Phụ lục đính kèm về cây an điền hoa nhỏ

PHỤ LỤC
TENE.C2CDCl31H
8 7 6 5 4 3 2 1 0 ppm
0.000
1.257
1.534
1.599
1.678
1.959
1.973
1.988
2.004
2.009
2.015
2.022
2.041
2.056
2.071
2.086
2.101
5.084
5.098
5.100
5.117
5.133
5.148
7.255
6.242
1.922

4.196
2.573
2.000
PC 1.00
GB 0
LB 0.30 Hz
SSB 0
WDW EM
SF 500.1300157 MHz
SI 32768
F2 Processing parameters
SFO1 500.1335009 MHz
PL1 3.00 dB
P1 10.50 usec
NUC1 1H
======== CHANNEL f1 ========
MCWRK 0.01500000 sec
MCREST 0.00000000 sec
D1 1.00000000 sec
TE 0.0 K
DE 6.00 usec
DW 50.000 usec
RG 101.6
AQ 3.2769001 sec
FIDRES 0.152588 Hz
SWH 10000.000 Hz
DS 0
NS 16
SOLVENT CDCl3
TD 65536

PULPROG zg30
PROBHD 5 mm Multinucl
INSTRUM av500
Time 9.43
Date_ 20090428
F2 Acquisition Parameters
PROCNO 1
EXPNO 1
NAME 111TENE.C2
Current Data Parameters
11
7
3
8
4
12
9
5
1
28, 29, 30
Phuù luùc 1a: Phoồ H-NMR cuỷa hụùp chaỏt TENE.C2
1
TENE.C2CDCl31H
1.61.71.81.92.02.12.2 ppm
1.534
1.599
1.678
1.959
1.973
1.988

2.004
2.009
2.015
2.022
2.041
2.056
2.071
2.086
2.101
6.242
1.922
4.196
2.573
PC 1.00
GB 0
LB 0.30 Hz
SSB 0
WDW EM
SF 500.1300157 MHz
SI 32768
F2 Processing parameters
SFO1 500.1335009 MHz
PL1 3.00 dB
P1 10.50 usec
NUC1 1H
======== CHANNEL f1 ========
MCWRK 0.01500000 sec
MCREST 0.00000000 sec
D1 1.00000000 sec
TE 0.0 K

DE 6.00 usec
DW 50.000 usec
RG 101.6
AQ 3.2769001 sec
FIDRES 0.152588 Hz
SWH 10000.000 Hz
DS 0
NS 16
SOLVENT CDCl3
TD 65536
PULPROG zg30
PROBHD 5 mm Multinucl
INSTRUM av500
Time 9.43
Date_ 20090428
F2 Acquisition Parameters
PROCNO 1
EXPNO 1
NAME 111TENE.C2
Current Data Parameters
5.15.2 ppm
5.084
5.098
5.100
5.117
5.133
5.148
2.000
11
7

3
8
4
12
9
5
1
28, 29, 30
Phuù luùc 1b: Phoồ H-NMR cuỷa hụùp chaỏt TENE.C2
1
TENE.C2CDCl3C13CPD
200 180 160 140 120 100 80 60 40 20 ppm
16.012
16.057
17.666
25.654
26.751
26.857
28.327
39.774
39.796
76.767
77.021
77.275
124.369
124.389
124.502
131.204
134.919
135.129

PC 1.00
GB 0
LB 1.00 Hz
SSB 0
WDW EM
SF 125.7577825 MHz
SI 32768
F2 Processing parameters
SFO2 500.1320005 MHz
PL13 22.00 dB
PL12 14.68 dB
PL2 3.00 dB
PCPD2 88.00 usec
NUC2 1H
CPDPRG2 waltz16
======== CHANNEL f2 ========
SFO1 125.7703643 MHz
PL1 1.00 dB
P1 10.50 usec
NUC1 13C
======== CHANNEL f1 ========
MCWRK 0.01500000 sec
MCREST 0.00000000 sec
DELTA 1.89999998 sec
d11 0.03000000 sec
D1 2.00000000 sec
TE 0.0 K
DE 6.00 usec
DW 16.650 usec
RG 8192

