Hợp chất vòng béo và dẫn xuất

HÔÏP CHAÁT VOØNG BEÙO

1


1. Goïi teân.

methylcyclopropan

2-ethylcyclobutanol

2-amino-5,5-dimethylcyclohexanol

Bicyclo[2,2,2]-2-octen

2-propylcyclopentanon

1,2,3,4,5,6-hexachlorocyclohexan

Acid 2(2’-oxocyclohexyl)propanoic
2


Bicyclo[4,1,0]heptan

1-ethyl-2,3-diphenylcyclohexanol

1,1,2,2-tetramethyl-3-cyclohexylcyclobutan

Bicyclo[3,2,1]octan

Bicyclo[2,2,1]heptan

Bicyclo[4,4,0]decan
DECALIN

3


1.
10
3

9
2
1

4

8
5

7
Tricyclo[4,2,2,01,6 ]-2-decen

Spiro[4,4]nonan

8
7

6

4

13 14 15 16 1

5

3
2

2

12

6

8

11

1

5,5-dimethylbicyclo[2,2,2]-2-octen

10

9

3

7 6
5

4

7,7-dimethyl dispiro[5,1,6,2]hexadecan

1
10

8
7
6

9

2
3

5
4

Tricyclo [3,3,1,11,5 ]decan

4


2. Vieỏt coõng thửực caỏu taùo

1-n-propyl-4-isopropylcyclohexan

methylcyclopentan

3-methylcyclopenten
3-ethoxy-1-(1-nitrocyclohexyl)-3-hexen-1-ol

Acid 3-chloro-2-hydroxy-6-cyclohexyl-3-hexenoic
5


2.

decalin

Norbornan
Br 2

1

7
8
6

Bicyclo[1,1,1]pentan

3

5

Br

1,5-dibromobicyclo[3,2,1]octan

4

3-cyclopropyl-2-methylheptan

6


3. Công thức khai triển của C6H12 tương ứng với vòng 6, 5, 4 cạnh. Gọi tên

1,2-dimethylcyclobutan

1,3-dimethylcyclobutan

ethylcyclobutan

methylcyclopentan

cyclohexan

7


4. Vẽ đồng phân hình học nếu có
1,1,2-trimethylcyclopropan không có đphh

trans-1,2-dimethylcyclobutan

cis-cis-1,3,5-trimethylcyclohexan

cis-1,2-dimethylcyclobutan

trans-cis-1,3,5-trimethylcyclohexan
8


5. Veõ caáu daïng gheá
a. Acid 2-methylcyclohexancarboxylic

trans(a,a)

trans(e,e)

cis(e,a)

cis(a,e)
9


b. Acid 3-methylcyclohexancarboxylic

trans(e,a)

cis(a,a)

trans(a,e)

cis(e,e)

10


c. Acid 4-methylcyclohexancarboxylic

trans(a,a)

cis(e,a)

trans(e,e)

cis(a,e)

11


6. Viết pứ cộng hơp Diels-Alder và gọi tên sp hình thành của cyclopentadien với
các chất sau:
a. Acid acrylic

bicyclo([2,2,1]-5-hepten-2-carboxylic

b. methylacrylat

Methyl bicyclo([2,2,1]-5-hepten-2-carboxylat
12


c. vinylacetat

bicyclo([2,2,1]-5-hepten-2-yl-acetat

13


7. Hoaứn thaứnh caực chuoói phaỷn ửựng
a.

b.

c.

14