Nghiên cứu đặc điểm hình thái thực vật, thành phần hóa học của cây crinum SP6 , amaryllidaceae phần 2

PHỤ LỤC

Phụ lục I; Các phổ của chất HM).
Phụ lục II; Các phổ của chất RM2.
Phụ lục III: Hình ảnh cây Mức hoa trắng


PHỤ LỤC I.

• Phổ UV của chất HMi.
• Phổ MS của chất HMi.
• Phổ ‘^C-NMR và ^H-NMR của chất HMj.
‘H-NMR của chất HMị.

•

Phổ

•

Phổ mơ phỏng ‘^C-NMR của chất HMj.

m ơ phỏng

• PhỔ D EPT90& D EPT135củachấtH M ,.


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93

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Page

8 May 2007
2. 0

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Current Data Parameters
NAME
KINH HMl
EXPNO
2
PROCNO
1
F2 - Acquisition Parameters
Date

20070516
Time
11.19
INSTRUM
av500
PROBHD
5 mm Multinucl
PULPROG
zgpg30
TD
65536
SOLVENT
CDC13
NS
256
DS
2
SWH
32679.738 Hz
FIDRES
0.498653 Hz
AQ
1.0027661 sec
RG
3649.1
DW
15.300 usee
DE
6.00 usee
TE

303.1 K
D1
2.00000000 sec
dll
0.03000000 sec
DELTA
1.89999998 sec
MCREST
0.00000000 sec
MCWRK
0.01500000 sec
NUCl
PI
PLl
SFOl

13C
8.60 usee
-1.00 dB
125.7703643 MHz

======== CHANNEL f2 ====
CPDPRG2
waltzie
NUC2
IH
PCPD2
88.00 usee
PL2
-3.00 dB

PL12
15.47 dB
PL13
22.00 dB
SF02
500.1320005 MHz
F2 - Processing parameters
SI
32768
SF
125.7578513 MHz
WDW
EM
SSB
0
LB
1.00 Hz
GB
0
PC
1. 00

■

165

160

I

155

'

'

■ .--T—

150

- .-^

1

145

,

,

.

,

I

140

■ ,

■

.

I

135

.........................| -

130

125

120

ppm


KINH-HM1-DMS0-C13CPD&DEPT
DEPT90

200

190

x -p
-r -r
180

170

160

150

140

130

120

110

100

180

170

160

150

140

130

120

110

100

Tp
-r -r

90

80

70

60

50

■• I • ■

'■'1.........1'"

n y-r
-rr

---p
T -r
1

T^JTT

np
-r -T

90

80

70

60

50

ìiệmếềimểmmm
t-r-p ■-rrr
-r ^p^

n
r-r^
40

30

20

ppm

DEPT135
CH &CH 3

CH2
200

190

i-ry
rr

■ ■I • ■

40

30

20

ppm


KINH-HM1-DMS0-C13CPDSDEPT
DEPT9 O

170

165

160

155

150

145

140

135

130

125

120

115

ppm

165

160

155

150

145

140

135

130

125

120

115

ppm

DEPT135
CH&CH3

CH2
170

C13CPD

------ -------------- -------------1
-------------------- -------------1
------.---------------------------Ị----- •----- -------•----- •----- 1
----- •----- -------^ ^ ------1
----- •------^
----- -------•------\----- ----------------------------\--------------------■
------^
------1
----- ■
-------^

------------•------1
---------------------------•------1
------------ ^

170

■

165

160

155

150

145

140

135

130

125

^

----- 1
----- --------------------- ----- 1 •----- ^ ^ ----- ■ 1

---------

120

115

ppm


D U = C : / B r u k e r / X W I N - N M R , USER,=VH_KINH, NAME=KINH_HM1, EXPN0=2, PR0CN0=1
F l = 2 4 0 . OOOppm, F 2 = - 5 . OOOppm MI=0.00cm, MAXI=10000.00cm, PC=1.400
FREQUENCY
INTENSITY
ADDRESS
#
[PPM]
[Hz]
21036.311
167.2763
7837.7
0.45
1
149.9594
18858.576
0.59
10021.3
2
18215.510
144.8459
0.72

10666.1
3
15322.783
121.8435
0.78
13566.7
4
121.6841
15302.729
0.45
13586.8
5
116.5404
14655.866
0.78
14235.4
6
115.1148
14 476.592
0 .8 8
14415.2
7
5030.381
40.0005
1.75
23886.9
8
5020.729
39.9238
0.48

