Phản ứng dung dịch pps
Bạn đang xem bản rút gọn của tài liệu. Xem và tải ngay bản đầy đủ của tài liệu tại đây (96.6 KB, 6 trang )
! "
#$%&'$%(%&(%)*
!"!#$
+,*',-%%,./*0%*1*'2.
3/4*'52.*6%7
8
9:70
3
987;
3
9
30%,0<=*$(5*5**=*70
3
9:
3>?%
][
10
][
][
10
][
1414
+
−
+
+
−
−
+=→=
H
CH
H
OH
a
(4@$57
8
9
7
8
9A
3A
:BAC
A
≥A
3"
M
H
OH
8
14
10
][
10
][
−
+
−
−
≤=
D.(EFG7;
3
9)
]
100
1
][
a
COH ≤
−
BAC 7
8
9:
→<:3$'
HA
3"
B,,.$*'C
=*'IEFG7;
3
94%
'F<BAC7
8
9
7
8
9A
3A
:
%&' ()*
+,*',-%.2*%,(J0%*1*'2.21$5
)5K*'J%,$5
08
;
→
0
3
8
L
;
8
][
][
.][
][
]].[[
−
+
−+
=→=
A
HA
KH
HA
AH
K
aa
3/4*'52.*6%7
8
9:70
3
987;
3
9(70
3
9:7
8
97;
3
9
3-*$.EF5*?J$/*'
:709870
3
9(709:
70
3
9
709:
7
8
987;
3
9
(EI%709)570
3
9)5EI%7
8
9F4=*M2/%@
)2(
][][
][][
.][
−+
−+
+
−
+−
=
OHH
OHHC
KH
a
a
%E%6**
6*'4-'1*2*'
gd
gdaagd
H
OHCKH
][
10
][,][
14
+
−
−+
==
A
4J*FM%,4J(J
7
8
9)57;
3
9214J*F)
)5 NJ< NO'1***=*?=*'IEFG
7;
3
9 4% 7
8
9 **' )P* % I EF G 7
8
9 4%
%
agdgd
COHOH
100
1
][][ ≤≈
−−
BC4F5*
aa
a
a
CKOHHH
OHH
C
KH .]].[[][
][][
.][
2
=−→
−
=
−++
−+
+
14
10][
−+
+=
aa
CKH
agdgdgd
CHOH
100
1
][H ,][
100
1
][ ≤≤
++−
2
[ ]
+
=
a a
H K C
L
agdgdgd
CHOH
100
1
][H ,][
100
1
][ >≤
++−
F'F<BC
aa
aa
CK
KK
H ++−=
+
42
][
2
+ ()*
P0<=*$(M2/%.
8
%F%%A)5A
8
%F%%)5A0
3
*=*
7
8
9
%
:70
3
9
P
0<=*$(4A
8
%*'M
%7
8
9
][
]].[[
2
2
−
−+
=
HA
AH
K
a
(47
8
9
%
:70
3
9≈
B)Q7
8
9:70
3
9C
D.(7
8
9:7
8
9
%A
8
DQ
5*'4J*F)
A
BHA$1*C*=*%I$J(7
8
9:7
8
9
%A
M%$5
N,%,
0*2*%,(J
%6*<*2*%,(J
,-./'$ #$01 ()*
C1*'2.%,/*$***1*'2.%,(J
8
,%,/*<=*$(4*1$5%%J/*%,(J)5*%R
2MN*<%F%,%O$5<%F%,/*
EC1*'2.%,/**F**1*'2.%,(J
=*'IEFG
8
%F%,(J
),6*<,,P*/<$A
3
)5
L
;;A
3
B
L
;;%<
:
MS!C
][
][
.][
][
]][[
3
3
3
3
−
+
+−
=→=
COOCH
COOHCH
KH
COOHCH
HCOOCH
K
aa
3/4*'52.*6%7
8
9:7
L
;;
3
987$
3
987;
3
9
3%,MEFG7;
3
97$
3
9:
$
:A
3
D.(7
L
;;
3
9:7
8
9A
3
3$EF5*?J$/*'7
L
;;987
L
;;
3
9:A
3
3 F G 7
L
;;
3
9 4% 7
L
;;9 )Q %, (J * ? *=*
7
L
;;9:A
3
()5EI%7
8
94=*
14
2
5
10][
10
.10.78,1][
−+
−
−+
−
=
H
H
(42/%<
%CP*/<%,(J
TFF,,%%,(J0
U
)50
UU
/4*'52.*6%7
8
9:70
3
U
9870
3
UU
9BVCBEFG7;
3
9)Q%,C
][
]][[
I
I
HA
HA
HA
K
I
+−
=
()5BVC
][
][
][
][
][
++
+
+=
H
HA
K
H
HA
KH
II
HA
I
HA
III
(
][][][
2
IIHAIHA
HAKHAKH
III
+=
+
J%%%,0
U
)50
UU
?(JM%I$J('1*2*'
0
II
