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ABS
ABS
ABS

2.63365 NM
3.82449 NM
3^55736 NM

0

ABS

294.000
258.000
227.000

.0414 ẳ:?slleu

93 SBU 2.0
0FF Page 3

Basel irie

•

8 May 2007

600.00

PHỤ LỤC I.

NM

Phổ uv của chất HMt.

PHỤ LỤC
•
250.00

Phổ MS của chất HMj.
350.00

450.00

550.00

ABS
: -0.1997 -> 4.2457
NM :
202.00 -> 600.00
Basel
ine
Erase
ụ
ieu
Re-scale
Zoom
Cursor
ỉlTBn
More
Phụ lục I: Các phổ của chất HMị.

Urite labels OTỊ the graph___________________________________________________


m/ z
abund.
m/z
abund.
m/ z
abund.
50.10
61.05
2245
72.15
477
Scan
79 (4.5896528
min): D-DIP100.D
51.10
9637 HM1 62.05
3919
73.05
3295
52.10
6968
63.05
9748
74.05
909
m/z
10617

64.05
1916
77.05
1525
53.10
File3485
C:\HPCHEM\1\DATA\D-DIP100.D
85.05
65.05
1005
78.05
558
54.10
Operator
Phong Cau truc,
Hoa hoc
86.05
11649
66.05
800 vien
79.05
3314
55.10
Acquired
9
May
107
1:16
pm
using AcqMethod

DEFAULT
87.05
1874
67.05
1519
80.05
2607
56.10
Instrument
598 9B
91.05
6057
68.15
1487
81.05
11449
57.10
Sample Name
MS
92.05
845
69.05
5215
82.05
1534
58.10
Misc Info
HM1
93.05
1707

83.05
2847
59.10
vial 675
Number 70.05
CHC13 + CH30H
94.05
3801
71.05
3585
84.05
1414
60.10
1
95.05
Scan 79 (4 .589 min):
D-DIP100 . D
96.05
HM1
97.05
98.05
abund.
m/z
abund.
m/z
abund.
m/z
657
119.05
1173

139.05
1174
99.15
531
121.05
785
143.10
304
101.05
360
123.05
468
149.00
574
105.05
m/ z
2233
124.05
345
152.00
322
107.05
2456
125.05
1098
154.00
43568
108.05
19952
126.05

3346
155.00
4122
109.05
2000
127.05
590
156.00
505
110.05
1311
129.05
1493
157.00
323
111.05
640
135.15
352
171.10
336
112.15
628
137.05
57376
184.00
320
113.05
549
138.05

5534
115.05

2590
334
1059
2337
482
687
339
854
895
4193
1049

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—I—’—■—■——I—■—■—■—■—í ................ . . I '
Current
Data Parameters
NAME
KINH HM1
EXPNO
2
PROCNO
1
1

1

■ ' I

1 1

'

1

I ■ ' ■

1

I

1

1

KINH-HMl-DMS0-C13CPD

F2 - Acquisition Parameters
Date_
20070516
Time 16
11.19
^
00
INSTRƯM
av500
7.
00 Cò
PROBHD
5 mm Multinucl
27
PULPROG
zgpg30
6
TD
65536
SOLVENT
CDC13
256
NS
2
DS

32679.738Hz
SWH
0.498653Hz
FIDRES
1.0027661sec
AQ
RG
3649.1
15.300usec
DW
DE
6.00usec
TE
303.1K
DI
2.00000000sec
dll
0.03000000sec
DELTA
1.89999998sec
MCREST
0.00000000sec
MCWRK
0.01500000sec
SI
32768
SF
125.7578513MHz
WDW
EM

SSB
0
LB
1.00Hz
GB
0
PC
1.00
T
1

(T
l
LT
>
CT
i

o
IT >

rH

ư~)
f—
vô LO

00

1

T-'
I

======== CHANNEL fl ========
NUC1
13C
P1
8.60
usec
PL1
-1.00 dB
SF01
125.7703643 MHz
CHANNEL f2 ========
waltzl6
CPDPRG2
1H
NUC2
88.0
usec
PCPD2
-3.00 dB
PL2
15.47
PL12
I 22.0 dB dB
PL13
500.1320005 MHz
SF02

I

F2 - Processing parameters

130

165
12
5

160
' I
'
120

155

ppm

150

145

140

135


1

irn

' * 11 ■'1' ■ ’1 ■ I
............I'"