23896.6
9
39.8337
5009.399
5.33
23907.9
10
39.7570
4999.755
0.79
23917.6
11
4988.411
39. 6668
10.65
23929.0
12
4978.617
3 9 . 58 8 9
0.80
23938.8
13
3 9. 49 99
12.50
4967.418
23950.0
14
39.3329
10.63
4946.422

23971.1
15
39.1660
5.32
4925.430
23992.1
16
38 . 9 99 2
1.78
4 9 04 .4 50
24013.2
17


DU=C:/Bruker/XWIN-NMR, USER=VH_KINH, NAME=KINH_HM1, EXPN0=3, PR0CN0=1
Fl=215.000ppm, F2=-5.000ppm, MI=0.00cm, MAXI=10000.00cm, PC=1.400
#

ADDRESS

1
2
3
4

13318 .1
14046.3
14242.0
24583.7

FREQUENCY
[Hz]
[PPM]
15323.272
121.8474
116.5414
14655.991
14476.641
115.1152
4999.019
39.7511

I N T EN S I T Y
5.98
5.51
6.50
1.30


DU=C:/Bruker/XWIN-NMR, USER=VH_KINH, NAME=KINH_HM1, EXPN0=4, PR0CN0=1
Fl=215.000ppm, F2=-5.OOOppm, MI=0.00cm, MAXI=10000.00cm, PC=1.400
#

ADDRESS

1
2
3
4

13318 .1
14046.2
14241.9
24582.6

FREQUENCY
[Hz]
[PPM]
15323.309
121.8477
14656.019
116.5416
115.1157
14476.699
5000.012
39.7590

INTENSITY
6.25
5.76
6.50
1.26


KINH-HM1-DMSO-C13CPD
cr>
IT)
a\

•

VD

•

CM

•

C
30

00

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OCT»OOr^’X>lDLOrOrH(T>
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S
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Current Data Parameters
NAME
KINH_HM1
EXPNO
2
PROCNO
1
F2 - Acquisition Parameters
20070516
Date_
Time
11.19
INSTRUM
av500
5 mm Multinucl
PROBHD
zgpg30
PULPROG
65536
TD
CDC13
SOLVENT
256

NS
2
DS
SWH
32679.738 Hz
0.498653 Hz
FIDRES
AQ
1.0027661 sec
RG
3649.1
DW
15.300 usee
DE
6.00 usee
TE
303.1 K
D1
2.00000000 sec
0.03000000 sec
dll
DELTA
1.89999998 sec
MCREST
0.00000000 sec
MCWRK
0.01500000 sec
NUCl
PI
PLl

SFOl

CHANNEL fl =========
13C
8.60 usee
-1.00 dB
125.7703643 MHz

CPDPRG2
NUC2
PCPD2
PL2
PL12
PL13
SF02

CHANNEL f2 ========
waltzl6
IH
88.00 usee
-3.00 dB
15.47 dB
22.00 dB
500.1320005 MHz

F2 - Processing parameters
SI
32768
125.7578513 MHz
SF

WDW
EM
SSB
0
LB
1.00 Hz
GB
0
PC
1.00

200

180

160

140

120

100

80

60

40

20

0 ppm


KINH-HM1-DMS0-C13CPD
c>
r

VO

o lO

00

VD
r '

in

uo

CJ
N

ơ
^

r-

r

H
r
H

CJ CJ
N N

Current Data Parameters
NAME
KINH HMl
EXPNO
2
PROCNO
1
F2 - Acquisition Parameters
20070516
Date
11.19
Time
INSTRUM
av500
PROBHD
5 mm Multinucl
zgpg30
PULPROG
TD
65536
SOLVENT
CDC13
NS

256
DS
2
SWH
32679.738 Hz
FIDRES
0.498653 Hz
AQ
1.0027661 sec
RG
3649.1
DW
15.300 usee
DE
6.00 usee
TE
303.1 K
D1
2.00000000 sec
0.03000000 sec
dll
DELTA
1.89999998 sec
MCREST
0.00000000 sec
MCWRK
0.01500000 sec
NUCl
PI
PLl

SFOl

13C
8.60 usee
-1.00 dB
125.7703643 MHz

= = = = = CHANNEL
====
CPDPRG2
NUC2
PCPD2
PL2
PL12
PL13
SF02

f2 ========
waltzl6
IH
88.00 usee
-3.00 dB
15.47 dB
22.00 dB
500.1320005 MHz

F2 - Processing parameters
SI
32768
SF

125.7578513 MHz
WDW
EM
SSB
0
LB
1.00 Hz
GB
0
PC
1.00

170

165

160

155

150

145

140

135

130

125

120

ppm


KINH-HM1-DMS0-C13CPD&DEPT
DEPT9O

^ T ' ............I ’ "