AQ 1.0912410 sec
FIDRES 0.458222 Hz
SWH 30030.029 Hz
DS 2
NS 128
SOLVENT CDCl3
TD 65536
PULPROG zgpg30
PROBHD 5 mm Multinucl
INSTRUM av500
Time 11.30
Date_ 20090502
F2 Acquisition Parameters
PROCNO 1
EXPNO 2
NAME 111TENE.C2
Current Data Parameters
10
6
2
3
7
11
9
5
12
4
8
1
30

28
29
Phuù luùc 2a: Phoồ C-NMR cuỷa hụùp chaỏt TENE.C2
13
TENE.C2CDCl3C13CPD
171819202122232425262728293031323334353637383940
ppm
16.012
16.057
17.666
25.654
26.751
26.857
28.327
39.774
39.796
132133134135
ppm
131.204
134.919
135.129
124.5
ppm
124.369
124.389
124.502
3
5
10
6

2
12
4
8
1
3
11
7
30
29
28
Phuù luùc 2b: Phoồ C-NMR cuỷa hụùp chaỏt TENE.C2
13
TENE.C2CDCl3C13CPD
2030405060708090100110120130140150160170180190200210 ppm
2030405060708090100110120130140150160170180190200210 ppm
2030405060708090100110120130140150160170180190200210 ppm
DEPT90
DEPT135
C13CPD
CH&CH3
CH2
&DEPT
Phuù luùc 3a: Phoồ DEPT-NMR cuỷa hụùp chaỏt TENE.C2
TENE.C2CDCl3C13CPD
20253035404550556065707580859095100105110115120125130135 ppm
20253035404550556065707580859095100105110115120125130135 ppm
20253035404550556065707580859095100105110115120125130135 ppm
DEPT90
DEPT135

C13CPD
CH&CH3
CH2
&DEPT
Phuù luùc 3b: Phoồ DEPT-NMR cuỷa hụùp chaỏt TENE.C2
TENE.C1CDCl3&MeOD1H
8 7 6 5 4 3 2 1 0 ppm
1.342
1.361
1.375
1.400
1.488
1.497
1.505
1.517
1.546
1.564
1.571
1.594
1.601
1.613
1.624
1.631
1.638
1.647
1.657
1.665
1.673
1.704
1.724

1.730
1.838
1.847
1.865
1.874
1.897
1.903
1.915
1.922
1.970
1.978
1.996
2.005
2.182
2.205
2.765
3.190
3.202
3.210
3.223
3.398
5.237
5.244
5.251
7.308
1.532
3.796
2.915
3.309
7.332

5.213
4.065
4.887
4.698
6.634
3.262
1.066
0.993
1.130
1.000
PC 1.00
GB 0
LB 0.30 Hz
SSB 0
WDW EM
SF 500.1299893 MHz
SI 32768
F2 Processing parameters
SFO1 500.1335009 MHz
PL1 1.00 dB
P1 7.80 usec
NUC1 1H
======== CHANNEL f1 ========
MCWRK 0.01500000 sec
MCREST 0.00000000 sec
D1 1.00000000 sec
TE 300.1 K
DE 6.00 usec
DW 50.000 usec
RG 90.5

AQ 3.2769001 sec
FIDRES 0.152588 Hz
SWH 10000.000 Hz
DS 0
NS 16
SOLVENT CDCl3
TD 65536
PULPROG zg30
PROBHD 5 mm TXI 1H13
INSTRUM av500
Time 11.24
Date_ 20090115
F2 Acquisition Parameters
PROCNO 1
EXPNO 1
NAME 111TENE.PE2
Current Data Parameters
12
3
7 nhúm -CH
3
Phuù luùc 4a: Phoồ H-NMR cuỷa hụùp chaỏt TENE.C1
1
18
TENE.C1CDCl3&MeOD1H
3.23.43.63.84.04.24.44.64.85.05.2 ppm
3.190
3.202
3.210
3.223

3.398
5.237
5.244
5.251
1.130
1.000
1.61.71.81.92.02.12.2
ppm
1.505
1.517
1.546
1.564
1.571
1.594
1.601
1.613
1.624
1.631
1.638
1.647
1.657
1.665
1.673
1.704
1.724
1.730
1.838
1.847
1.865
1.874