Tnr

KINH-HM1-DMS0-C13CPD&DEPT

DEPT90

DEPT135

■ ■ ’ I. I ■
■ ■
200

CH2

190

ỉ. . .,,,-,|..... .1-iỴ-ĩ-r-r

180

170

160

150

140

130

120

'"I....'-"ị"'
110 100

"T"
90

80

' ■
I"
70

60

T^prr

H-ry^T-

50

40

"r"
r
T"r
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20

■ I.
ppm


r

f

—I—

155

KINH-HM1-DMSO-C13CPD&DEPT

DU=C:/Bruker/XWIN-NMR,
USER=VH_KINH,
NAME=KINH_HM1,
EXPN0=3,
PR0CN0=1
DU=C:/Bruker/XWIN-NMR,
USER=VH_KINH,
NAME=KINH_HM1,
EXPN0=4,

DU=C:/Bruker/XWIN-NMR,
USER=VH_KINH,
NAME=KINH_HM1,
EXPN0=2,
Fl=215.OOOppm,
F2=-5.OOOppm,
MI=O.OOcm,
MAXI=10000.OOcm,
PC=1.400
PR0CN0=1

—I—’
PR0CN0=1
Fl=215.OOOppm,
PC=1.400
145
Fl=240.OOOppm, F2=-5.OOOppm,
F2=-5.OOOppm, MI=O.OOcm,
MI=O.OOcm, MAXI=10000.OOcm,
MAXI=10000.OOcm,
PC=1.400
r

r

—I—

DEPT90

1

140

r

—I—’

160
r

—I—’

145
1

r

—I—

160

r

1

170

—I—

165

■—I
—’

160

150

135

130

125

120

115

I

ppm

145

DEPT135
r

—I—’

140

#
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
#
1

F R E Q U E NC Y
I NT E NS IT Y
[ H z]
[ P PM ]
7 837 . 7
2 1 03 6 .3 11
1 67 .2 76 3
0. 4 5
1 0021 . 3

1 885 8. 576
1 49 .9 59 4
0. 59
1 06 66 . 1
1 82 1 5. 51 0
1 44. 84 59
0. 72
13 566 . 7
1 532 2 .7 83
1 21 . 843 5
0. 7 8
13 586
.
8
1
53
02
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29
1
21
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8
41
0. 4 5
CH2
1 42 3 5. 4
1 16 . 54 04
0. 7 8 1
1 46 55. 866

1 441 5. 2
1 447 6 . 592
1 1 5.1 1 48 ' I
0. 8'8 I
170
165
155
23 886 . 9
503 0. 3 81
40. 00 05
1. 7 150
5
23 896 . 6
502 0. 7 29
39 .9 23 8
0. 4 8
23 9 07 . 9
50 09 .3 99
39 . 833 7
5. 33
23 91 7. 6
499 9 .7 5 5
39 .7 57 0
0. 79
23 92 9. 0
49 88. 411
39 .6 66 8
1 0. 6 5
23 93 8. 8
497 8. 6 17

39 . 58 89
0. 8 0
23 9 50. 0
496 7 . 41 8
39 . 499 9
1 2. 5 0
23 97 1. 1
49 46 . 422
39 .3 32 9
1 0. 63
23 99 2. 1
492 5. 43 0
39 .1 66 0
5. 32
2 4013 . 2
49 04. 45 0
3 8.9 99 2
1. 7 8
AD D R ES S
F R E Q U E NC Y
IN T E NS IT Y
[ H z]
[P P M]
13 31 8. 1
5. 9 8
1 532 3 .2 72
12 1. 8 47 4
1 4046 .I
3 • T 1 1 46 '
55.I9 91

r
11 6. 5 41 4
5. 51
1 42 42
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1 447165
6 .6 41
6 . 50150
1 1 5.1 1 52
155
170
2 4583 . 7
499 9 . 019
1 .3 0
3 9. 7 511
AD D R ES S
FR E QU E N C Y
I NT E NS IT Y

1

AD D R ES S

140

135

130

125

120

115

135

130

125

120

115

C13CPD

2
3
4
#

ỉ

ppm

ppm


[ H z]

[ P PM ]
1 21 . 847 7
1 33 1 8.1
1 532 3 .3 09
1 40 46 .2
1 46 56 . 019
1 16 . 541 6
I
11 5. 11 57
1 447 6 .6 99
O 1 42 41 .9
o 2 45 82 .6
39 .7 59 0
50 00. 012
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6
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00
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121.844
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121.684 2 s
116.540
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115.115
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1
2
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6. 2 5
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1. 26