200

190

T -p
-T-r

-r-rỵr^

180

170

160

150

140

130

120

110

100

90

80

180

170

160

150

140

130

120

110

100

90

80

" ' i " .............. I ’ ■■

'■ ‘
r

■' I • •

70

60

50

-r.rp
^

T-p
^ -r

• ■I ”

70

60

50

‘ M^

40

^ " I"

30

20

■■I ■■

■■I ■■

40

30

' ' 1■
■

ppm

DEPT135
CH&CH3

CH2
200

190

20

ppm


KINH-HM1-DMS0-C13CPD&DEPT
DEPT90

165

160

155

150

145

140

135

130

125

120

115

110

ppm

160

155

150

145

140

135

130

125

120

115

110

ppm

160

155

150

145

140

135

130

125

120

115

110

ppm

DEPT135
CH&CH3

CH2
165

C13CPD

165


D U= C : / B r u k e r / X W I N - N M R , USER=VH_KINH, NAME=KINH_HM1, EXPN0=2, PR0CN0=1
F l = 2 4 0 . 0 0 0 p p m , F 2 = - 5 . OOOppm, MI=0.00cm, MAXI=10000.00cm, PC=1.400
FREQUENCY
I N T EN S I T Y
ADDRESS
#
[Hz]
[PPM]
21036.311
7837.7
167.2763
0.45
1
18 858.576
149.9594
0.59
10021.3
2
18215.510
144.8459
0.72
10666.1
3
15322.783

13566.7
121.8435
0.78
4
121.6841
15302.729
0.45
13586.8
5
14655.866
116.5404
14235.4
0.78
6
14476.592
115.1148
14415.2
0 .88
7
5030.381
40.0005
1.75
23886.9
8
5020.729
39.9238
0. 48
23896.6
9
39.8337

5009.399
5.33
23907.9
10
39.7570
4999.755
0.79
23917.6
11
4988.411
39. 6668
10.65
23929.0
12
4 978.617
39 . 58 8 9
0 .8 0
23938.8
13
4967.418
39 . 49 99
12.50
23950.0
14
4946.422
39.3329
10.63
23971.1
15
4925.430

39.1660
5.32
23992.1
16
3 8 .9 99 2
4 9 04 .4 50
1.78
24013.2
17


DU=C;/Bruker/XWIN-NMR, USER=VH_KINH, NAME=KINH_HM1, EXPN0=3, PR0CN0=1
Fl=215.OOOppm, F2=-5.OOOppm, MI=0.00cm, MAXI=10000.00cm, PC=1.400
#

ADDRESS

1
2
3
4

13318 .1
14046.3
14242.0
24583.7

FREQUENCY
[Hz]
[PPM]

15323.272
121.8474
14655.991
116.5414
14476.641
115.1152
4999.019
39.7511

I N T EN S IT Y
5.98
5.51
6. 5 0
1.30


DU=C:/Bruker/XWIN-NMR, USER=VH_KINH, NAME=KINH_HM1, EXPN0=4, PR0CN0=1
Fl=215.OOOppm, F2=-5,OOOppm, MI=0.00cm, MAXI=10000.00cm, PC=1.400
#

ADDRESS

1
2
3
4

13318.1
14046.2
14241.9

24582.6

FREQUENCY
[Hz]
[PPM]
15323.309
121.8477
14656.019
116.5416
14476.699
115.1157
5000.012
39.7590

INTENSITY
6.25
5.76
6.50
1.26


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Current Data Parameters
NAME
KINH__HM1
EXPNO
1
PROCNO
1

CJC
N vJ

F2 - Acquisition Parameters
Date_
20070516
Time
11.33
INSTRUM
av500
PROBHD
5 m m Multinucl
zgSO
PULPROG
TD
65536
SOLVENT
DMSO
16
NS
DS
0
SWH
10000.000 Hz
FIDRES
0.152588 Hz
3.2769001 sec
AQ
RG
161.3
DW
50.000 usee
DE

6.00 usee
302.7 K
TE
D1
1.00000000 sec
0.00000000 sec
MCREST
0.01500000 sec
MCWRK