1.897
1.903
1.915
1.922
1.970
1.978
1.996
2.005
2.182
2.205
6.634
3.262
1.066
0.993
12
3
18
Phuù luùc 4b: Phoồ H-NMR cuỷa hụùp chaỏt TENE.C1
1
TENE.C1CDCl3&MeOD1H
0.70.80.91.01.11.21.31.41.51.61.71.8 ppm
0.713
0.736
0.778
0.810
0.855
0.868
0.901
0.909
0.924

0.939
0.952
0.984
1.004
1.029
1.087
1.140
1.258
1.273
1.292
1.300
1.317
1.323
1.342
1.361
1.375
1.400
1.488
1.497
1.505
1.517
1.546
1.564
1.571
1.594
1.601
1.613
1.624
1.631
1.638

1.647
1.657
1.665
1.673
1.704
1.724
1.730
1.532
3.796
2.915
3.309
7.332
5.213
4.065
4.887
4.698
6.634
27
23
30
25
29
26
24
Phuù luùc 4c: Phoồ H-NMR cuỷa hụùp chaỏt TENE.C1
1
TENE.C1CDCl3&MeODC13CPD
200 180 160 140 120 100 80 60 40 20 ppm
18.248
21.070

23.213
23.449
24.147
26.900
28.000
30.612
32.974
36.738
36.893
38.589
38.637
38.825
39.025
39.421
42.008
47.508
47.757
48.946
49.117
49.287
49.460
49.629
52.751
55.181
76.763
77.017
77.272
78.875
125.476
138.116

PC 1.00
GB 0
LB 1.00 Hz
SSB 0
WDW EM
SF 125.7577932 MHz
SI 32768
F2 Processing parameters
SFO2 500.1320005 MHz
PL13 20.50 dB
PL12 19.62 dB
PL2 1.00 dB
PCPD2 80.00 usec
NUC2 1H
CPDPRG2 waltz16
======== CHANNEL f2 ========
SFO1 125.7703643 MHz
PL1 5.00 dB
P1 13.00 usec
NUC1 13C
======== CHANNEL f1 ========
MCWRK 0.01500000 sec
MCREST 0.00000000 sec
DELTA 1.89999998 sec
d11 0.03000000 sec
D1 2.00000000 sec
TE 300.0 K
DE 6.00 usec
DW 15.300 usec
RG 3072

AQ 1.0027661 sec
FIDRES 0.498653 Hz
SWH 32679.738 Hz
DS 2
NS 2048
SOLVENT CDCl3
TD 65536
PULPROG zgpg30
PROBHD 5 mm TXI 1H13
INSTRUM av500
Time 11.52
Date_ 20090115
F2 Acquisition Parameters
PROCNO 1
EXPNO 2
NAME 111TENE.PE2
Current Data Parameters
180.419
28
13
12
3
5
18
Phuù luùc 5a: Phoồ C-NMR cuỷa hụùp chaỏt TENE.C1
13
TENE.C1CDCl3&MeODC13CPD
2025303540455055
ppm
15.345

15.511
16.842
16.910
18.248
21.070
23.213
23.449
24.147
26.900
28.000
30.612
32.974
36.738
36.893
38.589
38.637
38.825
39.025
39.421
42.008
47.508
47.757
48.946
49.117
49.287
49.460
49.629
52.751
55.181
5

18
17
9
14
8
4
19
10
20
1
22
7
21
15
23
2
16
27
11
30
6
29
25
24
26
Phuù luùc 5b: Phoồ C-NMR cuỷa hụùp chaỏt TENE.C1
13
TENE.C5CDCl3&MeOD1H
7 6 5 4 3 2 1 0 ppm
0.977

0.990
1.020
1.089
1.141
1.260
1.289
1.301
1.324
1.334
1.390
1.415
1.486
1.512
1.518
1.547
1.565
1.583
1.609
1.643
1.668
1.701
1.724
1.867
1.903
1.939
1.950
1.957
1.970
1.986
1.996