KINH-HM1-DMS0-C13CPD

167.276

149.959

0 TI TJ P3 z 0
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ft
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0 0 M 0
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M 0 co
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0 0 CO c
C
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0 0 0 0CD
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Data Parameters
KINH HM1

2
1
F2 - Acquisition Parameters
00
Date_
20070516
Timeo
11.19
INSTRUM
av500
PR0BHD
5 mm Multinucl
PULPR0G
zgpg30
TD
65536
S0LVENT
CDC13
NS
256
ơì
DS
2
SWH o
32679.738Hz
0.498653Hz
FIDRES
AQ
I 1.0027661sec
RG

3649.1
DW
15.300usec
DE
6.00usec
TE o
303.1K
DI
2.00000000sec
dll
0.03000000sec
DELTA
1.89999998sec
MCREST
0.00000000sec
MCWRK
0.01500000sec

00
vo
• •
TH T—1
CN CN
rH rH
00

o L
\
LO ĩ
• •

VO L
r —1 1
r H« H

I

Ở
g

ộ

NAME
EXPN0
PR0CN0

NUC1IO
P1
PL1 o

o -

-

00 7V KTXTI?T L-rlAiNMCiLi
13C
8.60usec
-1.00dB
o o o o í

I

õ
ụ>
o

Ố
40.001

39.924

39.834

39.757

K
<
z

t-3

c

M
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N

ọ
oT
CU

SF01
CPDPRG2
NUC2
PCPD2
PL2
PL12
PL13
SF02

125.7703643MHz
_ ruaMMPT -F9- - -=
LilrilNlNlliL
waltzl6
1H
88.00usec
-3.00dB
15.47dB
22.00dB
500.1320005MHz

F2 - Processing parameters
SI
32768
SF
125.7578513MHz
WDW
EM
SSB
0

LB
1.00Hz
GB
0
PC
1.00


KINH-HM1-DMSO-C13CPD&DEPT
DEPT90

■ ■ l. I.....I
30

20

ppm

DEPT135

1 1 1. . . .I J ....I ....... r-, l-rrm .... I , .-. . . r , , ,-| . .Tị-, , .. . ......... I.................................. . . I.....................ị..............................
I.......T^rryrr ...... T-,-,-r T- r, ị................r I^r_1-I r, r, r, I.........I ........ r .-| . . ..... . . ,..............I..........................

200

CH2
190

180

170

160

150

140

130

120

110

100

90

80

70

60

50

-1—I—I—I—I—I—I—I—I—I—I—I—I—I—I—I—I—I—I—I—I—I—I—I—I—I—I—I—I—I—I—I—I—I—I—I—I—I—I—I—

' I '

170

165

I
160

155

7

1
145

140

1
135

130

r
125

120

ppm

40

30

20

ppm


r

—í—

1

150
DU=C:/Bruker/XÍỈIN-NMR,
USER=VH_KINH,
NAME=KINH_HM1,
EXPN0=3,
DU=C:/Bruker/XWIN-NMR,
NAME=KINH_HM1,
EXPN0=4,
PR0CN0=1
DU=C:/Bruker/XWIN-NMR, USER=VH_KINH,
USER=VH_KINH,
NAME=KINH_HM1,
EXPN0=2,
PR0CN0=1
PR0CN0=1
1
Fl=215.OOOppm,

F2=-5,OOOppm,
MI=O.OOcm,
MAXI=10000.OOcm,
Fl=240.OOOppm,
F2=-5.OOOppm, MI=O.OOcm, MAXI=10000.OOcm, PC=1.400
PC=1.400
—I—
Fl=215.OOOppm,
130 F2=-5.OOOppm, MI=O.OOcm, MAXI=10000.OOcm, PC=1.400

KINH-HM1-DMSO-C13CPD&DEPT

r

r

DEPT90

1

—I—

145

r

—I—

1

140

—I—

r

160

1

165

155

I

145

140

135

125

120

115

110

—' I
ppm

T

DEPT135
#

AD D R E SS

1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
#
1

7 83 7 .7
1 002 1 .3
1 066 6 .1
13 566 . 7
1 3 586 . 8
1 42 3 5. 4
1 441 5. 2
2 3 886 .9
2 3 89165
6 .6
2 39 07 .9
2 39 17 .6
2 39 29 . 0
2 39 3 8. 8
2 39 50. 0
2 39 71 .1
2 39 92 .1
2 401 3 .2
AD D R ES S