NUCl
PI
PLl
SFOl

CHANNEL fl ========
IH
10.50 usee
-3.00 dB
500.1335009 MHz

F2 - Processing parameters
SI
32768
SF
500.1300027 MHz
WDW
EM
SSB
0

LB
0.30 Hz
GB
0
PC
1.00

14

13

12

11

10

0 ppm

8

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Current Data Parameters
NAME
KINH^HMl
EXPNO
1
PROCNO
1
F2 - Acquisition Parameters
Date_
20070516
Time
11.33
INSTRUM
av500
PROBHD
5 m m Multinucl
PULPROG
zg30
TD

65536
SOLVENT
DMSO
NS
16
DS
0
SWH
10000.000 Hz
FIDRES
0.152588 Hz
AQ
3.2769001 sec
RG
161.3
DW
50.000 usee
DE
6.00 usee
TE
302.7 K
D1
1.00000000 sec
M CREST
0.00000000 sec
MCW R K
0.01500000 sec

===
= = ====

NUCl
PI
PLl
SFOl

CHANNEL fl ========
IH
10.50 usee
-3.00 dB
500.1335009 MHz

F2 - Processing parameters
SI
32768
SF
500.1300027 MHz
WDW
EM
SSB
0
LB
0.30 Hz
GB
0
PC
1.00

7.4

7.3

O
O
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•
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—

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—

7.2

7.1

7.0

6.9

6.8

ppm


D U =C : / B r u k e r / X W I N - N M R , USER= =VH_KINH, NAME=KINH_HM1, EXPN0=1, PR0CN0=1
F l=18.OOOppm, F 2= - l . O OO p p m, MI=0.83cm, MAXI=10000.00cm, PC=1.000
FREQUENCY

I N T EN S I T Y
ADDRESS
#
[PPM]
[Hz]
7.3384
8 .98
3670.131
15820.6
1
3668.122
7.3343
10.23
15827.2
2
7.2980
5.23
36 49 . 9 38
15886.8
3
3 6 4 7. 9 0 4
7.2939
4.30
15893.5
4
3641.716
7.2815
5.51
15913.8
5

7.2775
4.76
3639.681
15920.4
6
3395.781
6.7898
8.81
16719.6
7
6.7733
8.45
3387.555
16746.6
8
5.6626
2832.035
2.9 1
18566.9
9
3.3577
16.00
1679.285
22344.3
10
2.5125
6. 0 9
1256.598
23729.3
11

2.5091
11.5 2
1254.886
23734.9
12
2.5055
15.08
1253.099
23740.8
13
2.5019
11.02
1251.300
23746.7
14
2.4986
5.39
1249.628
23752.2
15


KINH-HMl-DMSO-IH
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Current Data Parameters
NAME
KINH_HM1
EXPNO
1
PROCNO
1

w

F2 - Acquisition Parameters
Date_
20070516
Time
11.33
INSTRUM
av500
PROBHD
5 m m Multinucl
PULPROG
zg30
TD
65536
SOLVENT
DMSO
NS
16
DS
0
SWH
10000.000 Hz
FIDRES
0.152588 Hz
AQ
3.2769001 sec
RG
161.3
DW
50.000 usee
DE

6.00 usee
TE
302.7 K
D1
1.00000000 sec
MCREST
0.00000000 see
MCWRK
0.01500000 sec

NUCl
PI
PLl
SFOl

CHANNEL fl ========
IH
10.50 usee
-3.00 dB
500.1335009 MHz

F2 - Processing parameters
SI
32768
SF
500.1300027 MHz
WDW
EM
SSB
0

LB
0.30 Hz
GB
0
PC
1.00

12

11

10

0 ppm

8
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KINH-HMl-DMSO-lH
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Current Data Parameters
NAME
KINH HMl
1
EXPNO
1
PROCNO

r- r- r- r-

F2 - Acquisition Parameters
20070516
Date
11.33
Time
INSTRUM
av500
PROBHD
5 m m Multinucl
PULPROG
zg30
TD
65536
SOLVENT
DMSO
16
NS
0
DS
SWH
10000.000 Hz
0.152588 Hz
FIDRES
3.2769001 sec
AQ
161.3
RG
DW

50.000 usee
DE
6.00 usee
302.7 K
TE
1.00000000 sec
D1
MCREST
0.00000000 sec
0.01500000 sec
MCWRK

NUCl
PI
PLl
SFOl

= CHANNEL fl ===== = = = =
IH
10.50 usee
-3.00 dB
500.1335009 MHz

F2 - Processing parameters
SI
32768
500.1300027 MHz
SF
WDW
EM

SSB
0
0.30 Hz
LB
GB
0
PC
1.00

u

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7.4

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7.2

7.3

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1

7.1

7.0

6.9

6.8

ppm