2.185
2.207
2.950
2.969
3.226
3.384
3.422
3.648
3.660
5.244
7.326
13.520
4.550
6.658
5.103
14.137
9.003
5.884
1.054
1.835
1.232
1.000
PC 1.00
GB 0
LB 0.30 Hz
SSB 0
WDW EM
SF 500.1299796 MHz
SI 32768
F2 Processing parameters

SFO1 500.1335009 MHz
PL1 3.00 dB
P1 10.50 usec
NUC1 1H
======== CHANNEL f1 ========
MCWRK 0.01500000 sec
MCREST 0.00000000 sec
D1 1.00000000 sec
TE 303.9 K
DE 6.00 usec
DW 50.000 usec
RG 143.7
AQ 3.2769001 sec
FIDRES 0.152588 Hz
SWH 10000.000 Hz
DS 0
NS 16
SOLVENT CDCl3
TD 65536
PULPROG zg30
PROBHD 5 mm Multinucl
INSTRUM av500
Time 14.38
Date_ 20090629
F2 Acquisition Parameters
PROCNO 1
EXPNO 1
NAME 111TENE.C5
Current Data Parameters
12

2
3
18
7 nhúm -CH
3
Phuù luùc 6a: Phoồ H-NMR cuỷa hụùp chaỏt TENE.C5
1
TENE.C5CDCl3&MeOD1H
0.51.01.52.02.53.03.5
ppm
0.782
0.810
0.840
0.854
0.867
0.881
0.896
0.903
0.921
0.942
0.953
0.977
0.990
1.020
1.089
1.141
1.260
1.289
1.301
1.324

1.334
1.390
1.415
1.486
1.512
1.518
1.547
1.565
1.583
1.609
1.643
1.668
1.701
1.724
1.867
1.903
1.939
1.950
1.957
1.970
1.986
1.996
2.185
2.207
2.950
2.969
3.226
3.384
3.422
3.648

3.660
13.520
4.550
6.658
5.103
14.137
9.003
5.884
1.054
1.835
1.232
5.2
ppm
5.244
1.000
2
3
18
12
23
24
25
26
27
29
30
Phuù luùc 6b: Phoồ H-NMR cuỷa hụùp chaỏt TENE.C5
1
TENE.C5CDCl3&MeODC13CPD
200 180 160 140 120 100 80 60 40 20 ppm

24.354
28.144
28.719
29.469
29.824
30.825
33.098
36.975
38.271
39.064
39.248
39.355
39.700
42.300
46.642
47.687
47.978
48.703
48.875
49.046
49.216
49.388
49.558
49.728
52.990
55.445
68.790
77.043
77.297
77.552

83.708
125.442
138.485
180.781
PC 1.40
GB 0
LB 1.00 Hz
SSB 0
WDW EM
SF 125.7577598 MHz
SI 32768
F2 Processing parameters
SFO2 500.1320005 MHz
PL13 22.00 dB
PL12 14.68 dB
PL2 3.00 dB
PCPD2 88.00 usec
NUC2 1H
CPDPRG2 waltz16
======== CHANNEL f2 ========
SFO1 125.7716224 MHz
PL1 1.00 dB
P1 10.50 usec
NUC1 13C
======== CHANNEL f1 ========
MCWRK 0.01500000 sec
MCREST 0.00000000 sec
DELTA 1.89999998 sec
d11 0.03000000 sec
D1 2.00000000 sec

TE 304.6 K
DE 6.00 usec
DW 15.900 usec
RG 8192
AQ 1.0420883 sec
FIDRES 0.479836 Hz
SWH 31446.541 Hz
DS 2
NS 2048
SOLVENT CDCl3
TD 65536
PULPROG zgpg30
PROBHD 5 mm Multinucl
INSTRUM av500
Time 16.07
Date_ 20090705
F2 Acquisition Parameters
PROCNO 1
EXPNO 2
NAME 111TENE.C5
Current Data Parameters
28
13
12
3
2
5
18
Phuù luùc 7a: Phoồ C-NMR cuỷa hụùp chaỏt TENE.C5
13