CH2

C13CPD

2
3
4
#

160

1

1 33 1 8.1
1 40 46 .3
1 42 42 . 0
2 4583 . 7
AD D R165
ES S

—I—

145
FR E QU E N C Y
IN T E NS IT Y
[H z ]
[P P M]
21 036 . 31 1
16 7. 27 63
0. 45
1 88 58. 57 6
1 49 . 9 59 4
0. 59
1 821 5. 51 0
1 44. 8 459
0. 7 2
1 53 22 . 7 83
12 1. 8 43 5
0. 7 8
1 53 02 . 72 9

12 1. 6 841
0. 45
1 46 5 5. 86 6
11 6. 5 40 4
0. 7 8
1 4476 . 59 2
11 5. 11 4 8
0. 88
5 03 0.
4
0.
0
00
5
1 .7 5
1 3 81
'—I—
5 02 0. 72 9
3
9.
92
3
8
0. 48
155
150
160
5 009 . 39 9
3 9. 83 37
5. 3 3

49 99 . 7 55
3 9. 7 57 0
0. 7 9
49 8 8. 41 1
3 9. 66 6 8
1 0.6 5
49 7 8. 61 7
3 9. 5 889
0. 80
49 67 . 41 8
3 9. 49 99
12 . 50
49 46 . 42 2
3 9. 33 29
1 0.6 3
49 2 5. 43 0
3 9. 16 6 0
5. 3 2
49 0 4. 4 50
3 8. 99 92
1 .7 8
FR E QU E N C Y
IN T E NS IT Y
[ H z]
[ P PM ]
1 532 3 .2 72
1 21 . 847 4
5. 9 8
1 46 55. 9 91
1 16 . 541 4

5. 51
1 447 6 .6 41
11 5. 11 52
6 . 50
499 9 . 019
39 .7 51 1
1 .3 0
F R E Q U155
E NC Y
IN T E NS IT Y
150

—T—I

135

130

125

120

115

110

135

130

125

120

115

110

ppm

—T—I

140

ppm


1
2
3
4

13 31 8. 1
1 4046 . 2
1 42 41 . 9
2 4582 . 6

00
00
C r- o ro

co ro as cr 00 r* CT r*
ro ro C C C C r- r-

o r * V£
o r o C?\
o o o
• • •
ĩ — \ — rH
Date_
1 1

ro
VD

vo

co

00 00
00 00

[ P PM ]
1 21 . 847 7
1 16 . 541 6
11 5. 11 57
39 .7 59 0

00ro ơ\ vo LOĩ—1o o o CT
roưo LO LT LO

>
00 ^ CNJ

6 .2 5
5. 7 6
6 . 50
1 .2 6

KINH-HM1-DMS0-1H
KINH-HM1-DMSO-1H
o 00

ữl ƠI 00
O'
OJ CNJ CM

CT|
rr- r-

r- r- r- r -

20070516
11.33
av500
5 mm Multinucl
zg30
65536
DMS0
16
0

10000.000Hz
0.152588Hz
3.2769001sec
161.3
50.000usec
6.00usec
302.7K
1.00000000sec
0.00000000sec
0.01500000sec

Time
INSTRUM
PR0BHD
PULPR0G
TD
S0LVENT
NS
DS
SWH
FIDRES
AQ
RG
DW
DE
TE
DI
MCREST
MCWRK
NUC1

P1
PL1
SF01

[ H z]
1 532 3 .3 09
1 46 56 . 019
1 447 6 .6 99
50 00. 012

Current
NAME
EXPNO
PROCNO 1

I

10.50usec
-3.00dB
500.1335009MHz

F2 - Processing parameters

o
o
o

X—1

Current

NAME
EXPN0
PR0CN0

32768
500.1300027MHz
EM

0

0.30Hz
0
1.00
r00

o
t—1

Data Parameters
KINH HMl
1
1

F2 - Acquisition Parameters
Date_
Time
INSTRUM
PR0BHD
PULPR0G
TD

S0LVENT
NS
DS
SWH
FIDRES

14

13
20070516 12
7.4
11.33

av500
5 mm Multinucl
zg30
65536
DMS0
16
0
10000.000Hz
0.152588Hz

Parameters
KINH_HM1
1

F2 - Acquisition Parameters

1

r+
TT "n TiT^TT
f
CHANNEL
ri - T-1H

SI
SF
WDW
SSB
LB
GB
PC

Data

11
7.3

10

7.2
9

—ị—I I I' ■ I ■■

8

7
7.1

AẴ

■ I •

6

5
7.0

4

3

2

1

0 ppm


AQ
RG
DW
DE
TE
DI
MCREST
MCWRK
NUC1

P1
PL1
SF01

3.2769001sec
161.3
50.000usec
6.00usec
DU=C:/Bruker/XWIN-NMR,
USER=VH_KINH, NAME=KINH_HM1, EXPN0=1, PR0CN0=1
302.7K
1.00000000sec F2=-l.OOOppm, MI=0.83cm, MAXI=lũOOO.OOcm, PC=1.000
Fl=18.OOOppm,
0.00000000sec
0.01500000sec

