
17: r,)6r
c}i6y hodn
toirn
1
7,6
gamFes
vd 12
ganFes2,
sr-rc
toin b0
khi
thr-r
d'uroc
vlio
v
ml
dung
dich
r.ia()r.r
?-5ltt
{L}
.
t

,iul;el,,,t).
Gia
iri
t6i
rlii;u
cua
y
can
clung
de hap
thu'
het
hhi
in
A.
100
!3'2AA'
c'
50'
t)"
150'
'\"''-
'';""-
''l'4r
''ii"
x' li il'li:{;"
i-ilio
5'5 gam Xtitc
dtrng
v6'i

ch'rng
dicli
NaOil
clr-ro-c
'{ tin-{
g.$:
{
OilQ
tflLlli
(-lL,{t
titdll
rllrc{r
LLl(r
r"
a-)
!2
o
""
7
1{, r!1,, x l)hAir fri,khoi
cLia
Y
lrin
hrvn
cua
XId44
SO
clong
pirAn
l l

,;a.tn
nrLroi
Y
i:it sii
ngr-ri,,en
iiL
('batl1-t
uuu
/\'
i {i.ltr
llc
s
,,iii.,,
ti.,t,
c ria X
li.,
^
I lJ^l.
{:"3'
E}"4'
ci*;
1$:
liiin
ilrr-r
hoiiir
loiri.r
v
lii.
{.jor
(cr

clkrc)
vz\o
bi'ir
clr*rg
200
ml
du*g
clictrr
x
(Naoll
trhd
v} l"lar(lo:
ir.51\,4)
i"ci
li.1
drrng
rlicl-l
ii*r'Jttoc
sar-r
'otira.
tnlg
{chi
iarn
bal'hoi
nuoc)
thi
thr-r
ei*o'c
19'9
garn

ch5t
rail
khan.
(jia
tri
V
ja
A.
1^12
13'
3"36.
{:"2'24
s"
5'6'
{r6u
zi}: Lsre
x
ki-rorrg
uo,
l,acr}
iro,
c6
ti
ktri0i
hoi
so
v6i
oxi
bbrqz,GT75.
Khi

X
tharr
gia
pha.
it^g
xh
phong
5oa
tao
i-a
m0t
aiidehi'i
,zh
m0l
i-*uOi
rila
axit
hfru
co 56
doi1g
phin
cAutao
cira
'>i
li
A"
4
83"
3.
c"7'

I)"
5'
cftu
2n: Tr0*
durg
riictrr
x
t:lu-,:a
13ar*;
Otr-{-:
0,17
(rnol); }"la'.0,02
(mol)
vcri
dung
drch
Y
chira
Iliic,;
co]
:
0,03
(nlcl);
tria':
0,1
(rnol) il'rn
clr-loc
rn
ga-'i\
kat

tiia,
Gi6
tri
cira m
li
!\. l1:, 1 1)
.
!] < crl
f1
'7
<tO
q ,/.{)(_).
$.
13.79.
lr,L.:. irg
ni'Lo
itr-rug
X la I
5.73'/o'
Xa
phong ho:r
riliry
:.il-ii.1c1.,it
V i,lhil
Y
ihrrc
lrien
6:'hal.r
r'tc;i
Cfiu

23:
I)hAn ilng
niro clLrcii
clAy dirng cl0
giai
thich
su'hinh
tlidnh thach
nhr-r
tiong l.rang
clong'/
A. CO2
r
Cla(OIl). ,-r
CaCOr
I
l-12O.
C.Ca(IIC().),-l>(]aC():r(]():ltl?O.I).Ca(]()rr(]():rII:()**_>
Ciu 24:
Cho ciic
chAt
sar-r :
C2ll3Cl,
Czll,1,
C:l-lo,
C2llrCOOII. C{,ll1NO
(czrplolactanr).
vinyl ilxolal.
phcnyl
axctat.

Sd circ
chAt
trong
cl6y
co khd nang thar"ii
gia phhn
img
triuig hcrp llr
A.6.
I]. 4 c.5
Ciiu
25:
Cho a
gam
le (du)
vdo
Vr lit dLrng
drch Cu(NO:):
1M seu: l<hi ket
gam
chAt
rf,n. Cho
a
gam
Fe
(clLr)
vAo
V2 lit clung dich AgNOr
1M. sar-r khi
cluo'c m

gam
chAt
rin.
QLran
he cr-ra
V
r
vd Vr li\
A'
V1
'
V:.
I].
Vr 2V:
C. VI l0V2
ChuT(t:
'l't.ong
so cAc polimc
sau:
(l)
to tlni.
(2)
stri
bong.
(3)
lcn,
(4)
to
6,6,
(7)

to
axetal.
Loai t<t c6
ngLrOn
goc
xenh-rlozo
Ia:
A.(1),
(2),(6).
I).3.
thirc
phan
[r'ng tlrLr tlrt<rc rrr
l<Ot
thLrc
phtin
Ln-rg cirng thLr
I).
lOv
r
v:
cnang.
(5)
lo
visco.
((i)
nilon
D.
(2).
(s). (7).