TENE.C5CDCl3&MeODC13CPD
60708090
100110120130140
150160
170
180
ppm
49.046
49.216
49.388
49.558
49.728
52.990
55.445
68.790
77.043
77.297
77.552
83.708
125.442
138.485
180.781
28
13
12
3
2
5
18
Phuù luùc 7b: Phoồ C-NMR cuỷa hụùp chaỏt TENE.C5

13
TENE.C5CDCl3&MeODC13CPD
15
20
2530354045
ppm
14.135
16.765
16.870
17.048
17.096
18.499
21.245
22.787
23.478
23.649
24.354
28.144
28.719
29.469
29.824
30.825
33.098
36.975
38.271
39.064
39.248
39.355
39.700
42.300

46.642
47.687
47.978
17
9
1
4
8
10
14
19
20
22
7
21
23
15 16
27
11
30
6
24
25
26
29
Phuù luùc 7c: Phoồ C-NMR cuỷa hụùp chaỏt TENE.C5
13
TENE.C5CDCl3&MeODC13CPD
2030405060708090100110120130140150160170180190 ppm
2030405060708090100110120130140150160170180190 ppm

2030405060708090100110120130140150160170180190 ppm
DEPT90
DEPT135
C13CPD
CH&CH3
CH2
&DEPT
28
13
12
3
2
5
18
Phuù luùc 8a: Phoồ DEPT-NMR cuỷa hụùp chaỏt TENE.C5
TENE.C5CDCl3&MeODC13CPD
152025303540455055 ppm
152025303540455055 ppm
152025303540455055 ppm
DEPT90
DEPT135
C13CPD
CH&CH3
CH2
&DEPT
Phuù luùc 8b: Phoồ DEPT-NMR cuỷa hụùp chaỏt TENE.C5
TENE.C4CDCl3&MeOD1H
8 7 6 5 4 3 2 1 0 ppm
1.351
1.375

1.400
1.427
1.442
1.473
1.498
1.535
1.542
1.550
1.563
1.569
1.592
1.600
1.613
1.627
1.655
1.671
1.700
1.720
1.725
1.745
1.752
1.772
1.780
1.884
1.899
1.907
1.913
1.935
1.943
1.960

1.968
1.995
2.187
2.210
2.817
2.825
2.845
2.852
2.944
2.963
3.193
3.381
3.384
3.387
3.626
3.635
3.648
3.654
3.667
3.676
5.246
5.277
7.329
6.947
1.544
6.826
3.289
3.193
1.535
3.372

1.372
5.311
5.369
2.281
4.389
0.962
1.158
1.104
1.000
PC 1.00
GB 0
LB 0.30 Hz
SSB 0
WDW EM
SF 500.1299785 MHz
SI 32768
F2 Processing parameters
SFO1 500.1335009 MHz
PL1 3.00 dB
P1 10.50 usec
NUC1 1H
======== CHANNEL f1 ========
MCWRK 0.01500000 sec
MCREST 0.00000000 sec
D1 1.00000000 sec
TE 303.6 K
DE 6.00 usec
DW 50.000 usec
RG 203.2
AQ 3.2769001 sec

FIDRES 0.152588 Hz
SWH 10000.000 Hz
DS 0
NS 16
SOLVENT CDCl3
TD 65536
PULPROG zg30
PROBHD 5 mm Multinucl
INSTRUM av500
Time 14.33
Date_ 20090629
F2 Acquisition Parameters
PROCNO 1
EXPNO 1
NAME 111TENE.C4
Current Data Parameters
12
2
3
18
7 nhúm -CH
3
Phuù luùc 9a: Phoồ H-NMR cuỷa hụùp chaỏt TENE.C4
1
TENE.C4CDCl3&MeOD1H
1.61.82.02.22.42.62.83.03.23.4
3.63.8
ppm
1.600
1.613

1.627
1.655
1.671
1.700
1.720
1.725
1.745
1.752
1.772
1.780
1.884
1.899
1.907
1.913
1.935
1.943
1.960
1.968
1.995
2.187
2.210
2.817
2.825
2.845
2.852
2.944
2.963
3.193
3.381
3.384