KINH-HM1-DMS0-1H

" CHANNEL t1

=

1H
10.50usec
-3.00dB
500.1335009MHz

F2 - Processing parameters
SI
32768

SF
500.1300027MHz
WDW
EM
SSB
0
LB
0.30Hz
GB
0
PC
1.00

#

1
2
3
4
5
6
7
8
9
10
11
12
13
14
15

o ro 00
o o

• ■
t—1\—1
Current
NAME
EXPN0
PR0CN0

AD D R ES S
1 582 0. 6
1 5827 . 2
1 5886 . 8
1 5893 . 5
1 59 13 . 8
1 59 2 0. 4
16 71 9. 6
16 7 46 . 6
1 8566 . 9
22 3 44. 3
23 72 9. 3
23 73 4. 9
23 7 40. 8
23 7 46 . 7
23 7 52 . 2

oọ^ọo^cNr-oro
rO(r)ữiCTioor'ơir'
corocNCNCNCNr-rr-r^r^r-r-r^vovo

FR E QU E N C Y
[ H z]
[P P M]
36 7 0.1 31
7 .3 3 84
36 6 8.1 22
7. 33 43
36 49 .9 3 8
7. 29 8 0
36 47 .9 0 4
7. 29 39
36 41 .7 16
7. 2 81 5
36 39 .6 81
7. 27 7 5
33 9 5.7 81
6. 7 89 8
33 87 . 55 5
6. 77 33
2 83 2 . 03 5
5. 66 26
16 79 .2 8 5
3 .3 57 7
1 2 56 . 59 8
2 . 512 5
12 54. 886
2. 5 091
12 53 . 099
2 . 505 5

12 51 .3 0 0
2. 5 019
12 49 .6 2 8
2. 49 86

ro
vo
vo

00
LO
ro

ro ơì vo CM ơ\
rH o o oCTl
LO LO uo LO ^

rõ

oj c\iCNJCsĩc\j

IN T E NS IT Y
8. 9 8
1 0.2 3
5. 2 3
4. 3 0
5. 51
4. 7 6
8. 81
8. 45

2 .9 1
16 . 00
6 . 09
11 . 52
1 5. 08
11 . 02
5. 3 9

vo
CM

o
•

rH

Data Parameters
KINH HM1
1
1

F2 - Acquisition Parameters
Date_
Time
INSTRUM
PR0BHD 12
PULPR0G
TD
S0LVENT
NS

DS
SWH
FIDRES
AQ
RG

20070516
11.33
av500
11
5 mm Multinucl 10
zg30
65536
DMS0
16
0
10000.000Hz
0.152588Hz
3.2769001sec
161.3

7

AA

A

6.9

6.8 ppm

Cs
J

o


DW
DE
TE
DI
MCREST
MCWRK

50.000usec
6.00usec
302.7K
1.00000000sec
0.00000000sec
0.01500000sec

KINH-HMl-DMSO-1H

— r*u7\ VTVTPT f 1
NUC1
P1
PL1
SF01

1H

10.50usec
-3.00dB
500.1335009MHz

o co

Ch r-

r- r-

F2 - Processing parameters
SI
SF
WDW
SSB
LB
GB
PC
00'vT
ro CO
coco

• •
r-r-

32768
500.1300027MHz
EM
0
0.30Hz

0
1.00
00
CN1
(T> Ch 00
1
• • • •
r- r- r- r-

Current
NAME
EXPNO
PR0CN0

Data Parameters
KINH HM1
1
1

F2 - Acquisition Parameters
20070516
Date_
11.33
I
Time
av500
INSTRUM
PROBHD
5 mm Multinucl

PULPROG
zg30
TD
65536
SOLVENT
DMS0
NS
16
DS
0
SWH
10000.000Hz
FIDRES
0.152588Hz
AQ
3.2769001sec
RG
161.3
DW
50.000usec
DE
6.00usec
TE
302.7K
DI
1.00000000sec
MCREST
0.00000000sec
MCWRK
0.01500000sec