0
][HA ,][
III
HAHAI
CCHA ≈≈
002
][
IIIIII
HAHAHAHA
CKCKH +=→
+
BLC
.* N
0
II
HAHA
CK
%6* $5 7
8
9 '1* 2*' 5 0
U
% 4 *J %O % 0
U
4*',*',-%*'/)
0
IIII
HAHA
CK
R2M%I)J$/EI%BLC,,/*'
222
][][][
+++
+=
III
HHH
J$.*
31*'2.%,(J*'2*'5K*'J
?%**1%I$J(
'1*2*'7
8
9EK*'7
8
9%F%,/**J4*'%,(J
31*'2.%,(J?%**15K*'J
*'2*'*M%I
$J('1*2*'7
8
9EK*'7
8
9%F%,%*1*'2.$**J4*'%,(J
3J
)5*1*'2.%,(J21*'2*'M'F<BLC
2#.*
CJNJ<5%,/*)5E/*
<:SM
ECJNJ<5%,/*)5E(J
6*<*2*%,(J<HSM
%CJNJ<5%,(J)5E/*
6*<*2*E(J<WSM
,C<,*',-%J4*'5
+,*',-%J4*'5
0<=*$(5*5*4*'*%
0→
8
80
3
0
3
$5A2E
0
3
8
;→0
3
8;
3
EA
0
3
8
;→
08;
3
E
5*'
EA
WW
EM
−−
>
HAA
CC
2
*=*,,%IN*%O%Elà 0
3
M
0
3
0
)5%6*E/**)5*1*'2.$**0
3
*=*,,2/%%*
%O%E0
3
)56*<,*',-%*%O%0
3
C<,*',-%J%**$*'6*
+J0%**0
3
$5A**$*'6*
0
3
8
;→0
3
8
L
;
8
0
0
3
8
;→
08;
3
E
0
0%,
0%%%K*'J%,$1*$/$5
][
]][[
][
]][[
2
2
2
1
−
−+
−+
=
=
HA
AH
K
AH
HAH
K
a
a
][
][][
2
22
21
AH
AH
KK
aa
−+
=→
/4*'52.*6%7
8
987
8
9:7;
3
9870
3
9870
3
9BVC
EF5*?J$/*'7
09870
3
9870
3
9::7
8
9
(7
8
9)5BVC7
8
987
09870
3
9870
3
9:7;
3
9870
3
9870
3
9
→7
8
987
09:7;
3
9870
3
9BC
0
3
)52*')45$5A%,4J(JB%6
8
$/)5$5.E4J(JB=
/J
8
9CR2M%IEFG7
8
94%7
09)57;
3
94%70
3
9
.%BC7
09:70
3
9
()5EI%
A
( )
2121
2
2
1
.][
aaaa
pKpKpHKKH +=→=
+
3./'$ ()*0145)6 )7'$
+,*',-%%%,(J0*1*'2.21
)5E$=*/<0
3
B,,/*'
J0C%*1*'2.21$5
E
][
][
][
][
]][[
−
+
−+
=→=
A
HA
KH
HA
AH
K
aa
/4*'52.*6%7
8
987
8
9:7;
3
9870
3
9
7
8
9:
E
→70
3
9:
E
87
8
97;
3
9
EF5*?J$/*'70
3
98709:
8
E
709:
8
E
70
3
9:
8
E
3
E
37
8
987;
3
9:
7
8
987;
3
9
('4-70
3
9)5709)5EI%7
8
94=*
][][
][][
][
−+
−+
+
−+
+−
=
OHHC
OHHC
KH
b
a
a
AJ,*',-%%6*%,7
8
9WW7;
3
99
][
][
][
+
+
+
+
−
=
HC
HC
KH
b
a
a
J,*',-%%6*E7
8
9HH7;
3
9
][
][
][
−
−
+
−
+
=
OHC
OHC
KH
b
a
a
L
)5
E
5*'?$*)7
8
9)57;
3
9B('><4*'/%JC
b
a
a
b
a
a
C
C
pKpH
C
C
KH log][ +=→=
+
81 !"$9
AX6*<%F,,
C;A
3
)5A
3
EC$*A
3A
)5A
3L
%CMAB%<
: MLC
,C
$MAB%<
L
:MS!C
VC
;
MAB<
;3
:AM C
VYC
;
L
MA
V'CB
C
;
L
MA
C;
L
MA
C
;
MA
=YM'%EJ0%,%4E*%%<
A
:"ML!)5<
:AML!
X6*<%FJ/5*5
C
L
MA)
L
;;MAB%<
L
:<
L;;
:MS!C
EC
L
M)
;
MAB<
;3
:AM C
LX6*<%FP*/<,,'1
C 0%, $%%
!
;;; M B< : LML"C )5 ?$ $%%
!
;;;
M
EC
$M!)
L
MAB%<
L
:MS!C
XR*',-%2.2/%%I*E-5!'XZ%F
L
;;)!'XZ%F
L
;;6*
C<,,21
EC<,,?=$%*1*'2.'XZ
%C<,,?=;%*1*'2.'XZ
,C<,,?=!M!Z*%