B.
(2), (3), (7).
c.
(2), (3),
(5)
Ciu27:
LISn hop
X
gOm
SOz vd 02
c6 ti khOi so
voi
I-12 bing 28.I.Ay 4.48 lit
h6n hop X
(clktc)
cho
cli
clLra
binh
dr-urg V2O5
nung
n6ng. I.I6n
hcrrr thu cltr<rc
cho
lOi
qr:a
clung
dich Ua(OII): ciLl thAy cri 33.19
gani
k6t tLra.

I-li6r-r sLrAt phAn
img oxi hod SO:
thi\nh SO.r lirr
h.2504.
1r.40%.
c.60%. l\.15%
Ciiu 2fi:'l'run-e
liod
5.4
gam
l.ron
hop X
96m
CII-rCOOll.
CIlr,,.CI'ICOOIl.
(.'61[5Oll
(phcnol)
r'ii
C6I-I5COOH
(axit
benzoic)
cAn dirng
V rnl dung dich
NaOII 0,1M.
(16
can clr,urg clich sar-r phAn irrrg. tiir-r
ducvc
6,94
gam
h6n hgp ch6t

rin khan.
Gi61ri
cira
V ld
A.
700.
8.669,6.
c.3s0
t).
900
Cfiu29:
Cho c6c
phAn
irng:
(1)
O:
I
dlrng dich
I(l )
(3)
i(Cllor
(r) r
lICl ddc +
(5)
Clz
(du) t
durng ciich
llzS
+
t0

(7)
NaNOz
(bdo
hod)
-r-
NFI4CI
ftao
hod)
Sfi
phAn
intg
cri th6 tao
ra
clon ch6t ki:
A.5.
C'f,u 30:
'|rong
citc
chAt:
zurctchit
act'ylic. axctot'r.
(2)
l,t,I
ll:O
"'
o
(a)
SO:
t
clurng

dich I
I:S
(6)
NI-13
(du)
r
Cl2
+
t].
6.
{:.7.
lt. +
xicloplolran, xiclohcxau. benzcn.
stiren.
axil arctic. axit iiclt'lic. anclchit a.r.clic.
ctyl
axctat.
viuyl
axctat.
c{irnct1,l
ctc. S0 cliit ct'r lihli rrirng larrr rriat uriru rruric
t},.7
.
t). 4
!1. 30,0.
bt'onr lir:
A.5.
Ciu
31: Cho
m

garlr
pharr
irng
xay
l'a hoAu
rn ldr
A. 31
.6.
c.6
(liiu
32:
Chi
clirng thr-r0c
thLr Cu(Ol-i)z/OI'l
rlirng cliclr licng
bict sau:
A.
glucozo.
urantoz(y. glixcr-ol.
anclchit axclic
c.21,2.
1J.24.4.
tlong cli€r-r hi0n
thich ho'p cri tlrC phan [ri"^t cltrtrc
tlit czi
ciie
li. long
tring 1rung.
glLrcozrr. liLrctozo'. glircrol.
(1.

setccarozo. glixerol.
zurctchit
axetic,
ancol etylrc.
I). glLrcozcr.
lr)ng trirng
trinrg.
glixcrtil,
ancol clr
lic.
(liiu
33:
I{ozl tan
hoan tozur
34,8
gzrm
h6n
hop X
(g0nr
l;co,
llc-rOr.
l;czO.r) cihi iOr thicu
V
nrl clurr-r, cliclr
llrSOr
2il^5o1,
(D
1.2 g/nrl).
saur
phan

furg
tliu drroc
h6n liop l.rai nrLrOi cri sO rlol biin-u rrliau.
(iiir
tri cuii
V
lz\
A.
zl00
h6n
ho-p X
gdnr
(Fe, FeO,
ItcaOa, |c2O3) vdo 400 ml clung dich Il{ll 2lvi.
saii
i,hi
toArr tlru duoc2"24lit khi LIz
(clktc).
dLrng dich
Y vit2.8
garn
I;e l<lrong tan.
(iiA
tri
rl.
250.
c" r0i) r).
100
{lAu
3.{:

i}hcnolpirtalci'
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