NUC1
P1
PLl
SF01
F2 SI
SF
WDW
SSB
LB
GB
PC

o
o
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■
X—1

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-P1
,
—
u il/ilN
JN ỉli 1J
1H
10.50usec
-3.00dB
500.1335009MHz
Processing parameters
32768

' I 1
500.1300027 MHz
EM
■"'■
0
7.3
0.30 Hz
0
1.00

k

00
o
•
\—
1

"T"'"

7.2
8

• I................I..................I.................I.................I

7.1

7.0
ppm

6.9

6.8

0 ppm
C
M
o


#

AD D R ES S

F R E Q U E NC Y
I NT E NS IT Y
22/Jul/2007
22/Jul/2007 10:04:10
10:04:31 ACD/CNMR
ACD/HNMR DB
DB (v.6.12)
(v.6.12)
[H z ]
[ P PM ]
1 582 0. 6
3 67 0. 13 1
7. 33 8 4
8.
9
8

HO
.
HO.
DU=C:/Bruker/XWIN-NMR,
USER=VH_KINH,
NAME=KINH_HM1,
EXPN0=1, PR0CN0=1
1 582
7 .2
3 66 8. 12 2
7 .3 3 43
111
0.1Í\
23
\99^10
^10
MAXI=10000.òũcm,
PC=1.000
1 58Fl=18.OOOppm,
86 . 8
3 6 49F2=-l.OOOppm,
. 93 8
7 .2MI=0.83cm,
9 80
5. 23
1 589 3 . 5
3 6 47 . 9 04
7 .2 93 9
4. 3 0
5. 51

1 591 3 . 8
3 6 41 . 71 6
7 .2 81 5
1 592 0. 4
4. 76
3 63 9. 6 81
7 .2 77 5
7.5.6:
1 67 19
8. 81
3 39 5. 7 81
6 .7 89 8
1 67 46 .6
8. 4 5
3 3 87 . 5 55
6 .7 73 3
1 856 6 .9
2. 91
2 832 . 03 5
5. 6 62 6
6ĨT
2 23 4 4.3
1 6. 0 0
1 67 9. 2 85
3. 3 577
2 37 29 .3
6. 09
-7-58[6]
12 56 . 59 8
2. 51 2 5

2 37 3 4.9
1
1.
52
1
2
54.
8
86
2
.
509
1
ãõ"
2 37 40. 8
1 5. 0 8
1 2 53 . 09 9
2. 5 055
2 37 46 .7
1 1. 02
1 2 51 . 3 00
2 . 501 9
OH
2 37 525^
.2
1 2 49 . 62 8
2 . 49 86
5. 39 OH

1

2
3
4
5
6
7
8
9
10
11
12
13
14
15

Carbon No.
1
2
3
4
5
6

9
J
3
J

pHr Chem. Shifts
120 i

145

88

Conf. Limits
—

c 5Ã
c

144.1
117.3
122.9
cĨÕÕ 127.7
CH
118.3
ĩõi
c 90 169.64

—
—
—
—

CH
110
CH

122.90(4)

118.30(6)

117.30(3)

—
2.7

Grp.1 Grp.2 Value Error
80"
4
3 8.50
—
70"
3.5

60"

50"

Group n Sh i f t Error
H 6.94
—
3
1
4
—
1 7.52
—
6
1 7.58

7
2.73
1 6.69
8
11

1 7.89
1 9.69

6.95[3Ị

2*m

6.93[3]

1.58
0.59
1

40"

1

7.0
1

25

I

30"
20^1
20"
Ĩ5

144.10(2)
145.00(1) " \

169.64(9)

127.70(5)

1.0
0.5 :

10 :

-gjg11]
õ.o

I
1 .

1
.

1

7.89[8]

i-T-T-ri
I'
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I I I I I I I I -I- I- -1-----1-----1
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155

150

145

2.- ^

tná *'S>£'*pfí-ỉ?9T><ỷ-

VAS/Q
ề

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140

135
rĩUí

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t 7.5

130
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125

JL
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120

JU1

I T p-r-T-T-T rm-p

1156.5


PHỤ LỤC II.