3.387
3.626
3.635
3.648
3.654
3.667
3.676
5.369
2.281
4.389
0.962
1.158
1.104
5.3 ppm
5.246
5.277
1.000
12
2
3
18
Phuù luùc 9b: Phoồ H-NMR cuỷa hụùp chaỏt TENE.C4
1
TENE.C4CDCl3&MeOD1H
0.70.80.91.01.11.21.31.41.51.61.71.81.92.02.1 ppm
0.684
0.728
0.785
0.811
0.824

0.849
0.854
0.868
0.874
0.904
0.933
0.954
0.978
0.992
1.021
1.062
1.090
1.142
1.161
1.167
1.186
1.191
1.213
1.259
1.303
1.325
1.343
1.351
1.375
1.400
1.427
1.442
1.473
1.498
1.535

1.542
1.550
1.563
1.569
1.592
1.600
1.613
1.627
1.655
1.671
1.700
1.720
1.725
1.745
1.752
1.772
1.780
1.884
1.899
1.907
1.913
1.935
1.943
1.960
1.968
1.995
6.947
1.544
6.826
3.289

3.193
1.535
3.372
1.372
5.311
5.369
2.281
4.389
27
23
24
25
26
29
30
Phuù luùc 9c: Phoồ H-NMR cuỷa hụùp chaỏt TENE.C4
1
TENE.C4CDCl3&MeODC13CPD
200 180 160 140 120 100 80 60 40 20 0 ppm
18.450
23.129
23.543
23.634
25.950
27.745
28.648
30.762
32.634
32.716
33.141

33.987
38.322
39.284
39.421
41.333
41.873
46.070
46.370
47.703
48.960
49.130
49.302
49.473
49.643
49.815
49.985
55.393
68.772
76.911
77.165
77.420
83.708
122.198
144.063
181.528
PC 1.00
GB 0
LB 1.00 Hz
SSB 0
WDW EM

SF 125.7577733 MHz
SI 32768
F2 Processing parameters
SFO2 500.1320005 MHz
PL13 22.00 dB
PL12 14.68 dB
PL2 3.00 dB
PCPD2 88.00 usec
NUC2 1H
CPDPRG2 waltz16
======== CHANNEL f2 ========
SFO1 125.7716224 MHz
PL1 1.00 dB
P1 10.50 usec
NUC1 13C
======== CHANNEL f1 ========
MCWRK 0.01500000 sec
MCREST 0.00000000 sec
DELTA 1.89999998 sec
d11 0.03000000 sec
D1 2.00000000 sec
TE 304.4 K
DE 6.00 usec
DW 15.900 usec
RG 8192
AQ 1.0420883 sec
FIDRES 0.479836 Hz
SWH 31446.541 Hz
DS 2
NS 4096

SOLVENT CDCl3
TD 65536
PULPROG zgpg30
PROBHD 5 mm Multinucl
INSTRUM av500
Time 10.50
Date_ 20090705
F2 Acquisition Parameters
PROCNO 1
EXPNO 2
NAME 111TENE.C4
Current Data Parameters
28
13
12
3
2
5
Phuù luùc 10a: Phoồ C-NMR cuỷa hụùp chaỏt TENE.C4
13
TENE.C4CDCl3&MeODC13CPD
5060708090100110120130140150160170180
ppm
41.333
41.873
46.070
46.370
47.703
48.960
49.130

49.302
49.473
49.643
49.815
49.985
55.393
68.772
76.911
77.165
77.420
83.708
122.198
144.063
181.528
28
13
12
3
2
5
Phuù luùc 10b: Phoồ C-NMR cuỷa hụùp chaỏt TENE.C4
13
Phuù luùc 10c: Phoồ C-NMR cuỷa hụùp chaỏt TENE.C4
13
TENE.C4CDCl3&MeODC13CPD
202530354045
ppm
16.621
16.787
16.997

18.450
23.129
23.543
23.634
25.950
27.745
28.648
30.762
32.634
32.716
33.141
33.987
38.322
39.284
39.421
41.333
41.873
46.070
46.370
47.703
9
17
1
19
14
18
4
8
10
21

29
22
7
20
23
15
27
30
16
11
6
24
25
26