Phổ MS của chất RM2


m/ z
abund.
m/z
abund.
m/ z
abund.
51.15
1716
62.15
257
73.10
13648

D-DIP112.D
Scan
20
(0.724
min) 63.05
52.15
1097
597
74.10
1903
File
53.15
5888 RM2
64.00
859
75.10
498
C:\HPCHEM\1\DATA\D-DIP112.D
Operator 3743
54.15
65.00
4134
77.10
10468
Phong Cau truc, vien Hoa hoc
55.15
1901
78.10 AcqMethod
2932
Acquired 31680

1066.10
May 107
5:08 pm using
HIDIP
56.15
27112
67.10
13067
79.10
15152
Instrument
598 9B MS
57.15
52072
68.10
6193
80.10
4363
Sample Name
RM2
58.15
9756
69.10
16119
81.10
11970
Misc Info
CH30H + CHC13
59.15
2466

230528
82.10
9239
vial Number
1 70.10
60.05
5249
71.10
24448
83.10
10248
61.15
72.10
3979
84.10
6425
1816
Scan 20 (0. ,724 min): D-DIP112 . D
m/z
m/ z
abund.
m/ z
abund.
RM2
97.10
98.10
99.10
100.10
101.10
102.10

103.10
104.10
105.10
106.10
107.10

8381
abund.
3059
2860
728
851
535
1951
1322
9673
3613
5768
. 724 min)
:
Scan 20 (0,
RM2
141.10
m/ z
142.10
143.10
144.10
145.10
146.10
147.10

148.10
149.10
150.05
151.05
Scan 20 (0.

abund.
1971
1005
1926
1149
2424
1366
3242
1583
2448
1287
931
,724 min):
RM2

108.10
109.10
110.10
111.10
112.10
113.10
114.10
115.00
116.10

117.10
118.10
D-DIP112

.
D

152.05
m/ z
153.05
154.05
155.05
156.05
157.05
158.05
159.05
160.05
161.05
162.05
D-DIP112

.
D

m/ z
85.10
86.10
87.10
88.10
89.10

91.00
92.10
93.10
94.10
95.10
96.10

abund.
7456
2653
1719
502
726
17408
3288
8956
6532
8996
14283

m/ z

abund.

4399
5328
2954
4646
2525
2097

496
3117
1267
4464
1838
abund.

119.10
120.10
121.10
122.10
123.10
124.10
125.10
126.10
127.10
128.10
129.10
m/ z

7096
3424
4422
8537
3607
1939
2220
932
2191
2532

5108
abund.

130.10
131.10
132.10
133.10
134.10
135.10
136.10
137.10
138.10
139.10
140.10
m/ z

1448
3494
1743
2927
2587
3001
2055
1615
856
1128
504
abund.

687

836
626
1404
636
1646
819
1819
1000
1265
716
abund.

163.15
164.05
165.05
166.05
167.05
168.05
169.05
170.05
171.05
172.05
173.05
m/z

973
491
805
359
959

598
896
442
1175
565
923
abund.

174.05
175.15
176.15
177.15
178.15
179.05
180.15
181.05
182.15
183.15
184.05
m/ z

756
723
1167
682
409
426
314
500
417

755
343
abund.

190

209.15

169

224.25

154

abund.
185.05
m/z

863

196.15
m/ z


186.05
187.15
188.15
189.15
190.05
191.15

192.15
193.05
194.15
195.05
Scan 20 (0.724

488
488
539
543
492
890
333
346
188

197.15
198.15
199.15
200.15
201.15
202.15
203.15
204.15
205.15
255
min) :
RM2

m/z abund.

240.20
240
241.20
609
242.20
1079
243.20
334
244.20
1711
245.20
498
246.20
233
252.20
171
253.20
243
254.20
376
255.20
604
Scan 20 (0.724
min) :
RM2
m/z abund.
327.25
328.25
329.25
219.15

m/ z
272.20
273.20
274.20
279.20
282.30
283.20
284.20
285.20
289.20
295.30

554
390
705
451
436
328
306
283
283

210.15
211.15
212.15
213.15
214.15
215.15
216.15

217.15
218.15
206.15
D-DIP112.D

m/ z
256.20
257.20
258.20
259.20
260.20
261.20
267.30
268.30
269.20
270.20
271.20
D-DIP112.D
m/ z

591
952
356

206
374
243
581
700
367

623
579
698

225.15
226.15
227.15
228.15
229.15
230.25
231.25
232.15
233.25

321
192
229
359
346
425
473
613
333
205

abund.
1216
28192
6483
3158

810
256
153
152
271
387
537

abund.

296

239.20

350

abund.
449
579
209
158
211
210
210
235
266
164

m/ z
297.30

298.30
299.30
300.30
311.30
312.20
313.30
314.30
315.30
325.25

abund.
758
1447
656
217
330
224
373
613
220
288


296.20

641

m/ z

abund.

326.25

m/ z

657

abund.


Library Searched : D:\DATABASE\WILEY275.L
Quaiity
: 42
ID
: Conimine $$ 23-Norcon-5-enin-3-amine, N-methyl-, (3.beta.)~ (CAS) $$ Conimin $$
Norcon-5-enine, 3.beta.-(methylamino)-


f,,

‘ỉ'' '' -r‘-r,lr I —T

Scan 2 (0,

I '

I—T—1—T

.186 min):
RM2

File
m/ z
abund.
Operator
51.15
Acquired 1265
52.15
Instrument 617
53.15
4363
Sample Name
54.15
Misc Info 4994
55.15
62024
vial Number
56.15
25904
57.15
88568
58.15
Abundance 9353
59.15
5139
60.15
2428
1637
61.15
Scan 2 (0. 80000

.186 min):
RM2
m/z
95.10
96.10
97.10
98.10
99.10
100.10
101.10
102.10
103.10
104.00
105.10
Scan 2 (0.
m/ z

abund.
70000
5717
4785
8268
60000 3734
3569
4923
50000 8934
2731
1050
1132
40000 _

2553
.186 min):
RM2
30000
abund.

139.10
978
140.20 20000 635
141.10
1385
142.10
1491
143.10
1232
144.10 10000 379
145.10
698
146.10
1984
147.10
15385
148.10
1627
149.00
8600

— T — ĩ — — t—T—r 1 ■ ị—r

D-DIP112. D

C:\HPCHEM\1\DATA\D-DIP112.D
•
m/ z
abund.
Phong Cau truc, vien Hoa hoc
62.05
311 pm using AcqMethod HIDIP
10 May
107
5:08
63.05
772
5989B MS
64.00
457
RM2
65.10
2395
CH30H + CHC13
981
1 66.10
67.10
8182
68.10
5336
69.10
23888
“Scan 2 (0.186 mìn): D-DIP112.D
70.10
65632

71.10
48360
72.10
7428
D-DIP112. D

m/ z
106.00
70
107.10
108.10
109.10
110.10
111.10
112.10
113.10
114.10
115.10
116.10
D-DIP112. D
m/ z
150.05
151.05
152.05
153.05
154.05
155.05
156.05
157.05
158.05

159.05
160.05

abund.
743
1958
1169
3119
2735
17824
27016
13256
1425
1656
484
83abund.
1421
834
689
582
498
950
384
1141
248
426
679

129

112

180

200

220

240

260

280


Scan 2 (0.

186 min):
RM2

D-DIP112. D

m/z
abund.
184.05
155
185.15
304
187.15
240

189.15
196
190.15
153
191.15
250
192.15
218
193.15
186
194.15
193
195.15
155
m/ z
abund.
m/ z
73.10
46424
84.10
74.10
8605
85.10
75.00
1487
86.10
76.00
1100
87.10
77.10

3144
88.00
78.10
775
89.10
79.10
3985
90.10
80.10
1231
91.10
81.10
6858
92.10
82.10
8026
93.10
83.10
27912
94.10
m/ z
abund.
m/ z
117.10
995
128.10
118.10
497
129.10
119.10

1921
130.10
120.10
877
131.10
121.10
1995
132.10
122.10
1700
133.10
123.10
1902
134.10
124.10
1362
135.10
125.10
2112
136.10
126.10
1133
137.10
127.10
2185
138.10
m/ z
abund.
m/ z
161.05

848
172.05
162.05
311
173.05
163.05
462
175.15
164.15
224
176.15
165.05
496
177.05
166.05
364
178.05
166.95
2777
179.05
168.05
590
180.15

m/ z
198.15
199.15
200.15
201.15
205.15

206.05
207.05
209.25
210.05
211.05

abund.
290
899
228
167
179
229
157
160
315
228
abund.
18464
9512
1360
9233
3195
1118
352
3404
914
2871
10470
abund.

4395
59528
4930
1441
894
1324
839
1353
709
1022
618
abund.
240
314
240
250
521
324
354
420


169.15
170.05
171.15
m/ z
213.15
214.15
217.15
218.15

219.05
220.15
222.25
239.10
241.10
242.10

569
209
570
abund.
263
197
221
254
257
246
212
235
2229
492

181.15
182.15
183.15
m/ z
244.10
257.20
258.20
259.20

260.20
264.20
265.30
272.10
279.10

279
227
315
abund.
252
2441
735
1590
324
260
159
179
407


197.15

272

212.15

610

-

PHỤ LỤC III.

Hình ảnh cây Mức hoa trắng


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